{"id":262,"date":"2013-03-28T09:50:53","date_gmt":"2013-03-28T14:50:53","guid":{"rendered":"https:\/\/elements.chem.umass.edu\/thaigroup\/?page_id=262"},"modified":"2018-10-12T12:41:31","modified_gmt":"2018-10-12T17:41:31","slug":"supramolecular-assembly","status":"publish","type":"page","link":"https:\/\/elements.chem.umass.edu\/thaigroup\/publications\/supramolecular-assembly\/","title":{"rendered":"Supramolecular Assembly and Disassembly"},"content":{"rendered":"
302)<\/a>

Penido, J. A.; Le, S. P.; Varadarajan, A.; Thayumanavan, S.; Perry, S. L.* & Loh, W.* Complex Coacervate Emulsions as a Strategy to Stabilize Enzymes for Catalysis in Organic Solvents. ACS Macro Letters, 2025<\/a><\/p>\n

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301)<\/a>

Jia, Z.; Chen, A. M.; Li, S., & Thayumanavan, S.” Stepwise Disassembly of Supramolecular Structures Triggered by Specific Protein Binding.” Biophysical Journal, 2025<\/i><\/a><\/p>\n<\/div><\/div>

299)<\/a>

Das, R; Medeiros, J; Krishna, J; Munugoti, S; Dutta, R; Devarajan, A; Ghosh, A; & Thayumanavan, S; “Multicheckpoint Cellular Targeting of siRNAs Using Antibody-Directed Lipid-Polymer Hybrid Nanoparticles.” Bioconjugate Chemistry. 2025 Jul 3<\/a>.<\/p>\n

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289)<\/a>

Das, R.*<\/span>; Dutta, R.*<\/span>; Yi, J.*<\/span>; Qiu, J.; Krishna, J.; Tzafriri, G.; Lin, Z. and Thayumanavan, S. “Intramolecular electrostatic interactions regulate reactivity of zwitterionic functionalities in amphiphilic assemblies.” \u00a0Angew. Chem. Int. Ed.<\/em> 2024, e202405868<\/a> (https:\/\/doi.org\/10.1002\/anie.202405868)<\/span><\/p>\n

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284)<\/a>

Kanjilal, P.; Singh, K.;<\/span> Das, R.; Matte, J. <\/span>and Thayumanavan, S. “Antibody Polymer Conjugates (APCs) for Active Targeted Therapeutic Delivery” <\/span>Biomacromolecules<\/i>\u00a02023<\/span>, 24<\/span>, 8<\/span>, 3638\u20133646,<\/span><\/span><\/a> (DOI:10.1021\/acs.biomac.3c00385)<\/span><\/p>\n

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275)<\/a>

Das, R.; Kanjilal, P.; Medeiros, J.; Thayumanavan, S. \u201cWhat\u2019s Next After LNPs? A Perspective on Enablers of Nucleic Acid Therapeutics\u201d <\/span>Bioconj. Chem. <\/span><\/i>2022<\/b>, <\/span>33<\/span><\/i><\/a>, In press. (DOI:10.1021\/acs.bioconjchem.2c00058)<\/span><\/p>\n<\/div><\/div>

274)<\/a>

Singh, K.; Canakci, M.; Kanjilal, P.; Williams, N.; Shanthalingam, S.; Osborne, B.; Thayumanavan, S. \u201cEvaluation of Cellular Targeting by Fab\u2019 vs Full-length Antibodies in Antibody-Nanoparticle Conjugates (ANCs) Using CD4 T-cells\u201d <\/span>Bioconj. Chem. <\/span><\/i>2022<\/b>, <\/span>33<\/span><\/i><\/a>, In press. (DOI: 10.1021\/acs.bioconjchem.2c00024)<\/span><\/p>\n

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272)<\/a>

Liu, H.; Prachyathipsakul, T.; Koyasseril-Yehiya, T.M.; Le, S.P.; Thayumanavan, S. \u201cMolecular bases for temperature sensitivity in supramolecular assemblies and their applications as thermoresponsive soft materials\u201d Mater. Horiz., <\/em>2021<\/strong>, 9<\/strong>, 164-193<\/a>. (DOI:10.1039\/D1MH01091C)
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271)<\/a>

Liu, H.; Kanjilal, P.; Thayumanavan, S. \u201cSelf-assembly of Polymers from Multicomponent Reactions\u201d Polymer International, <\/em>2022<\/strong>, In Press <\/a>. (DOI:10.1002\/pi.6352)<\/p>\n

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270)<\/a>

Wu, P.; Gao, J.; Prasad, P.; Dutta, K.; Kanjilal, P.; Thayumanavan, S. \u201cInfluence of Polymer Structure and Architecture on Drug Loading and Redox-Triggered Release\u201d Biomacromolecules, <\/em>2021<\/strong>, 23<\/span>, 1<\/span>, 339\u2013348<\/span> <\/a>. (DOI:10.1021\/jacs.1c08574)
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269)<\/a>

Liu, H.; Lu, H.H.; Zhuang, J.; Thayumanavan, S. \u201cThree-Component Dynamic Covalent Chemistry: From Janus Small Molecules to Functional Polymers\u201d J. Am. Chem. Soc., <\/em>2021<\/strong>, 143, 20735-20746<\/a>. (DOI:10.1021\/jacs.1c08574)
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268)<\/a>

Gao, J.*; Prachyathipsakul, T.*; Thayumanavan, S. \u201cMultichannel Dual Protein Sensing Using Amphiphilic Supramolecular Assemblies\u201d Chem. Commun., <\/em>2021<\/strong>, 57, 12828-12831<\/a>. (DOI:10.1039\/D1CC05407D)
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267)<\/a>

Gao, J.; Le, S.; Thayumanavan, S. \u201cEnzyme Catalysis in Non-Native Environment with Unnatural Selectivity using Polymeric Nanoreactors\u201d Angew. Chem. Int. Ed., <\/em>2021<\/strong>, 60, 27189\u201327194<\/a>. (DOI:10.1002\/anie.202109477)
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266)<\/a>

Lionello, C.; Gardin, A.; Cardellini, A.; Bochicchio, D.; Shivrayan, M.; Fernandez, A.; Thayumanavan, S.; and Pavan, G.M. \u201cToward Chemotactic Supramolecular Nanoparticles: From Autonomous Surface Motion Following Specific Chemical Gradients to Multivalency-Controlled Disassembly\u201d ACS Nano, <\/em>2021<\/strong>, 15<\/em>, 10, 16149-16161 <\/a>. (DOI:10.1021\/acsnano.1c05000)
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265)<\/a>

Nandi, D.; Shivrayan, M.; Gao, J.; Krishna, J.; Das, R.; Liu, B.; Thayumanavan, S.; and Kulkarni, A. \u201cCore Hydrophobicity of Supramolecular Nanoparticles Induces NLRP3 Inflammasome Activation\u201d ACS Appl. Mater. Interfaces, <\/em>2021<\/strong>, 13<\/em>, 38, 45300-45314<\/a>. (DOI:10.1021\/acsami.1c14082)
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264)<\/a>

Liu, H.; Westley, J.; Thayumanavan, S. \u201cExcimer-monomer fluorescence changes by supramolecular disassembly for protein sensing and quantification\u201d Chem. Commun., <\/em>2021<\/strong>, 57, 9776-9779<\/a>. (DOI:10.1039\/D1CC03944J)
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262)<\/a>

Anson, F.; Thayumanavan, S.; Hardy, J.A. \u201cExogenous Introduction of Initiator and Executioner Caspases Results in Different Apoptotic Outcomes\u201d JACS Au, <\/em>2021<\/strong>,1<\/span>, 8<\/span>, 1240\u20131256<\/span>\u00a0<\/a>. (DOI:10.1021\/jacsau.1c00261)
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261)<\/a>

Dutta, K.; Das, R.; Medeiros, J.; Kanjilal, K.; Thayumanavan, S.\u201cCharge-Conversion Strategies for Nucleic Acid Delivery\u201d Adv. Funct. Mater., <\/em>2021<\/strong>, 31<\/em>, 2011103<\/a>. (DOI:10.1002\/adfm.202011103)
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260)<\/a>

Liu, H.; Lionello, C.; Westley, J.; Cardellini, A.; Huynh, U.; Pavan, G.M.; Thayumanavan, S. \u201cUnderstanding functional group and assembly dynamics in temperature responsive systems leads to design principles for enzyme responsive assemblies\u201d Nanoscale, <\/em>2021<\/strong> , 13, 11568-11575 <\/a>. (DOI:10.1039\/D1NR02000E)
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259)<\/a>

Liu, B.; Singh, K.; Gong, S.; Canakci, M.; Osborne, B.A.; Thayumanavan, S. \u201cProtein-Antibody Conjugates (PACs): A Plug-and-Play Strategy for Covalent Conjugation and Targeted Intracellular Delivery of Pristine Proteins\u201d Angew. Chemie. Int. Ed., <\/em>2021<\/strong> , 60<\/em>, 12813-12818\u00a0<\/a>. (DOI:10.1002\/anie.202103106)
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258)<\/a>

Anson, F.; Liu, B.; Kanjilal, P.; Wu, P.; Hardy, J. A.; Thayumanavan, S. \u201cEvaluating Endosomal Escape of Caspase-3-Containing Nanomaterials Using Split GFP\u201d Biomacromolecules, <\/em>2021<\/strong> ,22<\/span>, 3<\/span>, 1261\u20131272<\/span> <\/a>. (DOI:10.1021\/acs.biomac.0c01767)
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257)<\/a>

Dutta, K.; Das, R.; Medeiros, J. M.; Thayumanavan, S. \u201c”Disulfide Bridging Strategies in Viral and Non-viral Platforms for Nucleic Acid Delivery\u201d Biochemistry, <\/em>2021<\/strong>, <\/em>60<\/span>, 13<\/span>, 966\u2013990<\/span><\/em><\/a>. (DOI:10.1021\/acs.biochem.0c00860)
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255)<\/a>

Anson, F.; Kanjilal, P.; Thayumanavan, S.; Hardy, J. \u201cTracking Exogenous Intracellular Casp-3 Using Split GFP” Prot. Sci., <\/em>2020<\/strong>, 30 <\/em>, 366-380\u00a0<\/a>. (DOI:10.1002\/pro.3992)
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253)<\/a>

Dutta, K.; Kanjilal, P.; Das, R.; Thayumanavan, S. \u201cSynergistic Interplay of Covalent and Non-Covalent Interactions in Reactive Polymer Nanoassembly Facilitates Intracellular Delivery of Antibodies” Angew. Chem. Int. Ed., <\/em>2020<\/strong>, 59, <\/em>2-12\u00a0<\/a>. (DOI: 10.1002\/anie.202010412)
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252)<\/a>

Koyasseril-Yehiya, T. M.; Garc\u00eda-Heredia, A.; Anson, F.; Rangadurai, P.; Siegrist, M. S.; Thayumanavan, S. \u201cSupramolecular Antibiotics: A Strategy for Conversion of Broad-Spectrum to Narrow-Spectrum Antibiotics for Staphylococcus aureus” Nanoscale, <\/em>2020<\/strong>, 12, <\/em>20693-20698\u00a0<\/a>. (DOI: 10.1039\/D0NR04886K)
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250)<\/a>

Gao, J.; Dutta, K.; Zhuang, J.; Thayumanavan, S. \u201cCellular and subcellular targeted delivery using a simple all-in-one polymeric nanoassembly” Angew. Chem. Int. Ed., <\/em>2020<\/strong>, 59, <\/em> 23466-23470 <\/a>. (DOI: 10.1002\/anie.202008272)
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249)<\/a>

Kumar, V.; Munkhbat, O.; Secinti, H.; Thayumanavan, S \u201cDisassembly of Polymeric Nanoparticles with Enzyme-Triggered Polymer Unzipping: Polyelectrolyte Complexes vs. Amphiphilic Nanoassemblies” Chem. Commun., <\/em>2020<\/strong>, 56, <\/em>8456-8459\u00a0<\/a>. (DOI: 10.1039\/D0CC03257C)
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247)<\/a>

Dutta, K.; Das, R.; Ling, J.; Monibas, R.M.; Carballo-Jane, E.; Kekec, A.; Feng, D.D.; Lin, S.; Mu, J.; Saklatvala, R.; Thayumanavan, S.; Liang, Y. “In Situ Forming Injectable Thermoresponsive Hydrogels for Controlled Delivery of Biomacromolecules” ACS Omega, <\/em>2020<\/strong>, 5, <\/em>17531-17542\u00a0<\/a>. (DOI: 10.1021\/acsomega.0c02009)
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246)<\/a>

Zhuang, J. and Thayumanavan, S. “Triblock\u2013Diblock Composite Nanoassemblies with Sequentially Addressable Host\u2013Guest Properties for Hydrophobics and Hydrophilics” ACS Macro Lett, <\/em>2020<\/strong>, 9, <\/em>1019-1023\u00a0<\/a>. (DOI: 10.1021\/acsmacrolett.0c00290)
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244)<\/a>

Liu, B.; Wu, R.; Gong, S.; Xiao, H.; Thayumanavan, S. “In Situ Formation of Polymeric Nanoassemblies Using an Efficient reversible Click Reaction” Angew. Chem. Int. Ed., <\/em>2020,<\/strong> 59, <\/em> 15135 \u201315140 <\/a>. (DOI: 10.1002\/anie.202004017)
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242)<\/a>

Canakci, M.; Singh, K.; Munkhbat, O.; Santhalingam, S.; Mitra, A.; Gordon, M.; Osborne, B.; Thayumanavan, S. “Targeting CD4+ Cells with Anti-CD4 Conjugated mertansine Loaded Nanogels” Biomacromolecules, <\/em>2020,<\/strong> 21, <\/em> 2473\u20132481 <\/a>. (DOI: 10.1021\/acs.biomac.0c00442)
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241)<\/a>

Liu, B.; Ejaz, W.; Gong, S.; Kurbanov, M.; Canakci, M.; Anson, F.; Thayumanavan, S. ” Engineered Interactions with Mesoporous Silica Facilitate Intracellular Delivery of Proteins and Gene Editing” Nano Lett., <\/em>2020,<\/strong> 20<\/em>, 4014-4021<\/a> (DOI: 10.1021\/acs.nanolett.0c01387) <\/p>\n<\/div><\/div>

240)<\/a>

Zhao, B.; Zhuang, J.; Xu, M.; Liu, T.; Limpikirati, P.; Thayumanavan, S.; Vachet, R.W. “Covalent Labeling with an \u03b1, \u03b2 Unsaturated Carbonyl Scaffold for Studying Protein Structure and Interactions by Mass Spectrometry” Anal. Chem., <\/em>2020,<\/strong> 92, <\/em> 6637\u22126644 <\/a>. (DOI: 10.1021\/acs.analchem.0c00463 ) <\/p>\n<\/div><\/div>

239)<\/a>

Mitra, A.; Shanthalingam, S.; Sherman, H.; Singh, K.; Canakci, M.; Torres, J.A.; Lawlor, R.; Ran, Y.; Golde, T.; Miele, L.; Thayumanavan, S.; Minter, L.M.; Osborne, B.A. “Regulation of Notch ligand expression on CD4 T cells” Frontiers in Immunology, <\/em>2020,<\/strong> 11<\/em>, 735\u00a0<\/a>. (DOI: 10.3389\/fimmu.2020.00735) <\/p>\n<\/div><\/div>

238)<\/a>

Jiang, Z.; Liu, H.; He, H.; Yadava, N.; Chambers, J. “Anionic Polymers Promote Mitochondrial Targeting of Delocalized Lipophilic Cations\u201d Bioconjugate Chem., <\/em>2020,<\/strong> 31, <\/em> 1344\u20131353<\/a>. (DOI: 10.1021\/acs.bioconjchem.0c00079)
\n[Video<\/a>] [Featured as the Cover Art<\/a>]<\/p>\n

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237)<\/a>

Gao, J.; Wu, P.; Fernandez, A.; Zhuang, J.; Thayumanavan, S. “Cellular AND Gates: Synergistic Recognition to Boost Selective Uptake of Polymeric Nanoassemblies\u201d Angew.Chem.Int.Ed., <\/em>2020,<\/strong> 59, <\/em>1-6<\/a>. (DOI: 10.1002\/anie.202002748) <\/p>\n<\/div><\/div>

236)<\/a>

Jiang, Z.; Liu, H. (co-first); He, H.; Ribbe, A.E.; Thayumanavan, S. “Blended Assemblies of Amphiphilic Random and Block Copolymers for Tunable Encapsulation and Release of Hydrophobic Guest Molecules\u201d Macromolecules, <\/em>2020,<\/strong> 53, <\/em>2713\u20132723\u00a0<\/a>. (DOI: 10.1021\/acs.macromol.9b02595) <\/p>\n<\/div><\/div>

235)<\/a>

Tsuei, M.; Shivrayan, M.; Kim, Y.; Thayumanavan, S.; Abbott, N.L. “Optical “Blinking” Triggered by Collisions of Single Supramolecular Assemblies of Amphiphilic Molecules with Interfaces of Liquid Crystals\u201d J. Am. Chem. Soc., <\/em>2020,<\/strong> 142, <\/em>6139\u20136148\u00a0<\/a>. (DOI: 10.1021\/jacs.9b13360) <\/p>\n<\/div><\/div>

232)<\/a>

Jiang, Z. and Thayumanavan, S. “Disulfide\u2010containing Macromolecules for Therapeutic Delivery\u201d Isr. J. of Chem., <\/em>2020,<\/strong> 60, <\/em> 132-139<\/a>. (DOI: 10.1002\/ijch.201900160)
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231)<\/a>

Jiang, Z. and Thayumanavan, S. “Noncationic Material Design for Nucleic Acid Delivery\u201d Advanced Therapeutics, <\/em>2020<\/strong> <\/em>,1900206 <\/a>. (DOI: 10.1002\/adtp.201900206) <\/p>\n<\/div><\/div>

229)<\/a>

Zhao, B.; Gao, J.; Serrano, M.A.C.; Arcaro, K.F.; Thayumanavan, S.; and Vachet, R.W. “Polymeric nanoassemblies for enrichment and detection of peptides and proteins in human breast milk\u201d Anal Bioanal Chem, <\/em>2020, <\/strong> 412, <\/em> 1027-1035<\/a>. (DOI: 10.1007\/s00216-019-02342-8)
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227)<\/a>

Jiang, Z.; He, H.; Liu, H.; Thayumanavan, S. “Cellular Uptake Evaluation of Amphiphilic Polymer Assemblies: Importance of Interplay between Pharmacological and Genetic Approaches\u201d Biomacromolecules, <\/em>2019<\/strong>, 20,<\/em> 4407-4418 <\/a>. (DOI: 10.1021\/acs.biomac.9b01073)
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226)<\/a>

Wang, M.; Gao, J.; Zhao, B.; Thayumanavan, S.and Vachet, R.W. “Efficient enrichment of glycopeptides by supramolecular nanoassemblies that use proximity-assisted covalent binding” Analyst, <\/em>2019<\/strong>, 144, <\/em> 6321-6326 <\/a>. (DOI: 10.1039\/C9AN01113G)
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225)<\/a>

Liu, B. and Thayumanavan, S. “Three-Component Sequential Reactions for Polymeric Nanoparticles with Tailorable Core and Surface Functionalities\u201d Chem, <\/em>2019<\/strong>, 5, <\/em> 3166-3183 <\/a>. (DOI: 10.1016\/j.chempr.2019.09.001)
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223)<\/a>

Liu, B.; Ianosi-Irimie, M.; Thayumanavan, S. “Reversible Click Chemistry for Ultrafast and Quantitative Formation of Protein-Polymer Nanoassembly and Intracellular Protein Delivery” ACS Nano, <\/em>2019<\/strong>, 13, <\/em> 9408-9420 <\/a>. (DOI: 10.1021\/acsnano.9b04198)
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222)<\/a>

Dutta, K.; Bochicchio, D.; Ribbe, A.E.; Alfandari, D.; Mager, J.; Pavan, G.M.; Thayumanavan, S. “Symbiotic Self-Assembly Strategy toward Lipid-Encased Cross-Linked Polymer Nanoparticles for Efficient Gene Silencing” ACS Appl. Mater. Interfaces <\/em>2019<\/strong>, <\/em> 11, 24971-24983 <\/a>. (DOI: 10.1021\/acsami.9b04731)
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221)<\/a>

Raghupathi, K.; Kumar, V.; Sridhar, U.; Ribbe, A.E.; He, H.; Thayumanavan, S. “Role of Oligoethylene Glycol Side Chain Length in Responsive Polymeric Nanoassemblies\u201d Langmuir, <\/em>2019<\/strong>, 35,<\/em> 7929-7936 <\/a>. (DOI: 10.1021\/acs.langmuir.9b00676)
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217)<\/a>

Singh, K.; Ejaz, W.; Dutta, K.; Thayumanavan, S. “Antibody Delivery for Intracellular Targets \u2013 Emergent Therapeutic Potential\u201d Bioconjugate Chem. <\/em>2019<\/strong>, 30,<\/em> 1028-1041<\/a>. (DOI: 10.1021\/acs.bioconjchem.9b00025)
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215)<\/a>

Khomein, P.; Dutta, K.; Gnanasekaran, K.; Gianneschi, N. C.; Thayumanavan, S. “Spatiotemporal Control over the Host\u2013guest Characteristics of a Stimulus-triggerable Trifunctional Polymer Assembly\u201d Polym. Chem. <\/em>2019<\/strong>, 10,<\/em> 1423-1430\u00a0<\/a>. (DOI: 10.1039\/C8PY01788C)
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214)<\/a>

Gao, J.; Wang, H.; Zhuang, J.; Thayumanavan, S. “Tunable Enzyme Responses in Amphiphilic Nanoassemblies through Alterations in the Unimer\u2013aggregate Equilibrium\u201d Chem. Sci. <\/em>2019<\/strong>, 10,<\/em> 3018-3024<\/a>. (DOI: 10.1039\/C8SC04744H)
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212)<\/a>

Jiang, Z.; Cui, W.; Prasad, P.; Touve, M. A.; Gianneschi, N. C.; Mager, J.; Thayumanavan, S. “Bait-and-Switch Supramolecular Strategy To Generate Noncationic RNA\u2013Polymer Complexes for RNA Delivery\u201d Biomacromolecules <\/em>2019<\/strong>, 20,<\/em> 435\u2013442<\/a>. (DOI: 10.1021\/acs.biomac.8b01321)
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210)<\/a>

He, H.; Liu, B.; Wang, M.; Vachet, R. W.; Thayumanavan, S. “Sequential Nucleophilic ‘Click’ Reactions for Functional Amphiphilic Homopolymers\u201d Polym. Chem. <\/em>2019<\/strong>, 10,<\/em> 187-193<\/a>. (DOI: 10.1039\/C8PY01341A)
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209)<\/a>

Zhuang, J.; Secinti, H.; Zhao, B.; Thayumanavan, S. “Propagation of Enzyme Induced Surface Events Inside Polymer Nanoassemblies for a Fast and Tunable Response\u201d Angew. Chem. Int. Ed. <\/em>2018<\/strong>, 57,<\/em> 7111-7115<\/a>. (DOI: 10.1002\/anie.201803029)
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208)<\/a>

Molla, M. R.; Rangadurai, P.; Antony, L.; Swaminathan, S.; de Pablo, J. J.; Thayumanavan, S. “Dynamic Actuation of Glassy Polymersomes through Isomerization of a Single Azobenzene Unit at the Block Copolymer Interface\u201d Nat. Chem. <\/em>2018<\/strong>, 10,<\/em> 659\u2013666<\/a>. (DOI: 10.1038\/s41557-018-0027-6)
\n[Highlighted by UMass News<\/a>]
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207)<\/a>

Serrano, M. A. C.; Gao, J.; Kelly, K. A.; Thayumanavan, S.; Vachet, R. W. “Supramolecular Polymeric Assemblies for the Selective Depletion of Abundant Acidic Proteins in Serum\u201d ACS Appl. Mater. Interfaces <\/em>2018<\/strong>, 10,<\/em> 40443\u201340451<\/a>. (DOI: 10.1021\/acsami.8b15976)
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205)<\/a>

Kim, Y.-K.; Raghupathi, K. R.; Pendery, J. S.; Khomein, P.; Sridhar, U.; de Pablo, J. J.; Thayumanavan, S.; Abbott, N. L. “Oligomers as Triggers for Responsive Liquid Crystals\u201d Langmuir <\/em>2018<\/strong>, 34,<\/em> 10092\u201310101<\/a>. (DOI: 10.1021\/acs.langmuir.8b01944)
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204)<\/a>

Leriche, G.; Manafirad, A.; Nguyen, S.; Bell, N.; Patterson, J. P.; Thayumanavan, S.; Yang, J.; Dinsmore, A. D.; Gianneschi, N. C. “Water Permeability and Elastic Properties of an Archaea Inspired Lipid Synthesized by Click Chemistry\u201d Chem. Mater. <\/em>2018<\/strong>, 30,<\/em> 3618\u20133622<\/a>. (DOI: 10.1021\/acs.chemmater.8b00992)
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202)<\/a>

Serrano, M. A. C.; Zhao, B.; He, H.; Thayumanavan, S.; Vachet, R. W. “Molecular Features Influencing the Release of Peptides from Amphiphilic Polymeric Reverse Micelles\u201d Langmuir <\/em>2018<\/strong>, 34,<\/em> 4595\u20134602<\/a>. (DOI: 10.1021\/acs.langmuir.7b04065)
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201)<\/a>

Zhao, B.; Serrano, M. A. C.; Wang, M.; Liu, T.; Gordon, M. R.; Thayumanavan, S.; Vachet, R. W. “Improved Mass Spectrometric Detection of Acidic Peptides by Variations in the Functional Group pKa Values of Reverse Micelle Extraction Agents\u201d Analyst <\/em>2018<\/strong>, 143,<\/em> 1434-1443<\/a>. (DOI: 10.1039\/C7AN02094E)
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200)<\/a>

Gao, J.; Zhao, B.; Wang, M.; Serrano, M. A. C.; Zhuang, J.; Ray, M.; Rotello, V. M.; Vachet, R. W.; Thayumanavan, S. “Supramolecular Assemblies for Transporting Proteins Across an Immiscible Solvent Interface\u201d J. Am. Chem. Soc. <\/em>2018<\/strong>, 7,<\/em> 2421-2425<\/a>. (DOI: 10.1021\/jacs.7b13245)
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197)<\/a>

Gao, J.; Liu, X.; Secinti, H.; Jiang, Z.; Munkhbat, O.; Xu, Y.; Guo, X.; Thayumanavan, S. “Photoactivation of Ligands for Extrinsically and Intrinsically Triggered Disassembly of Amphiphilic Nanoassemblies\u201d Chem. Eur. J. <\/em>2018<\/strong>, 24,<\/em> 1789\u20131794<\/a>. (DOI: 10.1002\/chem.201705217)
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196)<\/a>

Zhao, B.; Serrano, M. A. C.; Gao, J.; Zhuang, J.; Vachet, R. W.; Thayumanavan, S. “Self-assembly of Random Co-polymers for Selective Binding and Detection of Peptides\u201d Polym. Chem. <\/em>2018<\/strong>, 9,<\/em> 1066-1071<\/a>. (DOI: 10.1039\/C7PY01947E)
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195)<\/a>

Homyak, C. C.; Fernandez, A.; Touve, M. A.; Zhao, B.; Anson, F.; Hardy, J. A.; Vachet, R. W.; Gianneschi, N. C.; Ross, J. L.; Thayumanavan, S. “Lipogels for Encapsulation of Hydrophilic Proteins and Hydrophobic Small Molecules\u201d Biomacromolecules <\/em>2018<\/strong>, 19,<\/em> 132\u2013140<\/a>. (DOI: 10.1021\/acs.biomac.7b01300)
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194)<\/a>

Khomein, P.; Swaminathan, S.; Young, E. R.; Thayumanavan, S. “Fluorescence Enhancement Through Incorporation of Chromophores in Polymeric Nanoparticles\u201d J. Inorg. Organomet. Polym. Mater. <\/em>2018<\/strong>, 28,<\/em> 407-413<\/a>. (DOI: 10.1007\/s10904-017-0670-1)
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193)<\/a>

Zhao, B.; Zhuang, J.; Serrano, M. A. C.; Vachet, R. W.; Thayumanavan, S. “Influence of Charge Density on Host\u2013Guest Interactions within Amphiphilic Polymer Assemblies in Apolar Media\u201d Macromolecules <\/em>2017<\/strong>, 50,<\/em> 9734\u20139741<\/a>. (DOI: 10.1021\/acs.macromol.7b02434)
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192)<\/a>

Liu, B.; Thayumanavan, S. “Importance of Evaluating Dynamic Encapsulation Stability of Amphiphilic Assemblies in Serum\u201d Biomacromolecules <\/em>2017<\/strong>, 18,<\/em> 4163\u20134170<\/a>. (DOI: 10.1021\/acs.biomac.7b01220)
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190)<\/a>

Wang, M.; Zhao, B.; Gao, J.; He, H.; Castellanos, L. J.; Thayumanavan, S.; Vachet, R. W. “Altering the Peptide Binding Selectivity of Polymeric Reverse Micelle Assemblies via Metal Ion Loading\u201d Langmuir <\/em>2017<\/strong>, 33,<\/em> 14004\u201314010<\/a>. (DOI: 10.1021\/acs.langmuir.7b02488)
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189)<\/a>

Dutta, K.; Hu, D.; Zhao, B.; Ribbe, A.; Zhuang, J.; Thayumanavan, S. “Templated Self-Assembly of a Covalent Polymer Network for Intracellular Protein Delivery and Traceless Release\u201d J. Am. Chem. Soc. <\/em>2017<\/strong>, 139,<\/em> 5676\u20135679<\/a>. (DOI: 10.1021\/jacs.7b01214)
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188)<\/a>

Khomein, P.; Thayumanavan, S. \u201cEffect of Incorporating Flat Aromatic Molecules on Spherical Polymeric Nanoparticles\u201d Chem. Commun. <\/em>2017<\/strong>, 53,<\/em> 5190-5192<\/a>. (DOI: 10.1039\/C7CC00963A)
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Zhuang, J.; Garzoni, M.; Torres, D. A.; Poe, A.; Pavan, P. M.; Thayumanavan, S. \u201cProgrammable Nanoassemblies from Non-Assembling Homopolymers Using Ad\u2005Hoc Electrostatic Interactions\u201d Angew. Chem. Int. Ed. <\/em>2017<\/strong>, 56,<\/em> 4145\u20134149<\/a>. (DOI: 10.1002\/anie.201611688) <\/p>\n<\/div><\/div>

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Serrano, M. A. C.; He, H.; Zhao, B.; Ramireddy, R. R.; Vachet, R. W.; Thayumanavan, S. \u201cPolymer-Mediated Ternary Supramolecular Interactions for Sensitive Detection of Peptides\u201d Analyst <\/em>2017<\/strong>, 142,<\/em> 118\u2013122<\/a>. (DOI: 10.1039\/C6AN01591C) <\/p>\n<\/div><\/div>

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Homyak, C.; Anson. F.; Thayumanavan, S. \u201cSupramolecular Polymers in Nanomedicine\u201d Comprehensive Supramolecular Chemistry II, 2016, Elsevier Inc. Ed. J. W. Atwood<\/a>. (DOI: 10.1016\/B978-0-12-409547-2.12566-1) <\/p>\n<\/div><\/div>

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Liu, X.; Ding, H.; Jiang, Z.; Zhuang, J.; Xu, Y.; Guo, X.; Thayumanavan, S. \u201cMulti-Stimuli-Responsive Amphiphilic Assemblies through Simple Postpolymerization Modifications\u201d Macromolecules <\/em>2016<\/strong>, 49,<\/em> 6186\u20136192<\/a>. (DOI: 10.1021\/acs.macromol.6b01397) <\/p>\n<\/div><\/div>

180)<\/a>

Bai, W.; Jiang, Z.; Ribbe, A. E.; Thayumanavan, S. \u201cSmart Organic Two-Dimensional Materials Based on a Rational Combination of Non-covalent Interactions\u201d Angew. Chem. Int. Ed. <\/em>2016<\/strong>, 55,<\/em> 10707\u201310711<\/a>. (DOI: 10.1002\/anie.201605050) <\/p>\n<\/div><\/div>

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Munkhbat, O.; Garzoni, M.; Raghupathi, K. R.; Pavan, G. M.; Thayumanavan, S. \u201cRole of Aromatic Interactions in Temperature-Sensitive Amphiphilic Supramolecular Assemblies\u201d Langmuir <\/em>2016<\/strong>, 32,<\/em> 2874\u20132881<\/a>. (DOI: 10.1021\/acs.langmuir.5b04540)
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Wang, H.; Zhuang, J.; Raghupathi, K. R.; Thayumanavan, S. \u201cA Supramolecular Dissociation Strategy for Protein Sensing\u201d Chem. Commun. <\/em>2015<\/strong>, 51,<\/em> 17265\u201317268<\/a>. (DOI: 10.1039\/C5CC07408H) <\/p>\n<\/div><\/div>

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Prasad, P.; Molla, M. R.; Cui, W.; Canakci, M.; Osborne, B.; Mager, J.; Thayumanavan, S. \u201cPolyamide Nanogels from GRAS Components and Their Toxicity in Mouse Pre-implantation Embryos\u201d Biomacromolecules <\/em>2015<\/strong>, 16,<\/em> 3491\u20133498<\/a>. (DOI: 10.1021\/acs.biomac.5b00900) <\/p>\n<\/div><\/div>

175)<\/a>

Li, L.; Yuan, C.; Chen, D.; Ribbe, A. E.; Kittilstved, K. Thayumanavan, S. \u201cUtilizing Reversible Interactions in Polymeric Nanoparticles to Generate Hollow Metal Organic Nanoparticles\u201d Angew. Chem. Int. Ed. <\/em>2015<\/strong>, 54,<\/em> 12991\u201312995<\/a>. (DOI: 10.1002\/anie.201505242) <\/p>\n<\/div><\/div>

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Ventura, J.; Eron, S. J.; Gonz\u00e1lez-Toro, D. C.; Raghpathi, K. R.; Wang, F.; Hardy, J. A.; Thayumanavan, S. \u201cReactive Self-Assembly of Polymers and Proteins to Reversibly Silence a Killer Protein\u201d Biomacromolecules <\/em>2015<\/strong>, 16,<\/em> 3161\u20133171<\/a>. (DOI: 10.1021\/acs.biomac.5b00779) <\/p>\n<\/div><\/div>

172)<\/a>

Bell, N. C.; Doyle, S. J.; Battistelli, G.; LeGuyader, C. L. M.; Thompson, M. P.; Poe, A.; Montalti, M.; Thayumanavan, S.; Tauber, M. J.; Gianneschi, N. C. \u201cDye Encapsulation in Polybornene Micelles\u201d Langmuir <\/em>2015<\/strong>, 31,<\/em> 9707\u20139717<\/a>. (DOI: 10.1021\/acs.langmuir.5b01822) <\/p>\n<\/div><\/div>

171)<\/a>

Ramireddy, R. R.; Prasad, P.; Fine, A.; Thayumanavan, S. \u201cZwitterionic Amphiphilic Homopolymer Assemblies\u201d Polym. Chem. <\/em>2015<\/strong>, 6,<\/em> 6083-6087<\/a>. (DOI: 10.1039\/C5PY00879D) <\/p>\n<\/div><\/div>

170)<\/a>

Molla, M. R.; Prasad, P.; Thayumanavan, S. \u201cProtein\u2010Induced Supramolecular Disassembly of Amphiphilic Polypeptide Nanoassemblies\u201d J. Am. Chem. Soc. <\/em>2015<\/strong>, 137,<\/em> 7286-7289<\/a>. (DOI: 10.1021\/jacs.5b04285) (R,S)\"170\"<\/p>\n<\/div><\/div>

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Raghupathi, K. R.; Sridhar, U.; Byrne, K.; Raghupathi, K. R.; Thayumanavan, S. “Influence of Backbone Conformational Rigidity in Temperature-Sensitive Amphiphilic Supramolecular Assemblies” J. Am. Chem. Soc. <\/em>2015<\/strong>, 137, <\/em>5308-5311<\/a> (DOI: 10.1021\/jacs.5b02108). (R, S)\"168\"<\/a><\/p>\n<\/div><\/div>

167)<\/a>

Wang, Hui; Raghupathi, K.; Zhuang, J.; Thayumanavan, S. “Activatable Dendritic 19F Probes for Enzyme Detection” ACS Macro Letters, <\/em>2015<\/strong>, 4, <\/em>422-425 <\/a>(DOI: 10.1021\/acsmacrolett.5b00199). (R, S)\"167\"<\/a><\/p>\n<\/div><\/div>

165)<\/a>

Yuan, C.; Chang, Y.; Mao, J.; Yu, S.; Luo, W.; Xu, Y.; Thayumanavan, S.; Dai, L. \u201cSupramolecular Assembly of Crosslinkable Monomers for Degradable and Fluorescent Polymer Nanoparticles\u201d J. Mater. Chem. B.<\/em> , 2015<\/strong>, 2858-2866<\/a>\u00a0\u00a0(DOI: 10.1039\/c4tb01880j).\u00a0\u00a0(R,S)<\/p>\n

\"165\"<\/a><\/p>\n

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163)<\/a>

Molla, M. R.; Rangadurai, P.; Pavan, G. M.; Thayumanavan, S. \u201cExperimental and Theoretical Investigations in Stimuli Responsive Dendrimer-based Assemblies\u201d Nanoscale, 2015<\/strong>, 7, <\/em>3817-3837 <\/a>(DOI: 10.1039\/C4NR04563G). (R,S)<\/p>\n

\"163\"<\/a><\/p>\n<\/div><\/div>

162)<\/a>

Molla, M. R.; Marcinko, T.; Prasad, P.; Deming, D.; Garman, S.; Thayumanavan, S. \u201cUnlocking a Caged Lysosomal Protein from a Polymeric Nanogel with a pH Trigger\u201d Biomacromolecules, 2014<\/strong>, 15<\/em>, 4046-4053<\/a> (DOI: 10.1021\/bm501091p). (R,S)<\/p>\n

\"162\"<\/a><\/p>\n<\/div><\/div>

161)<\/a>

Li, L.; Thayumanavan, S. \u201cEnvironment-Dependent Guest-Exchange in Supramolecular Hosts\u201d\u00a0Langmuir<\/em>, 2014<\/strong>, 30<\/em>, 12384-12390<\/a>\u00a0(DOI: 10.1021\/la502760c). (R,S)<\/p>\n

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160)<\/a>

Li, L.; Yuan, C.; Dai, L.; Thayumanavan, S. “Thermo-responsive Polymeric Nanoparticles: Nucleation from Cooperative Polymerization Driven by Dative Bonds”\u00a0Macromolecules, 2014<\/strong>, 47<\/em>, 5869-5876<\/a>\u00a0(DOI: 10.1021\/ma5015808). (R,S)<\/p>\n

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158)<\/a>

Li, L; Raghupathi, K. R.; Song, C.; Prasad, P.; Thayumanavan, S. \u201cSelf-assembly of Random Copolymers\u201d \u00a0Chem. Commun., 2014, 50, 13417-13432<\/a>, (Invited Review),\u00a0DOI: 10.1039\/C4CC03688C.\u00a0(S)<\/p>\n

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156)<\/a>

Raghupathi, K.; Guo, J.; Munkhbat, O.; Rangadurai, P.; Thayumanavan, S. \u201cSupramolecular Assembly and Disassembly of Facially Amphiphilic Dendrimers\u201d\u00a0Acc. Chem. Res. 2014<\/strong>,\u00a047<\/em>, 2200-2211 (Invited Review)<\/a>\u00a0\u00a0(DOI: 10.1021\/ar500143u)\u00a0(PMCID# PMC4100797).\u00a0(R,S)<\/p>\n

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155)<\/a>

Amado Torres, D.; Garzoni, M.; Subrahmanyam, A.; Pavan, G. M.; Thayumanavan, S. <\/i>“Protein-Triggered Supramolecular Disassembly: Insights Based on Variations in Ligand Location in Amphiphilic Dendrons” J. Am. Chem. Soc. <\/i>2014<\/b>, 136<\/i>, 5385-5399.<\/a> (DOI:<\/strong> 10.1021\/ja500634u ) (R,S) \"155\"<\/a><\/p>\n<\/div><\/div>

153)<\/a>

Guo, J.; Zhuang, J.; Wang, F.; Raghupathi, K.; Thayumanavan, S. “Protein AND Enzyme Gated Supramolecular Disassembly” \u00a0J. Am. Chem. Soc.<\/em> 2014<\/strong>, 136<\/em>, 2220-2223<\/a>\u00a0\u00a0\u00a0(DOI: 10.1021\/ja4108676) (R,S).\u00a0<\/span><\/p>\n

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150)<\/a>

Zhuang, J.; Chacko, R.; Amado Torres, D.; Wang, H.; Thayumanavan, S. “Dual Stimuli \u2013 Dual Response Nanoassemblies Prepared from a Simple Homopolymer” ACS Macro Lett. <\/i>2014<\/b>, 3<\/i>, 1-5<\/a> (DOI: 10.1021\/mz400515s) (R,S).<\/p>\n

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149)<\/a>

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Raghupathi, K.; Li, L.; Ventura, J.; Jennings, M.; Thayumanavan, S. \u201cpH Responsive Soft Nanoclusters with Size and Charge Conversional Features\u201d Polym. Chem. <\/i>2014<\/b>, 5<\/i>, 1737-1742.<\/a> (DOI:10.1039\/C3PY01277H) (R,S)<\/p>\n

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148)<\/a>

Yuan, C.; Raghupathi, K.; Popere, B. C.; Ventura, J.; Dai, L.; Thayumanavan, S. \u201cComposite Supramolecular Nanoassemblies with Independent Stimulus Sensitivities”\u00a0 Chem. Sci.<\/i> 2014<\/b>, 5<\/i>, 229-234.<\/a> (DOI:10.1039\/C3SC52347K) (R,S)<\/p>\n

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\"148\"<\/a><\/p>\n<\/div><\/div>

147)<\/a>

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Wang, H.; Zhuang, J.; Thayumanavan, S. \u201c“Functionalizable Amine-based Polymer Nanoparticles” <\/span>ACS Macro Lett. <\/span>2013<\/span><\/b>, 2<\/i>, 948-951.<\/span><\/a> (DOI: <\/strong>10.1021\/mz4004248) (R,S)<\/span><\/p>\n

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146)<\/a>

Wang, F.; Gomez-Escudero, A.; Ramireddy, R. R.; Murage, G.; Thayumanavan, S.; Vachet, R. W. \u201cElectrostatic Control of Peptide Side-Chain Reactivity using Amphiphilic Homopolymer-based Supramolecular Assemblies\u201d J. Am. Chem. Soc. 2013<\/b>, 135<\/i>, 14179-14188.<\/a> (DOI: 10.1021\/ja404940s) (S)<\/p>\n

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145)<\/a>

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Ramireddy, R.; Subrahmanyam, A.; Thayumanavan, S. “Zwitterionic Moieties from the Huisgen Reaction-A Case Study with Amphiphilic Dendritic Assemblies”\u00a0Chem. Eur. J., 2013<\/strong>, 19<\/em>, 16374-16381<\/a>.\u00a0(S)<\/p>\n

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144)<\/a>

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Li, L.; Raghupathi, K.; Yuan, C.; Thayumanavan, S. \u201cSurface Charge Generation in Nanogels for Activated Cellular Uptake at Tumor-Relevant pH\u201d <\/span>Chem. Sci. 2013<\/b>, 4<\/em>, 3654-3660.<\/a> (DOI: 10.1039\/C3SC50899D) <\/span>(R,S)\"144\"<\/a><\/p>\n

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143)<\/a>

Fuller, J.; Raghupathi, K.; Ramireddy, R. R.; Subrahmanyam, A.; Yesilyurt, V.; Thayumanavan, S. \u201cTemperature-Sensitive Transitions Below LCST in Amphiphilic Dendritic Assemblies \u2013 Host-Guest Implications\u201d\u00a0J. Am. Chem. Soc.<\/em> 2013<\/strong>, 135, <\/em>8947-8954.<\/a> (DOI: 10.1021\/ja402019c) (R,S)
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142)<\/a>

Zhuang, J.; Gordon, M.; Ventura, J.; Li, L. Thayumanavan, S. \u201cMulti-Stimuli Responsive Macromolecules and Their Assemblies\u201d Chem. Soc. Rev.<\/i> 2013<\/b>, 42<\/em>, 7421-7435.<\/a><\/span> (DOI: 10.1039\/C3CS60094G) (R, S)
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138)<\/a>

Bickerton, S.; Jiwpanich, S.; Thayumanavan, S. \u201cInterconnected Roles of Scaffold Hydrophobicity, Drug Loading and Encapsulation Stability in Polymeric Nanocarriers\u201d Mol. Pharm.<\/em> 2012<\/strong>, 9<\/em>, 3569-3578.<\/a> (DOI: 1021\/mp3004226) (R, S)
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137)<\/a>

Siripornnopakhun, W.; Niamnont, N.; Krumsri, A.; Tumcharern, G.; Vilaivan, T.; Rashatasakhon, P.; Thayumanavan, S.; Sukwattanasinitt, M. \u201cInclusion Complexes between Amphiphilic Phenylene-Ethynylene Fluorophores and Cyclodextrins in Aqueous Media\u201d J. Phys. Chem. B.<\/em> 2012<\/strong>, 116<\/em>, 12268-12274. <\/a> (DOI: 10.1021\/jp3057652) (S)
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132)<\/a>

Amado Torres, D.; Azagarsamy, M.; Thayumanavan, S. \u201cSupramolecular Displacement-Mediated Activation of a Silent Fluorescence Probe for Label-free Ligand Screening\u201d J. Am. Chem. Soc.<\/em> 2012<\/strong>, 134<\/em>, 7235-7237.<\/a> (DOI: 10.1021\/ja301204z) (S)
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Ramireddy, R.; Raghupathi, K. R.; Torres, D. A.; Thayumanavan, S. \u201cStimuli Sensitive Amphiphilic Dendrimers\u201d New J. Chem.<\/em> 2012<\/strong>, 26<\/em>, 340-349. (Invited Perspective).<\/a> (DOI: 10.1039\/C2NJ20879B) (S)
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Rodthongkum, N.; Ramireddy, R.; Thayumanavan, S.; Vachet, R. W. \u201cSelective Enrichment and Sensitive Detection of Peptide and Protein Biomarkers in Human Serum Using Polymeric Reverse Micelles and MALDI-MS\u201d Analyst<\/em> 2012<\/strong>, 137<\/em>, 1024-1030.<\/a> (DOI: 10.1039\/C2AN16089G) (S)
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Yesilyurt, V.; Ramireddy, R.; Azhagarsamy, M. A.; Thayumanavan, S. “Accessing Lipophilic Ligands in Dendrimer-based Amphiphilic Supramolecular Assemblies for Protein-Induced Disassembly” Chem. Eur. J.<\/em> 2012<\/strong>, 18<\/em>, 223-229.<\/a> (DOI:\u00a010.1002\/chem.201102727) (S)
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Wang, F.; Klaikherd, A.; Thayumanavan, S. “Temperature Sensitivity Trends and Multi-Stimuli-Sensitive Behavior in Amphiphilic Oligomers\u201d J. Am. Chem. Soc.<\/em> 2011<\/strong>, 133<\/em>, 13496-13503.<\/a> (DOI: <\/strong>10.1021\/ja204121a) (S)
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Raghupathi, K. R.; Azagasarmy, M. A.; Thayumanavan, S. \u201cGuest Release Control in Enzyme-Sensitive Amphiphilic Dendrimer-based Nanoparticles through Photochemical Crosslinking\u201d Chem. Eur. J.<\/em> 2011<\/strong>, 17<\/em>, 11752-11760. <\/a> (DOI:\u00a010.1002\/chem.201101066) (S)
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119)<\/a>

Nagamani, C.; Viswanathan, U.; Versek, C.; Tuominen, M.; Auerbach, S. M.; Thayumanavan, S. \u201c”Importance of Dynamic Hydrogen Bonds and Reorientation Barriers in Proton Transport” Chem. Commun.<\/em> 2011<\/strong>, 47<\/em>, 6638-6640<\/a>. (DOI: 10.1039\/C1CC11207D) <\/span>(E, S)
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Yesilyurt, V.; Ramireddy, R.; Thayumanavan, S. \u201cPhoto-Regulated Release of Non-covalent Guests from Dendritic Amphiphilic Nanocontainers\u201d <\/strong>Angew. Chem. It. Ed.<\/em> 2011<\/strong>, 50<\/em>, 3038-3042.<\/a> (DOI:\u00a010.1002\/anie.201006193) (S)
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Jiwpanich, S.; Ryu, J.-H.; Bickerton, S.; Thayumanavan, S. \u201cNoncovalent Encapsulation Stability in Supramolecular Nanoassemblies” J. Am. Chem. Soc.<\/em> 2010<\/strong>, 132<\/em>, 10683-10685.<\/a> (DOI: <\/strong>10.1021\/ja105059g) (R, S)
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Rodthongkum, N.; Chen, Y.; Thayumanavan, S.; Vachet, R. W. \u201cSelective Enrichment and Analysis of Acidic Peptides and Proteins Using Polymeric Reverse Micelles and MALDI-MS\u201d Anal. Chem.<\/em> 2010<\/strong>, 82<\/em>, 8686-8691.<\/a> (DOI: <\/strong>10.1021\/ac101922b) (S)
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Rodthongkum, N.; Chen, Y.; Thayumanavan, S.; Vachet, R. W. \u201cMALDI-MS Signal Enhancement of Peptides after Selective Extraction with Polymeric Reverse Micelles\u201d Anal. Chem.<\/em> 2010<\/strong>, 82<\/em>, 3686-3691.<\/a> (DOI: <\/strong>10.1021\/ac1000256) (S)
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Azagarsamy, M.; Yesilyurt, V.; Thayumanavan, S. “Disassembly of Dendritic Micellar Containers due to Protein Binding” J. Am. Chem. Soc.<\/em> 2010<\/strong>, 132<\/em>, 4550-4551.<\/a> (DOI: <\/strong>10.1021\/ja100746d) (S)<\/p>\n

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106)<\/a>

Chen, Y.; Thorn, M.; Christensen, S.; Versek, C.; Poe, A.; Hayward, R. C.; Tuominen, M. T.; Thayumanavan, S. \u201cEnhancement of Anhydrous Proton Transport by Supramolecular Nanochannels in Comb Polymers\u201d Nature Chem.<\/em> 2010<\/strong>, 2<\/em>, 503-508.<\/a> (DOI: 10.1038\/nchem.629) (E, S)<\/p>\n

\"\"<\/a><\/p>\n<\/div><\/div>

104)<\/a>

Ryu, J.; Roy, R.; Ventura, J.; Thayumanavan, S. \u201cRedox-Sensitive Disassembly of Amphiphilic Copolymer Based Micelles\u201d Langmuir<\/em>, 2010<\/strong>, 26<\/em>, 7086-7092.<\/a> (DOI: <\/strong>10.1021\/la904437u) (S)
\n\"\"<\/a><\/p>\n<\/div><\/div>

102)<\/a>

Azagarsamy, M.; Krishnamoorthy, K.; Sivanandan, K.; Thayumanavan, S. \u201cSite-specific Installation and Study of Electroactive Units in Every Layer of Dendrons\u201d J. Org. Chem.<\/em> 2009<\/strong>, 74<\/em>, 9475-9485.<\/a> (DOI: <\/strong>10.1021\/jo902109u) (S)
\n\"\"<\/a><\/p>\n<\/div><\/div>

101)<\/a>

Azagarsamy, M.; Sokkalingam, P.; Thayumanavan, S. \u201cEnzyme Triggered Disassembly of Dendrimer-based Amphiphilic Nanocontainers\u201d J. Am. Chem. Soc.<\/em> 2009<\/strong>, 131<\/em>, 14184-14185.<\/a> (DOI:<\/strong> <\/strong>10.1021\/ja906162u) (S)
\n\"\"<\/a><\/p>\n<\/div><\/div>

100)<\/a>

Azagarsamy, M.; Thayumanavan, S. \u201cMagnetic Resonance Imaging: Making Sense of Disassembly\u201d Nature Chemistry<\/em>, 2009<\/strong>, 1<\/em>, 523-524.<\/a> (DOI<\/abbr>:10.1038\/nchem.383) <\/span>(S)
\n\"\"<\/a><\/p>\n<\/div><\/div>

98)<\/a>

Chen, Y.; Thayumanavan, S. \u201cAmphiphilicity in Homopolymer Surfaces Reduces Non-specific Protein Adsorption\u201d Langmuir, 2009<\/strong>, 25, 13795-13799 (Invited manuscript for the 25th year anniversary of Langmuir).<\/a> (DOI<\/abbr>: <\/span><\/strong>10.1021\/la901692a) (S)
\n\"\"<\/a><\/p>\n<\/div><\/div>

96)<\/a>

Rodthongkum, N.; Washington, J. D.; Savariar, E. N.; Thayumanavan, S.; Vachet, R. W. \u201cGenerating Peptide Titration-type Curves Using Polymeric Reverse Micelles as Selective Extraction Agents Along with MALDI-MS Detection\u201d Anal. Chem.<\/em> 2009<\/strong>, 81<\/em>, 5046-5053.<\/a> (DOI<\/abbr>:<\/span> <\/strong>10.1021\/ac900661e) (S)
\n\"\"<\/a><\/p>\n<\/div><\/div>

95)<\/a>

Kale, T.; Klaikherd, A.; Popere, B.; Thayumanavan, S. \u201cSupramolecular Assemblies of Amphiphilic Homopolymers\u201d Langmuir<\/em>, 2009<\/strong>, 25<\/em>, 9660-9670 (Invited Feature Article).<\/a> (DOI<\/abbr>:<\/span>10.1021\/la900734d) <\/strong>(S)<\/p>\n

\"\"<\/a><\/p>\n<\/div><\/div>

94)<\/a>

Gonz\u00e1lez, D. C; Savariar, E. N.; Thayumanavan, S. \u201cFluorescence Patterns from Supramolecular Polymer Assembly and Disassembly for Sensing of Metallo- and Non-metalloproteins\u201d J. Am. Chem. Soc. 2009<\/strong>, 131, 7708-7716.<\/a> <\/em>(DOI<\/abbr>: <\/span><\/strong>10.1021\/ja900579g) (S)<\/p>\n

\"\"<\/a><\/p>\n<\/div><\/div>

93)<\/a>

Azagarsamy, M.A.; Gomez-Escudero, A.; Yesilyurt, V.; Vachet, R.W.; Thayumanavan, S. \u201cAmphiphilic Nanoassemblies for the Detection of Peptides and Proteins Using Fluorescence and Mass Spectrometry\u201d Analyst<\/em>, 2009<\/strong>, 134<\/em>, 635-649 (Invited Review).<\/a> (DOI<\/abbr>: <\/span><\/strong>10.1039\/B818484D) <\/span>(S)
\n\"\"<\/a><\/p>\n<\/div><\/div>

90)<\/a>

Jiwpanich, S.; Sandanararj, B. S.; Thayumanavan, S. \u201cFluorophore-Cored Dendrimers for Patterns in Metalloprotein Sensing\u201d Chem. Commun.<\/em> 2009<\/strong>, 806-808.<\/a> (DOI<\/abbr>: 1<\/span>0.1039\/B815263B) <\/span>(S)
\n\"\"<\/a><\/p>\n<\/div><\/div>

88)<\/a>

Savariar, E. N.; Kopelman, J.; Thayumanavan, S. \u201cSupramolecular Assemblies from Amphiphilic Dendrons for Sensing Metalloproteins Through Pattern Generation\u201d Israel J. Chem. 2009<\/strong>, 49, 41-47 (Invited article).<\/a> (DOI:\u00a010.1560\/IJC.49.1.41) (S)
\n\"\"<\/a><\/p>\n<\/div><\/div>

86)<\/a>

Gomez-Escudero, A.; Azagarsamy, M.A.; Theddu, N.; Vachet, R.W.; Thayumanavan, S. \u201cSelective Peptide Binding Using Facially Amphiphilic Dendrimers\u201d J. Am. Chem. Soc.<\/em> 2008<\/strong>, 130<\/em>, 11156-11163.<\/a> (DOI: <\/strong>10.1021\/ja803082v) (S)
\n\"\"<\/a><\/p>\n<\/div><\/div>

85)<\/a>

Savariar, E. N.; Ghosh, S.; Gonz\u00e1lez, D. C.; Thayumanavan, S. \u201cDisassembly of Noncovalent Amphiphilic Polymers with Proteins and Utility in Pattern Sensing\u201d J. Am. Chem. Soc.<\/em> 2008<\/strong>, 130<\/em>, 5416-5417<\/a>.\u00a0 (DOI: <\/strong>10.1021\/ja800164z) (R, S)
\n\"\"<\/a><\/p>\n<\/div><\/div>

84)<\/a>

Savariar, E.N.; Krishnamoorthy, K.; Thayumanavan, S. \u201cMolecular Discrimination Inside Polymer Nanotubules\u201d Nature Nanotech.<\/em> 2008<\/strong>, 3<\/em>, 112-117.<\/a> (DOI: 10.1038\/nnano.2008.6) <\/span><\/strong>(S)
\n\"\"<\/a><\/p>\n<\/div><\/div>

83)<\/a>

Klaikherd, A.; Ghosh, S.; Thayumanavan, S. \u201cA Facile Method for the Synthesis of Cleavable Block Copolymers from ATRP-based Homopolymers\u201d Macromolecules,<\/em> 2007<\/strong>, 40<\/em>, 8518-8520.<\/a> (DOI: <\/strong>10.1021\/ma071852n) (R, S)
\n\"\"<\/a><\/p>\n<\/div><\/div>

82)<\/a>

Combariza, Y.; Savariar, E. N.; Vutukuri, D. R; Thayumanavan, S.; Vachet, R. W. \u201cPolymeric Inverse Micelles as Selective Peptide Extraction Agents for MALDI-MS Analysis\u201d Anal. Chem.<\/em> 2007<\/strong>, 79<\/em>, 7124-7130.<\/a> (DOI: <\/strong>10.1021\/ac071001d) <\/strong>(S)
\n\"\"<\/a><\/p>\n<\/div><\/div>

81)<\/a>

Ambade, A.; Aathimanikandan, S. V.; van der Poll, D.; Thayumanavan, S. \u201cSmaller Building Blocks Form Larger Assemblies: Aggregation Behavior of Biaryl-based Dendritic Facial Amphiphiles\u201d J. Org. Chem.<\/em> 2007<\/strong>, 72<\/em>, 8167-8174.<\/a> (DOI: 10.1021\/jo070447r) (S)
\n\"\"<\/a><\/p>\n<\/div><\/div>

78)<\/a>

Ambade, A.; Chen, Y.; Thayumanavan, S. \u201c”Controlled Functional Group Presentations in Dendrimers as a Tool to Probe the Hyperbranched Architecture” New J. Chem. 2007<\/strong>, 31, 1052-1063 (invited review)<\/a>. (DOI: 10.1039\/B617628C) (S)<\/p>\n

\"\"<\/a><\/p>\n<\/div><\/div>

77)<\/a>

Sandanaraj, B. S.; Demont, R.; Thayumanavan, S. \u201cGenerating Patterns for Sensing Using a Single Receptor Scaffold\u201d J. Am. Chem. Soc. 2007<\/strong>, 129, 3506-3507.<\/a> <\/em> (DOI: <\/strong>10.1021\/ja070229f) (S)
\n\"\"<\/a><\/p>\n<\/div><\/div>

76)<\/a>

Sandanaraj, B. S.; Bayraktar, H.; Krishnamoorthy, K.; Knapp, M. J.; Thayumanavan, S. \u201cRecognition and Modulation of Cytochrome c<\/em>‘s Redox Properties using an Amphiphilic Homopolymer\u201d Langmuir<\/em>, 2007<\/strong>, 23<\/em>, 3891-3897.<\/a> (DOI: <\/strong>10.1021\/la063063p) (S)
\n\"\"<\/a><\/p>\n<\/div><\/div>

75)<\/a>

Ambade, A. V.; Savariar, E. N.; Thayumanavan, S. \u201cDendritic Nanostructures for Cancer Therapy\u201d Nanotechnology for Cancer Therapy<\/em>, 2007<\/strong>, 509-521. (invited review).<\/a> (DOI: 10.1201\/9781420006636.ch26) (R, S)<\/p>\n<\/div><\/div>

74)<\/a>

Krishnamoorthy, K.; Reddy, D. R.; Nantalaksakul, A.; Thayumanavan, S. \u201cProbing the Periphery of Dendrimers by Heterogeneous Electron Transfer\u201d Chem. Commun.<\/em> 2007<\/strong>, 739-741.<\/a> (DOI: 10.1039\/B614236B)\u00a0(S)
\n\"\"<\/a><\/p>\n<\/div><\/div>

73)<\/a>

Arumugam, S.; Vutukuri, D. R.; Thayumanavan, S.; Ramamurthy, V. \u201cA Styrene Based Water Soluble Polymer as a Reaction Medium for Photodimerization of Aromatic Hydrocarbons in Water\u201d J. Photochem. Photobiol. A: Chem.<\/em> 2007<\/strong>, 185<\/em>, 168-171.<\/a> (DOI: 10.1016\/j.jphotochem.2006.05.032) (S)
\n\"\"<\/a><\/p>\n<\/div><\/div>

72)<\/a>

Ambade, A. V.; Sandanaraj, B. S.; Klaikherd, A.; Thayumanavan, S. \u201cFluorescent Polyelectrolytes as Protein Sensors\u201d Polymer International<\/em>, 2007<\/strong>, 56<\/em>, 474-481 (Invited review).<\/a> (DOI:\u00a010.1002\/pi.2185) (S)
\n\"\"<\/a><\/p>\n<\/div><\/div>

71)<\/a>

Rotello, V.; Thayumanavan, S. \u201cEditorial (Special issue on \u2018Recognition Mediated Self-Assembly of Polymers\u2019)\u201d Polymer International,<\/em> 2007<\/strong>, 56<\/em>, 435.<\/a> (DOI:\u00a010.1002\/pi.2288) (S)<\/p>\n<\/div><\/div>

70)<\/a>

Chen, Y.; Vutukuri, D. R.; Ambade, A. V.; Thayumanavan, S. \u201cSelf-Assembly of Facially Amphiphilic Dendrimers on Surfaces\u201d J. Am. Chem. Soc.<\/em> 2006<\/strong>, 128<\/em>, 14760-14761.<\/a> (DOI: 10.1021\/ja065625x) (S)
\n\"\"<\/a><\/p>\n<\/div><\/div>

69)<\/a>

Savariar, E. N.; Aathimanikandan, S. V.; Thayumanavan, S. \u201cSupramolecular Assemblies from Amphiphilic Homopolymers: Testing the Scope\u201d J. Am. Chem. Soc.<\/em> 2006<\/strong>, 128<\/em>, 16224-16230.<\/a> (DOI: 10.1021\/ja065213o) (S)
\n\"\"<\/a><\/p>\n<\/div><\/div>

67)<\/a>

Ghosh, S.; Basu, S.; Thayumanavan, S. \u201cSimultaneous and Reversible Functionalization of Copolymers for Biological Applications\u201d Macromolecules<\/em>, 2006<\/strong>, 39<\/em>, 5595-5597.<\/a> (DOI: 10.1021\/ma061420x) <\/strong>(R, S)
\n\"\"<\/a><\/p>\n<\/div><\/div>

66)<\/a>

Roy, R.; Sandanaraj, B. S.; Klaikherd, A.; Thayumanavan, S. \u201cTuning Substrate Selectivity of a Cationic Enzyme Using Cationic Polymers\u201d Langmuir,<\/em> 2006<\/strong>, 22<\/em>, 7695-7700.<\/a> (DOI: <\/strong>10.1021\/la060496j) (R, S)
\n\"\"<\/a><\/p>\n<\/div><\/div>

65)<\/a>

Sandanaraj, B. S.; Demont, R.; Aathimanikandan, S. V.; Savariar, E. N.; Thayumanavan, S. \u201cSelective Sensing of Metalloproteins from Non-selective Binding using a Fluorogenic Amphiphilic Polymer\u201d J. Am. Chem. Soc. 2006<\/strong>, 128, 10686-10687.<\/a> <\/em>(DOI: <\/strong>10.1021\/ja063544v) <\/strong>(S)
\n\"\"<\/a><\/p>\n<\/div><\/div>

63)<\/a>

Klaikherd, A.; Sandanaraj, B. S.; Vutukuri, D.; Thayumanavan, S. \u201cComparison of Facially Amphiphilic Biaryl Dendrimers with Classical Amphiphilic Ones Using Protein Surface Recognition as the Tool\u201d J. Am. Chem. Soc.<\/em> 2006<\/strong>, 128<\/em>, 9231-9237.<\/a> (DOI: <\/strong>10.1021\/ja0622406) (S)<\/p>\n

\"\"<\/a><\/p>\n<\/div><\/div>

60)<\/a>

Basu, S.; Vutukuri, D.; Thayumanavan, S. \u201cHomopolymer Micelles in Heterogeneous Solvent Mixtures\u201d J. Am. Chem. Soc.<\/em> 2005<\/strong>, 127<\/em>, 16794-16795.<\/a> (DOI: 10.1021\/ja056042a) (S)
\n\"\"<\/a><\/p>\n<\/div><\/div>

57)<\/a>

Arumugam, S.; Vutukuri, D. R.; Thayumanavan, S.; Ramamurthy, V. \u201cAmphiphilic Homopolymer as a Reaction Medium in Water: Product Selectivity Within Polymeric Nanopockets\u201d J. Am. Chem. Soc. 2005<\/strong>, 127, <\/a><\/em>13200-13206.<\/a> (DOI: <\/strong>10.1021\/ja051107v) (S)
\n\"\"<\/a><\/p>\n<\/div><\/div>

56)<\/a>

Aathimanikandan, S. V.; Savariar, E. N.; Thayumanavan, S. \u201cTemperature-Sensitive Dendritic Micelles\u201d J. Am. Chem. Soc.<\/em> 2005<\/strong>, 127<\/em>, 14922-14929.<\/a> (DOI: 10.1021\/ja054542y) (S)<\/p>\n

\"\"<\/a><\/p>\n<\/div><\/div>

55)<\/a>

Sandanaraj, B. S.; Vutukuri, D.; Simard, J.; Klaikherd, A.; Hong, R.; Rotello, V. M.; Thayumanavan, S. \u201cNon-Covalent Modification of Chymotrypsin Surface using Amphiphilic Polymeric Scaffold: Implications in Modulating Protein Function\u201d J. Am. Chem. Soc.<\/em> 2005<\/strong>, 127<\/em>, 10693-10698.<\/a> (DOI: 10.1021\/ja051947+) (S)
\n\"\"<\/a><\/p>\n<\/div><\/div>

54)<\/a>

Ambade, A.; Savariar, E. N.; Thayumanavan, S. \u201cDendrimeric Micelles for Controlled Drug Release and Targeted Delivery\u201d Mol. Pharm.<\/em> 2005<\/strong>, 2<\/em>, 264-272 (invited review)<\/a>. (DOI: 10.1021\/mp050020d) (S)
\n\"\"<\/a><\/p>\n<\/div><\/div>

53)<\/a>

Jiang, J.; Thayumanavan, S. \u201cSynthesis and Characterization of Amine-Functionalized Polystyrene Nanoparticles\u201d Macromolecules, 2005<\/strong>, 38, <\/a><\/em>5886-5891.<\/a> (DOI: 10.1021\/ma0507286) (S, R)
\n\"\"<\/a><\/p>\n<\/div><\/div>

52)<\/a>

Sivakumar, A. V.; Sandanaraj, B. S.; Arges, C. G.; Bardeen, C. J.; Thayumanavan, S. \u201cEffect of Guest Molecule Flexibility in Access to Dendritic Interiors\u201d Org. Lett.<\/em> 2005<\/strong>, 7<\/em>, 2809-2812.<\/a> (DOI: 10.1021\/ol050579b) (S)
\n\"\"<\/a><\/p>\n<\/div><\/div>

51)<\/a>

Sivanandan, K.; Aathimanikandan, S. V.; Arges, C. G.; Bardeen, C. J.; Thayumanavan, S. \u201cProbing Every Layer in Dendrons\u201d J. Am. Chem. Soc.<\/em>2005<\/strong>, 127<\/em>, 2020-2021.<\/a> (DOI: <\/strong>10.1021\/ja043356+) (S, E)
\n\"\"<\/a><\/p>\n<\/div><\/div>

49)<\/a>

Jayakumar, K. N.; Thayumanavan, S. \u201cComparison of AB2<\/sub> and AB4<\/sub> Monomers in Ferrocene-cored Benzyl Ether Dendrimers\u201d Tetrahedron<\/em>, 2005<\/strong>, 61<\/em>, 603-608.<\/a> (DOI: 10.1016\/j.tet.2004.11.002) (S)
\n\"\"<\/a><\/p>\n<\/div><\/div>

48)<\/a>

Vutukuri, D. R.; Basu, S.; Thayumanavan, S. \u201cDendrimers with both Polar and Apolar Nanocontainer Characteristics\u201d J. Am. Chem. Soc.<\/em> 2004<\/strong>, 126<\/em>, 15636-15637.<\/a> (DOI: 10.1021\/ja0449628) (S)
\n\"\"<\/a><\/p>\n<\/div><\/div>

47)<\/a>

Savariar, E. N.; Thayumanavan, S. \u201cControlled Polymerization of N<\/em>-isopropylacrylamide with an Activated Methacrylic Ester\u201d J. Poly. Sci. Part A: Poly. Chem.<\/em> 2004<\/strong>, 42<\/em>, 6340-6345.<\/a> (DOI:10.1002\/pola.20467) (S, R)<\/p>\n

\"\"<\/a><\/p>\n<\/div><\/div>

46)<\/a>

Basu, S.; Vutukuri, D.; Shyamroy, S.; Sandanaraj, B.S.; Thayumanavan, S. \u201cInvertible Amphiphilic Polymers\u201d J. Am. Chem. Soc.<\/em> 2004<\/strong>, 126<\/em>, 9890-9891.<\/a> (DOI: <\/strong>10.1021\/ja047816a) (S, R)<\/p>\n

\"\"<\/a><\/p>\n<\/div><\/div>

45)<\/a>

Jayakumar, K. N.; Thayumanavan, S. \u201cDendrimers Based on a Three-dimensionally Disposed AB4<\/sub> Monomer\u201d Org. Lett.<\/em> 2004<\/strong>, 6<\/em>, 2547-2550.<\/a> (DOI: 10.1021\/ol049147b) (S)
\n\"\"<\/a><\/p>\n<\/div><\/div>

44)<\/a>

Sivanandan, K.; Britto,S.S.; Thayumanavan, S. “Sequences in Dendrons and Dendrimers\u201d J. Org. Chem.<\/em> 2004<\/strong>, 69<\/em>, 2937-2944.<\/a> (DOI: 10.1021\/jo049878p) (S)<\/p>\n

\"\"<\/a><\/p>\n<\/div><\/div>

43)<\/a>

Thayumanavan, S.; Bharathi, P.; Sivanandan, K.; Vutukuri, D.R. \u201cTowards Dendrimers as Biomimetic Macromolecules\u201d Comptes Rendus Chimie, 2003<\/strong>, 6, 767-778 (invited review).<\/a> <\/em> (DOI: 10.1016\/j.crci.2003.08.007) (S)
\n\"\"<\/a><\/p>\n<\/div><\/div>

41)<\/a>

Vutukuri, D.; Sivanandan, K.; Thayumanavan, S. ” Synthesis of dendrimers with multifunctional periphery using an ABB\u2019 monomer” Chem. Commun. <\/em>2003<\/strong>, 796-797.<\/a> (DOI: 10.1039\/B212206P)<\/span> (S)
\n\"\"<\/a><\/p>\n<\/div><\/div>

40)<\/a>

Vutukuri, D.; Bharathi, P.; Yu, Z.; Rajasekaran, K.; Tran, M.-H.; Thayumanavan, S. “A Mild Deprotection Strategy for Allyl-Protecting Groups and Its Implications in Sequence Specific Dendrimer Synthesis” J. Org. Chem.<\/em> 2003<\/strong>, 68<\/em>, 1146-1149.<\/a>\u00a0 (DOI: 10.1021\/jo026469p) (S)
\n\"\"<\/a><\/p>\n<\/div><\/div>

39)<\/a>

Sivanandan, K.; Vutukuri, D.; Thayumanavan, S. “Functional Group Diversity in Dendrimers” Org. Lett.<\/em> 2002<\/strong>, 4<\/em>, 3751-3753.<\/a> (DOI: <\/strong>10.1021\/ol026746e) (S)
\n\"\"<\/a><\/p>\n<\/div><\/div>

38)<\/a>

Ganesh, R.N.; Shraberg, J.; Sheridan, P.G.; Thayumanavan, S. “Synthesis of Difunctionalized Dendrimers: An Approach to Main Chain Poly(dendrimers)” Tetrahedron Lett.<\/em> 2002<\/strong>, 43<\/em>, 7217-7220.<\/a> (DOI: 10.1016\/S0040-4039(02)01656-8) <\/strong>(S)
\n\"\"<\/a><\/p>\n<\/div><\/div>

36)<\/a>

Bharathi, P.; Zhao, H.; Thayumanavan, S. \u201cToward Globular Macromolecules with Functionalized Interiors: Design and Synthesis of Dendrons with an Interesting Twist\u201d Org. Lett.<\/em> 2001<\/strong>, 3<\/em>, 1961-1964.<\/a> (DOI: 10.1021\/ol016064b) (S)
\n\"\"<\/a><\/p>\n<\/div><\/div><\/div>\n","protected":false},"excerpt":{"rendered":"","protected":false},"author":21,"featured_media":0,"parent":5,"menu_order":1,"comment_status":"closed","ping_status":"closed","template":"","meta":{"footnotes":""},"class_list":["post-262","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"https:\/\/elements.chem.umass.edu\/thaigroup\/wp-json\/wp\/v2\/pages\/262","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/elements.chem.umass.edu\/thaigroup\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/elements.chem.umass.edu\/thaigroup\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/elements.chem.umass.edu\/thaigroup\/wp-json\/wp\/v2\/users\/21"}],"replies":[{"embeddable":true,"href":"https:\/\/elements.chem.umass.edu\/thaigroup\/wp-json\/wp\/v2\/comments?post=262"}],"version-history":[{"count":70,"href":"https:\/\/elements.chem.umass.edu\/thaigroup\/wp-json\/wp\/v2\/pages\/262\/revisions"}],"predecessor-version":[{"id":3382,"href":"https:\/\/elements.chem.umass.edu\/thaigroup\/wp-json\/wp\/v2\/pages\/262\/revisions\/3382"}],"up":[{"embeddable":true,"href":"https:\/\/elements.chem.umass.edu\/thaigroup\/wp-json\/wp\/v2\/pages\/5"}],"wp:attachment":[{"href":"https:\/\/elements.chem.umass.edu\/thaigroup\/wp-json\/wp\/v2\/media?parent=262"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}