2000-2009

      2009

    • 292) Kim, C.-K.; Ghosh, P.; Rotello, V. M. “Multimodal Drug Delivery Using Gold Nanoparticles”
      Nanoscale 2009, 1, 61-67.
    • 291) Erb, R. M.; Krebs, M. D.; Alsberg, E.; Samanta, B.; Rotello, V. M.; Yellen, B. B. “Beyond Diffusion-limited Aggregation Kinetics in Microparticle Suspensions”
      Phys. Rev. E 2009, 80, 051402.

    • 290) Zhu, Z.-J.; Rotello, V. M.; Vachet, R. W. “Engineered Nanoparticle Surfaces for Improved Mass Spectrometric Analyses”
      Analyst 2009, 134, 2183-2188.
    • 289) Rotello, V. M. “Sniffing out Cancer Using ‘Chemical Nose’ Sensors”
      Cell Cycle 2009, 8, 3615-3616.

    • 288) Jordan, B. J.; Hong, R.; Han, G.; Rana, S.; Rotello, V. M. “Modulation of Enzyme–substrate Selectivity using Tetraethylene Glycol Functionalized Gold Nanoparticles”
      Nanotechnology 2009, 20, 434004.

    • 287) Subramani, C.; Ofir, Y.; Patra, D.; Jordan, B. J.; Moran, I. W.; Park, M.-H.; Carter, K. R.; Rotello, V. M. “Nanoimprinted Polyethyleneimine: A Multimodal Template for Nanoparticle Assembly and Immobilization”
      Adv. Funct. Mater. 2009, 19, 2937-2942.

    • 286) Du, K.; Knutson, C. R.; Glogowski, E.; McCarthy, K. D.; Shenhar, R.; Rotello, V. M.; Tuominen, M. T.; Emrick, T.; Russell, T. P.; Dinsmore, A. D. “Self-Assembled Electrical Contact to Nanoparticles Using Metallic Droplets”
      Small 2009, 5, 1974-1977.
    • 285) De, M.; Rana, S.; Akpinar, H.; Miranda, O. R.; Arvizo, R. R.; Bunz, U. H. F.; Rotello, V. M. “Sensing of Proteins in Human Serum Using Conjugates of Nanoparticles and Green Fluorescent Protein”
      Nat. Chem. 2009, 1, 461-465.
      Article featured on the cover. Article featured in Chemistry World.

    • 284) Patra, D.; Pagliuca, C.; Subramani, C.; Samanta, B.; Agasti, S. S.; Zainalabdeen, N.; Caldwell, S. T.; Cooke, G.; Rotello, V. M. “Molecular Recognition at the Liquid–liquid Interface of Colloidal Microcapsules”
      Chem. Commun. 2009, 28, 4248-4250.
    • 283) Bajaj, A.; Miranda, O. R.; Kim, I.-B.; Phillips, R. L.; Jerry, D. J.; Bunz, U. H. F.; Rotello, V. M. “Detection and Differentiation of Normal, Cancerous, and Metastatic Cells Using Nanoparticle-polymer Sensor Arrays”
      Proc. Nat. Acad. Sci. U.S.A. 2009, 106, 10912-10916.

    • 282) Patra, D.; Ozdemir, F.; Miranda, O. R.; Samanta, B.; Sanyal, A.; Rotello, V. M. “Formation and Size Tuning of Colloidal Microcapsules via Host-Guest Molecular Recognition at the Liquid-Liquid Interface”
      Langmuir 2009, 25, 13852-13854.
    • 281) Bajaj, A.; Samanta, B.; Yan, H.; Jerry, D. J.; Rotello, V. M. “Stability, Toxicity and Differential Cellular Uptake of Protein Passivated-Fe3O4 Nanoparticles”
      J. Mater. Chem. 2009, 19, 6328-6331.
      Article featured on the cover.
    • 280) Samanta,B.; Yang, X.-C.; Ofir, Y.; Park, M.-H.; Patra, D.; Agasti, S. S.; Miranda, O. R.; Mo, Z.-H.; Rotello, V. M. “Catalytic Microcapsules Assembled from Enzyme-Nanoparticle Conjugates at Oil-Water Interfaces”
      Angew. Chem. Int. Ed. 2009, 48, 5341-5344.
    • 279) Rotello, V. M. “Hot and Sticky or Cold and Aloof”
      Nat. Mater. 2009, 8, 539-540.

    • 278) Park, M.-H.; Ofir, Y.; Samanta, B.; Rotello, V. M. “Robust and Responsive Dendrimer-gold Nanoparticle Nanocomposites via Dithiocarbamate Crosslinking”
      Adv. Mater. 2009, 21, 2323-2327.
    • 277) Krebs, M. D.; Erb, R. M.; Yellen, B. B.; Samanta, B.; Bajaj, A.; Rotello, V. M.; Alsberg, E. “Formation of Ordered Cellular Structures in Suspension via Label-Free Negative Magnetophoresis”
      Nano Lett. 2009, 9, 1812-1817.
    • 276) Agasti, S. S.; Chompoosor, A.; You, C.-C.; Ghosh, P.; Kim, C. K.; Rotello, V. M. “Photoregulated Release of Caged Anticancer Drugs from Gold Nanoparticles”
      J. Am. Chem. Soc. 2009, 131, 5728-5729.
    • 275) De, M.; Miranda, O. R.; Rana, S.; Rotello, V. M. “Size and Geometry Dependent Protein–nanoparticle Self-assembly”
      Chem. Commun. 2009, 16, 2157-2159.
    • 274) Samanta, B.; Patra, D.; Subramani, C.; Ofir, Y.; Yesilbag, G.; Sanyal, A.; Rotello, V.M. “Stable Magnetic Colloidosomes via “Click” Mediated Crosslinking of Nanoparticles at Water-oil Interfaces”
      Small 2009, 5, 685-688.
    • 273) Caldwell, S. T.; Farrugia, L. J.; Hewage, S. G.; Kryvokhyzha, N.; Rotello, V. M.; Cooke, G. “Model Systems for Flavoenzyme Activity: an Investigation of the Role Functionality Attached to the C(7) Position of the Flavin Unit has on Redox and Molecular Recognition Properties”
      Chem. Commun. 2009, 1350-1352.
    • 272) Carver, A. M.; De, M.; Bayraktar, H.; Rana, S.; Rotello, V. M.; Knapp, M. J. “Intermolecular Electron-Transfer Catalyzed on Nanoparticle Surfaces”
      J. Am. Soc. Chem. 2009, 131, 3798-3799.
    • 271) Samanta, B.; Ofir, Y.; Patra, D.; Rotello, V. M. “Self-assembly of Fluorocarbon-coated FePt Nanoparticles for Controlling Structure and Wettability of Surfaces”
      Soft Matter 2009, 5, 1247-1250.
    • 270) Erb, R. M.; Son, H. S.; Samanta, B.; Rotello, V. M.; Yellen, B. B. “Magnetic Assembly of Colloidal Superstructures with Multipole Symmetry”
      Nature 2009, 457, 999-1002.

    • 269) Yu, X.; Samanta, B.; Xu, H.; Arumugam, P.; Ofir, Y.; Jordan, B. j.; Rotello, V. M. “Fabrication and Functionalization of Supramolecular Microgel Arrays Through Complementary Hydrogen-Bonding Interactions”
      Small 2009, 5, 86-89.
    • 268) De, M.; Rana, S.; Rotello, V. M. “Nickel-Ion-Mediated Control of the Stoichiometry of His-Tagged Protein/Nanoparticle Interactions”
      Macromol. Biosci. 2009, 9, 174-178.
      Article featured on the cover.
    • 267) Phillips, R. L.; Miranda, O. R.; Mortenson, D. E.; Subramani, C.; Rotello, V. M.; Bunz, U. H. F. “Gold Nanoparticle-PPE Constructs as Biomolecular Material Mimics: Understanding the Electrostatic and Hydrophobic Interactions”
      Soft Matter 2009, 5, 607-612.
    • 266) Kim, C. K.; Ghosh, P.; Pagliuca, C.; Zhu, Z.-J.; Menichetti, S.; Rotello, V. M. “Entrapment of Hydrophobic Drugs in Nanoparticle Monolayers with Efficient Release into Cancer Cells”
      J. Am. Chem. Soc. 2009, 131, 1360-1361.
    • 265) Santore, M. A.; Zhang, J.; Srivastava, S.; Rotello, V. M. “Beyond Molecular Recognition: Using a Repulsive Field to Tune Interfacial Valency and Binding Specificity between Adhesive Surfaces”
      Langmuir 2009, 25, 84-96.
    • 264) Aniagyei, S. E.; Kennedy, C. J.; Stein, B.; Willits, D. A.; Douglas, T.; Young, M. J.; De, M.; Rotello, V. M., Srisathiyanarayanan, D.; Kao, C. C.; Dragnea, B. “Synergistic Effects of Mutations and Nanoparticle Templating in the Self-Assembly of Cowpea Chlorotic Mottle Virus Capsids”
      Nano Lett. 2009, 9, 393–398.
    • 263) Kim, I.-B.; Han, M. H.; Phillips, R. L.; Samanta, B.; Rotello, V. M.; Zhang, Z. J.; Bunz, U. H. F. “Nano-Conjugate Fluorescence Probe for the Discrimination of Phosphate and Pyrophosphate”
      Chem. Eur. J. 2009, 15, 449-456.

    • 262) Chen, H.-T.; Crosby, T. D.; Park, M.-H.; Nagarajan, S; Rotello, V. M.; Watkins, J. J. “Accessibility of Cylindrical Channels within Patterned Mesoporous Silica Films Using Nanoparticle Diffusion”
      J. Mater. Chem. 2009, 19, 70-71.
    • 2008

    • 261) Ghosh, P. S.; Kim, C.-K.; Han, G.; Forbes, N. S.; Rotello, V. M. “Efficient Gene Delivery Vectors by Tuning the Surface Charge Density of Amino Acid-Functionalized Gold Nanoparticles”
      ACS Nano 2008, 2, 2213-2218.
    • 260) You, C.-C.; Agasti, S. S.; Rotello, V. M. “Chemical and Biological Sensing Using Gold Nanoparticles”. From the Book:
      Nano and Microsensors for Chemical and Biological Terrorism Surveillance 2008, 29-59
      .
    • 259) Caldwell, S. T.; Cooke, G.; Fitzpatrick, B.; Long, D.-L.; Rabani, G.; Rotello, V. M. “A Flavin-based [2]Catenane”
      Chem. Commun. 2008, 45, 5912-5914.
    • 258) Bria, M.; Bigot, J.; Cooke, G.; Lyskawa, J.; Rabani, G.; Rotello, V. M.; Woisel, P. “Synthesis of a Polypseudorotaxane, Polyrotaxane, and Polycatenane Using ‘Click’ Chemistry”
      Tetrahedron 2008, 65, 400-407.
    • 257) De, M.; Ghosh, P. S.; Rotello, V. M. “Applications of Nanoparticles in Biology”
      Adv. Mater. 2008, 20, 4225-4241.
    • 256) Park, M-H.; Ofir, Y.; Samanta, B.; Arumugam, P.; Miranda, O. R.; Rotello, V. M. “Nanoparticle Immobilization on Surfaces via Activatable Heterobifunctional Dithiocarbamate Bond Formation”
      Adv. Mater. 2008, 20, 4185-4188.
    • 255) Jordan, B. J.; Ofir, Y.; Patra, D.; Caldwell, S. T.; Kennedy, A.; Joubanian, S.; Rabani, G.; Cooke, G.; Rotello, V. M. “Controlled Self-Assembly of Organic Nanowires and Platelets Using Dipolar and Hydrogen-Bonding Interactions”
      Small 2008, 4, 2074-2078.

    • 254) Zhu, Z.-J.; Ghosh, P.; Miranda, O. R.; Vachet, R. W.; Rotello, V. M. “Multiplexed Screening of Cellular Uptake of Gold Nanoparticles Using Laser Desorption/Ionization Mass Spectrometry”
      J. Am. Chem. Soc. 2008, 130, 14139-14143.
    • 253) Caldwell, S. T.; Cooke, G.; Hewage, S. G.; Mabruk, S.; Rabani, G.; Rotello, V. M.; Smith, B. O.; Subramani, C.; Woisel, P. “Model Systems for Flavoenzyme Activity: Intramolecular Self-assembly of a Flavin Derivativevia Hydrogen Bonding and Aromatic Interactions”
      Chem. Commun. 2008, 4126-4128.
    • 252) Agasti, S. S.; Caldwell, S. T.; Cooke, G.; Jordan, B. J.; Kennedy, A.; Kryvokhyzha, N.; Rabani, G.; Rana, S.; Sanyal, A.; Rotello, V. M. “Dendron-based Model Systems for Flavoenzyme Activity: Towards A New Class of Synthetic Flavoenzyme”
      Chem. Commun. 2008, 4123-4125.
    • 251) Ofir, Y.; Samanta B.; Rotello, V. M. “Polymer and Biopolymer Mediated Self-assembly of Gold Nanoparticle”
      Chem. Soc. Rev. 2008, 37, 1814-1825.
    • 250) Chompoosor, A.; Han, G.; Rotello, V. M. “Charge Dependence of Ligand Release and Monolayer Stability of Gold Nanoparticles by Biogenic Thiols”
      Bioconjugate Chem. 2008, 19, 1342-1345.
    • 249) Ghosh, P.; Han, G.; De, M.; Kim, C. K.; Rotello, V. M. “Gold Nanoparticles in Delivery Applications”
      Adv. Drug Deliv. Rev. 2008, 60, 1307-1315.

    • 248) Arumugam, P.; Patra, D.; Samanta, B.; Agasti, S. S.; Subramani, C.; Rotello, V. M. “Self-Assembly and Cross-linking of FePt Nanoparticles at Planar and Colloidal Liquid-Liquid Interfaces”
      J. Am. Chem. Soc. 2008, 130, 10046-10047.
    • 247) De, M.; Rotello, V. M. “Synthetic “Chaperones”: Nanoparticle-mediated Refolding of Thermally Denatured Proteins”
      Chem. Commun. 2008, 3504-3506.
    • 246) Ofir, Y.; Samanta, B.; Xiao, Q.; Jordan, B. J.; Xu, H.; Arumugam, P.; Arvizo, R.; Tuominen, M. T.; Rotello, V. M. “Polyelectrolyte Negative Resist Patterns as Templates for the Electrostatic Assembly of Nanoparticles and Electroless Deposition of Metallic Films”
      Adv. Mater. 2008, 20, 2561-2566.
    • 245) Zhang, J.; Srivastava, S.; Duffadar, R.; Davis, J. M.; Rotello, V. M.; Santore, M. M. “Manipulating Microparticles with Single Surface-Immobilized Nanoparticles”
      Langmuir 2008, 24, 6404-6408.
    • 244) McGrier, P. L.; Solntsev, K. M.; Miao, S.; Tolbert, L. M.; Miranda, O. R.; Rotello, V. M.; Bunz, U. H. F. “Hydroxycruciform: Amine-Responsive Fluorophores”
      Chem. Eur. J. 2008, 14, 4503-4510.

    • 243) Bayraktar, H.; Srivastava, S.; You, C.-C.; Rotello, V. M.; Knapp, M. J. “Controlled Nanoparticle Assembly through Protein Conformational Changes”
      Soft Matter 2008, 4, 751-756.
    • 242) Jordan, B. J.; Pollier, M. A.; Ofir, Y.; Joubanian, S.; Mehtala, J. G.; Sinkel, C.; Caldwell, S. T.; Kennedy, A.; Rabani, G.; Cooke, G.; Rotello, V. M. “Lock and Key’ Control of Optical Properties in A Push-pull System”
      Chem. Commun. 2008, 1653-1655.
    • 241) Richter, H.; McCarthy, K.; Nevin, K. P.; Johnson, J. P.; Rotello, V. M.; Lovley, D. R. “Electricity Generation by Geobacter sulfurreducens Attached to Gold Electrodes”
      Langmuir 2008, 24, 4376-4379.
    • 240) Phillips, R. L.; Miranda, O. R.; You, C.-C.; Rotello, V. M.; Bunz, U. H. F. “Rapid and Efficient Identification of Bacteria Using Gold-Nanoparticle-Poly(para-phenyleneethynylene) Constructs”
      Angew. Chem. Int. Ed. 2008, 47, 2590–2594.
    • 239) Samanta, B.; Yan, H.; Fischer, N. O.; Shi, J.; Jerry, D. J.; Rotello, V. M. “Protein-passivated Fe3O4 Nanoparticles: Low Toxicity and Rapid Heating for Thermal Therapy”
      J. Mater. Chem. 2008, 18, 1204-1208.
    • 238) Leroueil, P. R.; Berry, S. A.; Duthie, K.; Han, G.; Rotello, V. M.; McNerny, D. Q.; Baker, J. R., Jr.; Orr, B. G.; Banaszak Holl, M. M. “Wide Varieties of Cationic Nanoparticles Induce Defects in Supported Lipid Bilayers”
      Nano Lett. 2008, 8, 420-424.
    • 237) Ghosh, P. S.; Han, G.; Erdogan, B.; Rosado, O.; Rotello, V. M. “Binding of Nanoparticle Receptors to Peptide α-helices using Amino Acid-functionalized Nanoparticles”
      J. Pept. Sci. 2008, 14, 134-138.

    • 236) Agasti, S. S.; You, C-C.; Arumugam, P.; Rotello, V. M. “Structural Control of the Monolayer Stability of Water-soluble Gold Nanoparticles”
      J. Mater. Chem. 2008, 18, 70-73.
    • 235) You, C-C.; Agasti, S. S.; Rotello, V. M. “Isomeric Control of Protein Recognition with Amino Acid- and Dipeptide-Functionalized Gold Nanoparticles”
      Chem. Eur. J. 2008, 14, 143-150.

    • 2007

    • 234) Ofir, Y.; Samanta, B.; Arumugam, P.; Rotello, V. M. “Controlled Fluorination of FePt Nanoparticles: Hydrophobic to Superhydrophobic Surfaces”
      Adv. Mater. 2007, 19, 4075-4079.
    • 233) Cooke, G.; Daniels, L. M.; Cazier, F.; Garety, J. F.; Hewage, S. G.; Parkin, A.; Rabani, G.; Rotello, V. M.; Wilson, C. C.; Woisel, P. “The Synthesis of A Pyrrole-functionalized Cyclobis(paraquat-p-phenylene) Derivative and Its Corresponding [2]Rotaxane and [2]Catenane and Their Subsequent Deposition onto An Electrode Surface”
      Tetrahedron 2007, 63, 11114-11121.
    • 232) Srivastava, S.; Samanta, B.; Jordan, B. J.; Hong, R.; Xiao, Q.; Tuominen, M. T.; Rotello, V. M. “Integrated Magnetic Bionanocomposites through Nanoparticle-Mediated Assembly of Ferritin”
      J. Am. Chem. Soc. 2007, 129, 10776-11780.
    • 231) De, M.; You, C.-C.; Srivastava, S.; Rotello, V. M. “Biomimetic Interactions of Proteins with Functionalized Nanoparticles: A Thermodynamic Study”
      J. Am. Chem. Soc. 2007, 129, 10747-10753.
    • 230) Ghosh, P. S.; Han, G.; Erdogan, B.; Rosado, O.; Krovi, S. A.; Rotello, V. M. “Nanoparticles Featuring Amino Acid-functionalized Side Chains as DNA Receptors”
      Chem. Biol. Drug Des. 2007, 70, 13-18.

    • 229) Goicochea, N. L.; De, M.; Rotello, V. M.; Mukhopadhyay, S.; Dragnea, B. “Core-like Particles of an Enveloped Animal Virus Can Self-Assemble Efficiently on Artificial Templates”
      Nano Lett. 2007, 7, 2281-2290.
    • 228) Han, G.;Ghosh, P.; De, M.; Rotello V. M. “Drug and Gene Delivery Using Gold Nanoparticles”
      NanoBiotechnology 2007, 3, 40-45.

    • 227) Miranda, O. R.; You, C.-C.; Phillips, R.; Kim, I.-K.; Ghosh, P. S.; Bunz, U. H. F.; Rotello, V. M. “Array-Based Sensing of Proteins Using Conjugated Polymers”
      J. Am. Chem. Soc. 2007, 129, 9856-9857.
    • 226) Jordan, B. J.; Pollier, M. A.; Miller, L. A.; Tiernan, C.; Clavier, G.; Audebert, P.; Rotello, V. M. “Redox-Modulated Recognition of Tetrazines Using Thioureas”
      Org. Lett. 2007, 9, 2835-2838.
    • 225) Ghosh, P.; Verma, A.; Rotello, V. M. “Binding and Templation of Nanoparticle Receptors to Peptide α-Helices through Surface Recognition”
      Chem. Commun. 2007, 2796-2798.
    • 224) You, C-C.; Chompoosor, A.; Rotello, V. M. “The Biomacromolecule-nanoparticle Interface”
      Nano Today 2007, 2, 34-43.

    • 223) You, C-C.; Miranda, O. R.; Gider, B.; Ghosh, P. S.; Kim, IK-B.; Erdogan, B.; Krovi, S. A.; Bunz, U. H. F.; Rotello, V. M. “Detection and Identification of Proteins Using Nanoparticle–fluorescent Polymer ‘Chemical Nose’ Sensors”
      Nat. Nanotech. 2007, 2, 318-323.

    • 222) Xu, H.; Hong, R.; Wang, X.; Arvizo, R.; You, C-C; Samanta, B.; Patra, D.; Tuominen, M. T.; Rotello, V. M. “Controlled Formation of Patterned Gold Films via Site-selective Deposition of Nanoparticles onto Polymer-templated surfaces”
      Adv. Mater. 2007, 19, 1383-1386.
    • 221) Alexander, A-M.; Bria, M.; Brunklaus, G.; Caldwell, S.; Cooke, G.; Garety, J. F.; Hewage, S. G.; Hocquel, Y.; McDonald, N.; Rabani, G.; Rosair, G.; Smith, B. O.; Spiess, H. W.; Rotello, V. M.; Woisel, P. “Probing the Solvent-induced Tautomerism of a Redox-active Ureidopyrimidinone”
      Chem. Commun. 2007, 2246-2248.
    • 220) Fillon, Y.; Verma, A.; Ghosh, P.; Ernenwein, D.; Rotello, V. M.; Chmielewski, J. “Peptide Ligation Catalyzed by Functionalized Gold Nanoparticles”
      J. Am. Chem. Soc. 2007, 129, 6676-6677.
    • 219) Jordan, B. J.; Cooke, G.; Garety, J. F.; Pollier, M. A.; Kryvokhyzha, N.; Bayir, A.; Rabani, G.; Rotello, V.M. “Polymeric Model Systems for Flavoenzyme Activity: Towards Synthetic Flavoenzymes”
      Chem. Commun. 2007, 1248-1250.
    • 218) Arumugam, P.; Xu, H.; Srivastava, S.; Rotello, V. M. “‘Bricks and Mortar’ Nanoparticle Self-assembly Using Polymers”
      Polym. Int. 2007, 56, 461-466.

    • 217) Han, G.; Ghosh, P.; Rotello, V. M. “Functionalized Gold Nanoparticles for Drug Delivery”
      Nanomedicine 2007, 2, 113-123.

    • 216) Bayraktar, H.; You, C-C.; Rotello, V. M.; Knapp, M. J. “Facial Control of Nanoparticle Binding to Cytochrome C”
      J. Am. Chem. Soc. 2007, 129, 2732-2733.
    • 215) Sun, J.; DuFort, C.; Daniel, M.-C.; Murali, A.; Chen, C.; Gopinath, K.; Stein, B.; De, M.; Rotello, V. M.; Holzenburg, A.; Kao, C. C.; Dragnea, B. “Core-controlled Polymorphism in Virus-like Particles”
      Proc. Natl. Acad. Sci. USA 2007, 104, 1354-1359.

    • 214) Leduc, P. R.; Wong, M. S.; Ferreira, P. M.; Groff, R. E.; Haslinger, K.; Koonce, M. P.; Lee, W. Y.; Love, J. C.; McCammon, J. A.; Monteiro-Riviere, N. A.; Rotello, V. M.; Rubloff, G. W.; Westervelt, R.; Yoda, M. “Towards An in vivo Biologically Inspired Nanofactory”
      Nat. Nanotech. 2007, 2, 3-7.

    • 213) Cooke, G.; Garety, J. F.; Hewage, S. G.; Jordan, B. J.; Rabani, G.; Rotello, V. M.; Woisel, P. “Tuneable Side-Chain Supramolecular Polymer”
      Org. Lett. 2007, 9, 481-484.
    • 212) Srivastava, S.; Samanta, B.; Arumugam, P.; Han, G.; Rotello, V. M. “DNA-mediated Assembly of Iron Platinum (FePt) Nanoparticles”
      J. Mater. Chem. 2007, 17, 52-55.
    • 2006

    • 211) Nakade, H.; Jordan, B. J.; Xu, H.; Han, G.; Srivastava, S.; Arvizo, R. R.; Cooke, G.; Rotello, V. M. “Chiral Translation and Cooperative Self-Assembly of Discrete Helical Structures Using Molecular Recognition Dyads”
      J. Am. Chem. Soc. 2006, 128, 14924-14929.
    • 210) You, C.-C.; Agasti, S. S.; De, M.; Knapp, M. J.; Rotello, V. M. “Modulation of the Catalytic Behavior of a-Chymotrypsin at Monolayer-Protected Nanoparticle Surfaces”
      J. Am. Chem. Soc. 2006, 128, 14612-14618.
    • 209) Uzun, O.; Frankamp, B. L.; Sanyal, A.; Rotello, V. M. “Recognition-Mediated Assembly of Nanoparticle-Diblock Copolymer Micelles with Controlled Size”
      Chem. Mater. 2006, 18, 5404-5409.
    • 208) Norsten, T. B.; Guiver, M. D.; Murphy, J.; Astill, T.; Navessin, T.; Holdcroft, S.; Frankamp, B. L.; Rotello, V. M.; Ding, J. “Highly Fluorinated Comb-shaped Copolymers as Proton Exchange Membranes (PEMs): Improving PEM Properties through Rational Design”
      Adv. Funct. Mater. 2006, 16, 1814-1822.

    • 207) Cooke, G.; Garety, J. F.; Hewage, S. G.; Rabani, G.; Rotello, V. M.; Woisel, P. “The Tuneable Complexation of Gold Nanoparticles”
      Chem. Commun. 2006, 4119-4121.
    • 208) Bayir, A.; Jordan, B. J.; Verma, A.; Pollier, M. A.; Cooke, G.; Rotello, V. M. “Model Systems for Flavoenzyme Activity: Recognition and Redox Modulation of Flavin Mononucleotide in Water Using Nanoparticles”
      Chem. Commun. 2006, 4033-4035.
    • 207) Thibault, R. J.; Uzun, O.; Hong, R.; Rotello, V. M. “Recognition-controlled Assembly of Nanoparticles using Photochemically Crosslinked Recognition-induced Polymersomes”
      Adv. Mater. 2006, 18, 2179-2183.
    • 206) You, C-C.; Arvizo, R. R.; Rotello, V. M. “Regulation of α-Chymotrypsin Activity on the Surface of Substrate-Functionalized Gold Nanoparticles”
      Chem. Commun. 2006, 2905-2907.
    • 205) Dixit, S. K.; Goicochea, N. L.; Daniel, M-C.; Murali, A.; Bronstein, L.; De, M.; Stein, B.; Rotello, V. M.; Kao, C. C.; Dragnea, B. “Quantum Dot Encapsulation in Viral Capsids”
      Nano Lett. 2006, 6, 1993-1999.
    • 204) Vanderpuije, B. N. Y.; Han, G.; Rotello, V. M.; Vachet, R. W. “Mixed Monolayer-Protected Gold Nanoclusters as Selective Peptide Extraction Agents for MALDI-MS Analysis”
      Anal. Chem. 2006, 78, 5491-5496.

    • 203) Jordan, B. J.; Hong, R.; Gider, B.; Hill, J.; Emrick, T.; Rotello, V. M. “Stabilization of α-Chymotrypsin at Air–water Interface through Surface Binding to Gold Nanoparticle Scaffolds”
      Soft Matter 2006, 2, 558-560.
    • 202) Cooke, G.; Garety, J. F.; Jordan, B.; Kryvokhyzha, N.; Parkin, A.; Rabani, G.; Rotello, V. M.. “Flavin-Based [2]Rotaxanes”
      Org. Lett. 2006, 8, 2297-2300.
    • 201) Hong, R.; Fernandez, J. M.; Nakade, H.; Arvizo, R.; Emrick, T.; Rotello, V. M.. “In situ Observation of Place Exchange Reactions of Gold Nanoparticles. Correlation of Monolayer Structure and Stability”
      Chem. Commun. 2006, 2347-2349.
    • 200) Worrall, J. W. E.; Verma, A.; Yan, H.; Rotello, V. M. “‘Cleaning’ of Nanoparticle Inhibitors via Proteolysis of Adsorbed Proteins”
      Chem. Commun. 2006, 2338-2340.
    • 199) Han, G.; You, C.-C.; Kim, B.-j.; Turingan, R. S.; Forbes, N. S.; Martin, C. T.; Rotello, V. M.. “Light-regulated Release of DNA and its Delivery to Nuclei by Means of Photolabile Gold Nanoparticles”
      Angew. Chem. Int. Ed. 2006, 45, 3165-3169.
    • 198) Cooke, G.; Couet, J.; Garety, J. F.; Ma, C-Q.; Mabruk, S.; Rabani, G.; Rotello, V. M.; Sindelar, V.; Woisel, P. “The Electrochemically Tuneable Hydrogen Bonding Interactions between a Phenanthrenequinone-functionalized Self-assembled Monolayer and a Phenyl-urea Terminated Dendrimer”
      Tetrahedron Lett. 2006, 47, 3763-3766.
    • 197) Goodman, C. M.; Chari N. S; Han G.; Hong R.; Ghosh P.; Rotello V. M. “DNA-binding by Functionalized Gold Nanoparticles: Mechanism and Structural Requirements”
      Chem. Biol. Drug Des. 2006, 67, 297-304.

    • 196) Chen, C.; Daniel, M.-C.; Quinkert, Z. T.; De, M.; Stein, B.; Bowman, V. D.; Chipman, P. R.; Rotello, V. M.; Kao, C. C.; Dragnea, B. “Nanoparticle-Templated Assembly of Viral Protein Cages”
      Nano Lett. 2006, 6, 611-615.
    • 195) Xu, H.; Hong, R.; Lu, T.; Uzun, O.; Rotello. V. M. “Recognition-Directed Orthogonal Self-Assembly of Polymers and Nanoparticles on Patterned Surfaces”
      J. Am. Chem. Soc. 2006, 128, 3162-3163.
    • 194) Cooke, G.; Garety, J. F.; Mabruk, S.; Rabani, G.; Rotello, V. M.; Surpateanu, G.; Woisel, P. “The Electrochemical Polymerisation of A [2]Rotaxane”
      Tetrahedron Lett. 2006, 47, 783-786.
    • 193) You, C.-C.; Verma, A.; Rotello, V. M. “Engineering the Nanoparticle-Biomacromolecule Interface”
      Soft Matter 2006, 2, 190-204.
    • 192) Bayraktar, H.; Ghosh, P.; Rotello, V. M.; Knapp, M. J. “Disruption of Protein-Protein Interactions using Nanoparticles: Inhibition of Cytochrome c Peroxidase”
      Chem. Commun. 2006, 1390-1392.
    • 191) Frankamp, B. L.; Fischer, N. O.; Hong, R.; Srivastava, S.; Rotello, V. M. “Surface Modification Using Cubic Silsesquioxane Ligands. Facile Synthesis of Water-Soluble Metal Oxide Nanoparticles”
      Chem. Mater. 2006, 18, 956-959.
    • 190) Hong, R.; Han, G.; Kim, B.; Forbes, N. S.; Rotello, V. M. “Glutathione-Mediated Delivery and Release using Monolayer Protected Nanoparticle Carriers”
      J. Am. Chem. Soc. 2006, 128, 1078-1079.
    • 189) Han, G.; Martin, C. M.; Rotello, V. M. “Stability of Gold Nanoparticle-Bound DNA towards Biological, Physical and Chemical Agents”
      Chem. Biol. Drug Des. 2006, 67, 78-82.

    • 2005

    • 188) Verma, A.; Srivastava, S.; Rotello, V. M. “Modulation of the Interparticle Spacing and Optical Behavior of Nanoparticle Ensembles using a Single Protein Spacer”
      Chem. Mater. 2005, 17, 6317-6322.

    • 187) You, C.-C.; De, M.; Rotello, V. M. “Contrasting Effects of Exterior and Interior Hydrophobic Moieties in the Complexation of Amino Acid-Functionalized Gold Clusters with α-Chymotrypsin”
      Org. Lett. 2005, 7, 5685-5687.
    • 186) Shenhar, S.; Xu, H.; Frankamp, B. L.; Mates, T. E.; Sanyal, A.; Uzun, O.; Rotello, V. M. “Molecular Recognition in Structured Matrices: Control of Guest Localization in Block Copolymer Films”
      J. Am. Chem. Soc. 2005, 127, 16318-16324.
    • 185) You, C.-C. De, M.; Rotello, V. M. “Monolayer-Protected Nanoparticle-Protein Interactions”
      Curr. Opin. Chem. Biol. 2005, 9, 639-646.

    • 184) Han, G.; Chari, N. S.; Verma, A.; Hong, R.; Martin, C. T.; Rotello, V. M. “Controlled Recovery of the Transcription of Nanoparticle-Bound DNA by Intracellular Concentrations of Glutathione”
      Bioconjugate Chem. 2005, 16, 1356-1359.
    • 183) Xu, H.; Norsten, T. B.; Uzun, Jeoung, E.; Rotello, V. M. “Stimuli Responsive Surfaces through Recognition-Mediated Polymer Modification”
      Chem. Commun. 2005, 5157-5159.
    • 182) Uzun, U.; Xu, H.; Jeoung, E.; Thibault, R. J.; Rotello, V. M. “Recognition-Induced Polymersomes: Structure and Mechanism of Formation”
      Chem. Eur. J. 2005, 11, 6916-6920.

    • 181) Hong, R.; Fischer, N. O.; Emrick, T.; Rotello, V. M. “Surface PEGylation and Ligand Exchange Chemistry of FePt Nanoparticles for Biological Applications”
      Chem. Mater. 2005, 17, 10693-10698.
    • 180) Shenhar, R.; Jeoung, E.; Srivastava, S.; Norsten, T. B.; Rotello, V. M. “Cross-Linked Nanoparticle Stripes and Hexagonal Networks Obtained Via Selective Patterning of Block Copolymer Thin Films”
      Adv. Mater. 2005, 17, 2206-2210.
    • 179) You, C-C.; De, M.; Han, G.; Rotello, V. M. “Tunable Inhibition and Denaturation of α-Chymotrypsin with Amino Acid-Functionalized Gold Nanoparticles”
      J. Am. Chem. Soc. 2005,127, 12873-12881.
    • 178) Carroll, J. B.; Cooke, G.; Garety, J. F.; Jordan, B. J.; Mabruk, S ; Rotello, V. M. “The Electrochemically-Tuneable Interactions Between Flavin-Functionalised C(60) Derivatives and 2,6-Diethylamidopyridine”
      Chem. Commun. 2005, 3838-3840.
    • 177) Sandanaraj, B. S.; Vutukuri D. H.; Simard, J. M.; Khalikerd, A.; Hong, R.; Rotello, V. M.; Thayumanavan, S. “Non-Covalent Modification of Protein Surface using Amphiphilic Polymeric Scaffold – Implications in Modulating Protein Function”
      J. Am. Chem. Soc. 2005, 127, 10693-10698.
    • 176) Frankamp, B. L.; Boal, A. K.; Tuominen, M. T.; Rotello, V. M. “Direct Control of the Magnetic Interaction Between Superparamagnetic Nanoparticles Using Dendrimer Mediated Self-Assembly”
      J. Am. Chem. Soc. 2005, 127, 9731-9735.
    • 175) Nakade, H.; Ilker, M. F.; Uzun, O.; LaPointe, N. L.; Coughlin, E. B.; Rotello V. M. “Duplex Strand Formation Using Alternating Copolymers”
      Chem. Commun. 2005, 3271-3273.
    • 174) Carroll, J. B.; Jordan, B. J.; Xu, H.; Erdogan,. B.; Lee, L.; Cheng, L.; Tiernan, C.; Cooke, G.; Rotello, V. M. “Model Systems for Flavoenzyme Activity: Site Isolated Redox Behavior in Flavin Functionalized Random Polystyrene Copolymers”
      Org. Lett. 2005, 7, 10693-10698.
    • 173) Simard, J. M.; Szymanski, B.; Rotello, V. M. “Control of Substrate Selectivity through Complexation and Release of Chymoptrypsin from Gold Nanoparticle Surfaces”
      J. Biomed. Nanotech. 2005, 1, 341-344.

    • 172) Boyd, A. S. F.; Carroll, J. B.; Cooke, G.; Garety, J. F.; Jordan, B. J.; Mabruk, S.; Rosair, G.; Rotello, V. M. “Model systems for Flavoenzyme Activity: A Tuneable Intramolecularly Hydrogen Bonded Flavin-Diamidopyridine Complex”
      Chem. Commun. 2005, 2468-2470.
    • 171) McCusker, C.; Carroll, J. B.; Rotello, V. M. “Cationic Polyhedral Oligomeric Silsesquioxane (POSS) Units as Carriers for Drug Delivery Processes”
      Chem. Commun. 2005, 996-998.
    • 170) Simard, J. M.; Szymanski, B.; Rotello, V. M. “Reversible Regulation of Chymotrypsin Activity Using Negatively Charged Gold Nanoparticles featuring Malonic Acid Termini”
      Med. Chem. 2005, 1, 153-158.

    • 169) Shenhar, R.; Norsten, T. B.; Rotello, V. M. “Polymer-Mediated Nanoparticle Assembly: Structural Control and Applications”
      Adv. Mater. 2005, 17, 657-669.

    • 168) Srivastava, S.; Frankamp, B. L.; Rotello, V. M. “Controlled Plasmon Resonance of Gold Nanoparticles Self-Assembled with PAMAM Dendrimers”
      Chem. Mater. 2005, 17, 487-490.
    • 167) Foster, P.; Lahti, P.M.; Carroll, J. B.; Rotello, V. M. “Molecular Recognition In a Uradinyl-Functionalized Stable Radical”
      Chem. Commun. 2005, 895-897.
    • 166) Arvizo, R.; Verma. A.; Rotello, V.M. “Biomacromolecule Surface Recognition Using Nanoparticle Receptors”
      Supramol. Chem. 2005, 17, 155-161.

    • 165) Srivastava, S.; Verma, A.; Frankamp, B. L.; Rotello, V. M.; “Controlled Assembly of Protein-Nanoparticle Composites through Protein Surface Recognition”
      Adv. Mater. 2005, 617-621.
    • 164) Verma, A.; Rotello, V.M. “Surface Recognition of Biomacromolecules Using Nanoparticle Receptors”
      Chem. Commun. 2005, 301-312.

    2004

  • 163) Uzun, O.; Sanyal, A.; Nakade, H.; Thibault, R. J. Rotello, V. M. “Recognition-Induced Transformation of Microspheres into Vesicles: Morphology and Size Control”
    J. Am. Chem. Soc. 2004, 126, 14773-14777.
  • 162) Cooke, G.; Mabruk, S.; Rotello, V. M.; Surpateanu, G.; Woisel, P. “The Electrochemically Tuneable Recognition Properties of an Electropolymerised Flavin Derivative”
    Chem. Commun. 2004, 2722-2723.
  • 161) Hong, R.; Emrick, T.; Rotello, V. “Monolayer-Controlled Substrate Selectivity Using Non-Covalent Enzyme-Nanoparticle Conjugates”
    J. Am. Chem. Soc. 2004, 126, 13572-13573.
  • 160) Fischer, N.; Paulini, R.; Drechsler, U.; Rotello, V. “Light-Induced Inhibition of Chymotrypsin Using Photocleavable Monolayers on Gold Nanoparticles”
    Chem. Commun. 2004, 2866-2867.
  • 159) Verma, A.; Simard, J. M.; Worrall, J. W. E.; Rotello, V. M. “Tunable Reactivation of Nanoparticle-Inhibited β-Galactosidase by Glutathione at Intracellular Concentrations”
    J. Am. Chem. Soc. 2004, 126, 13987-13991.
  • 158) Verma, A.; Nakade, H.; Simard, J.M.; Rotello, V. M. “Recognition and Stabilization of Peptide α-Helices Using Templatable Nanoparticle Receptors”
    J. Am. Chem. Soc. 2004, 126, 10806-10807.
  • 157) Carroll, J. B.; Gray, M.; Bardon, K. M.; Nakade, H. Rotello, V. M. “Multivalent Recognition of Flavin Derivatives Using Polymer Scaffolds”
    Lett. Org. Chem. 2004, 227-233.
  • 156) Drechsler, U.; Erdogan, B.; Rotello, V. M. “Nanoparticles: Scaffolds for Molecular Receptors”
    Chem. Eur. J. 2004, 10, 5570-5579.
  • 155) Boal, A. K.; Frankamp, B. L.; Uzun, O.; Tuominen, M. T.; Rotello, V. M. “Modulation of Spacing and Magnetic Properties of Iron Oxide Nanoparticles through Polymer-Mediated ‘Bricks and Mortar’ Self-Assembly”
    Chem. Mater. 2004, 16, 3252-3256.
  • 154) Goodman, C. M.;McCusker, C. D.; Yilmaz, T.; Rotello, V. M. “Toxicity of Gold Nanoparticles Functionalized with Cationic and Anionic Sidechains”
    Bioconjugate Chem. 2004, 15, 897-900.
  • 153) Sanyal, A.; Norsten, T. B.; Uzun, O.; Rotello, V. M. “Adsorption/Desorption of Mono- and Diblock Copolymers on Surfaces Using Specific Hydrogen Bonding Interactions”
    Langmuir 2004, 20, 5958-5964.
  • 152) Cooke, G.; Legrand, Y.-M., Rotello, V. M. “Model Systems for Flavoenzyme Activity: An Electrochemically Tuneable Model of Roseoflavin”
    Chem. Commun. 2004, 1088-1090.
  • 151) Shenhar, R.; Sanyal, A.; Uzun, O.; Nakade, H.; Rotello, V. M. “Integration of Recognition Elements with Macromolecular Scaffolds: Effects on Polymer Self-Assembly in the Solid-State”
    Macromolecules 2004, 37, 4931-4939.
  • 150) Verma, A.; Simard, J. M.; Rotello, V.M. “Effect of Ionic Strength on the Binding of α-Chymotrypsin to Nanoparticle Receptors”
    Langmuir 2004, 20, 4178-4181.
  • 149) Gray, M.; Goodman, A. J.; Carroll, J. B.; Bardon, K.; Markey, M.; Cooke, G.; Rotello, V. “Model Systems for Flavoenzyme Activity: Interplay of Hydrogen Bonding and Aromatic Stacking in Cofactor Redox Modulation”
    Org Lett. 2004, 6, 385-388.
  • 148) Carroll, J. B.; Gray, M.; Cooke, G.; Rotello, V. M. “Proton Transfer versus Redox Modulation in Thiourea-Phenanthrenequinone Molecular and Polymeric Complexes”
    Chem. Commun. 2004, 442-443.
  • 147) Carroll, J. B.; Frankamp, B. L.; Srivastava, S.; Rotello, V. M. “Electrostatic Self-Assembly of Structured Gold Nanoparticle-Polyhedral Oligomeric Silsesquioxanes (POSS) Nanocomposites”
    J. Mater. Chem. 2004, 14, 690-694.
  • 146) Thibault, R. J.; Rotello, V.M. “Molecular Recognition-Mediated Assembly of Polymers”
    Encyclopedia of Polymer Science & Technology, Mark, H. ed, Wiley: New York, 2004.
  • 145) Goodman, C. M.; Frankamp, B. L.; Cooper, B. M.; Rotello, V. M. “Surfactant Layering on Mixed Monolayer-Protected Gold Clusters”
    Colloids Surf., B 2004, 39, 119-123.
  • 144) Norsten, T.; Sanyal, A.; Shenhar, R,; Rotello, V.M. “Polymer-Mediated Self-Assembly of Nanoparticles”
    Encyclopedia of Nanoscience and Nanotechnology, Nalwa, H.S. ed., Dekker: New York, 2004, 2985-2998.
  • 143) Thibault, R. J.; Rotello, V. M. “Recognition-Mediated Assembly of Polymers”
    Polymer News 2004, 29, 40-49.
  • 142) Das, K.; Nakade, H.; Pennelle, J.; Rotello, V. M., “Synthesis and Recognition Properties of Polymers Containing Embedded Binding Sites”
    Macromolecules 2004, 37, 310-314.
  • 141) Shenhar, R.; Sanyal, A.; Uzun, O.; Rotello, V. M. “Anthracene-Functionalized Polystyrene Random Copolymers: Effects of Side-Chain Modification on Polymer Structure and Behavior”
    Macromolecules 2004, 37, 92-98.
  • 140) Drechsler, U.;Fischer, N. O.; Frankamp, B. L.; Rotello, V. M. “Highly Efficient Biocatalysts via Covalent Immobilization of Candida rugosa Lipase on Ethylene Glycol Modified Gold-Silica Nanocomposites”
    Adv. Mater. 2004, 16, 271-274.
  • 139) Hong, R.; Fischer, N. O.; Verma, A.; Goodman, C. M.; Emrick, T. S.; Rotello, V. M. “Control of Protein Structure and Function through Surface Recognition by Tailored Nanoparticle Scaffolds”
    J. Am. Chem. Soc. 2004, 126, 739-743.
  • 138) Butterfield, S. M.; Goodman, C. M.; Rotello, V. M.; Waters, M. L. “A Peptide Flavoprotein Mimic: Flavin Recognition and Redox Potential Modulation in Water by a Designed β-Hairpin”
    Angew. Chem. 2004, 43, 724-727.
  • 137) Cooke, G.; Duclairoir, F. M. A.; Kraft, A.; Rosair, G.; Rotello, V. M. “Pronounced Stabilisation of the Ferrocenium State of Ferrocenecarboxylic Acid by Salt Bridge Formation with a Benzamidine”
    Tetrahedron Lett. 2004, 557-560.
  • 136) Goodman, C. M.; Rotello, V. “Biomacromolecule Surface Recognition Using Nanoparticles”
    Mini-Rev. Org. Chem. 2004, 1, 103-114.
  • 135) Sanyal, A.; Norsten, T. B.; Rotello, V.M. “Nanoparticle-Polymer Ensembles”
    Nanoparticles: Building Blocks for Nanotechnology, Rotello, V. M., ed., Kluwer: New York, 2004, 201-224.
  • 2003

  • 134) Cooke, G.; Duclairoir, M. A.; John, P.; Polwart, N.; Rotello, V. M. “Model Systems for Flavoenzyme Activity: Flavin-Functionalised SAMs as Models for Probing Redox Modulation through Hydrogen Bonding”
    Chem. Commun. 2003, 2468-2469.
  • 133) Legrand, Y.-M.; Gray, M.; Cooke, G.; Rotello, V. “Model Systems for Flavoenzyme Activity. Relationships between Cofactor Structure, Binding and Redox Properties”
    J. Am. Chem. Soc. 2003, 125, 15789-15793.
  • 132) Carroll, J. B.; Waddon, A.J.; Nakade, H.; Rotello, V. M. “’Plug and Play’ Polymers. Thermal and X-ray Characterizations of Noncovalently-Grafted Polyhedral Oligomeric Silsesquioxane (POSS)-Polystyrene Nanocomposites”
    Macromolecules 2003, 36, 6289-6291.
  • 131) Bryce, M.R.; Cooke, G.; Duclairoir, F. M. A.; John, P.; Perepichka, D. F.; Polwart, N.; Rotello, V. M.; Stoddart, J. F.; Tseng, H. R. “Surface Confined Pseudorotaxanes with Electrochemically Controllable Complexation Properties”
    J. Mater. Chem. 2003, 13, 2111-2117.
  • 130) Norsten, T. B.; Jeoung, E,; Thibault, R. J.; Rotello, V. M. “Specific Hydrogen Bond-Mediated Recognition and Modification of Surfaces using Complementary Functionalized Polymers”
    Langmuir 2003, 19, 7089-7093.
  • 129) Fischer, N. O.; Verma, A.; Goodman, C. M. Simard, J. M.; Rotello, V. M. “Reversible ‘Irreversible’ Inhibition of Chymotrypsin Using Nanoparticle Receptors”
    J. Am. Chem. Soc. 2003, 125, 13387-13391.
  • 128) Carroll, J. B.; Gray, M.; McMenimen, K. A.; Hamilton, D. G.; Rotello, V. M. “Redox Modulation of Benzene Triimides and Diimides via Non-Covalent Interactions”
    Org. Lett. 2003, 5, 3177-3180.
  • 127) Cooke, G.; de Cremiers, H. A.; Duclairoir, F. M. A.; Leonardi, J.; Rosair, G.; Rotello, V. M. “Ferrocene Incorporating Host-Guest Dyads with Electrochemically Controlled Three-Pole Hydrogen Bonding Properties”
    Tetrahedron 2003, 3341-3347.
  • 126) Thibault, R. J.; Hotchkiss, P. Gray, M.; Rotello, V. M. “Thermally Reversible Formation of Microspheres through Non-Covalent Polymer Crosslinking”
    J. Am. Chem. Soc. 2003, 125, 11249-11252.
  • 125) Shenhar, S.; Rotello, V. M. “Nanoparticles: Scaffolds and Building Blocks”
    Acc. Chem. Res. 2003, 36, 549-561.
  • 124) Das, K.; Pennelle, J.; Nüsslein, K.; Rotello, V. M. “Specific Recognition of Bacteria by Surface-Templated Polymer Films”
    Langmuir 2003, 19, 6226-6229.
  • 123) Gray, M.; Cuello, A.; Cooke, G.; Rotello, V. “Hydrogen Bonding in Redox-Modulated Molecular Recognition.
    An Experimental and Theoretical Investigation”
    J. Am. Chem. Soc. 2003, 125, 7882-7888.
  • 122) Das, K.; Pennelle, J.; Rotello, V. M. “Picomolar Detection of Polychlorinated Aromatic Contaminants in Water Using a Quartz Crystal Microbalance Coated with a Molecularly Imprinted Polymer Thin Film”
    Langmuir 2003, 19, 3921-3925.
  • 121) Boyd, A. S. F.; Cooke, G., Duclairoir F. M. A., Rotello V.M. “An Investigation of the Role of the Disparate Redox States of the Tetrathiafulvalene Unit in Modulating Hydrogen Bonding Interactions in Solution”
    Tetrahedron Lett. 2003, 303-306.
  • 120) Cooke, G.; Sindelar, V.; Rotello, V. M. “Electrochemically Tuneable Hydrogen Bonding Interactions between a Phenyl-Urea Terminated Dendrimer and Phenanthrenequinone”
    Chem. Commun. 2003, 752-753.
  • 2002

  • 119) Jeoung, E.; Rotello, V. M. “Photochemical Control of Molecular Recognition on Self-Assembled Monolayer-Protected Gold Clusters”
    J. Supramol. Chem. 2002, 2, 53-55.
  • 118) Beeby, A.; Bryce, M. R.; Christensen, C. A.; Cooke, G.; Duclairoir, F. M. A.; Rotello, V. M. “Electrochemically Controlled Interactions between TTF-Based Dendrimers and an Electron-Rich Oligomer”
    Chem. Commun. 2002, 2950-2951.
  • 117) Drechsler, U.; Thibault, R. J. ; Rotello, V. M. “Formation of Recognition-Induced Polymersomes Using Complementary Rigid Random Copolymers”
    Macromolecules 2002, 35, 9621-9623.
  • 116) Norsten,T.; Rotello, V. M. “Metal Directed Assembly of Terpyridine-Functionalized Gold Nanoparticles”
    Nano Lett. 2002, 2, 1345-1348.
  • 115) Thibault, R.; Galow, T.; Turnberg, E.; Gray, M.; Hotchkiss, P.; Rotello, V. M. “Specific Interactions of Complementary Mono- and Multivalent Guests with Recognition-Induced Polymersomes”
    J. Am. Chem. Soc. 2002, 124, 15249-15254.
  • 114) Frankamp, B. L.; Boal,, A. K.; Rotello, V. M. “Controlled Interparticle Spacing through Self-Assembly Of Au Nanoparticles And Poly(Amidoamine) Dendrimers”
    J. Am. Chem. Soc. 2002, 124, 15146-15147.
  • 113) Galow, T.; Fuller, N.; Cohen, C.; Rotello, V. M. “Flavin Mononucleotide as a Probe for Dopant Encapsulation in Sol-Gel Silicates”
    Langmuir 2002, 18, 9149-9152.
  • 112) Drechsler, U.; Rotello, V. “The Interplay Between Redox and Recognition Processes: Models and Devices”
    Adv. Phys. Org. Chem. 2002, 37, 315-337.
  • 111) Carroll, J. B.; Frankamp, B. L.; Rotello, V. M. “Self-Assembly of Gold Nanoparticles through Tandem Hydrogen Bonding and Polyoligosilsequioxane (POSS)-POSS Recognition Processes”
    Chem. Commun. 2002, 1892-1893.
  • 110) Briggs, C.; Norsten, T. B.; Rotello, V. M. “Inhibition and Acceleration of Deuterium Exchange in Amide- Functionalized Monolayer-Protected Gold Clusters”
    Chem. Commun. 2002, 1890-1891.
  • 109) Jeoung, E.; Carroll, J. B.; Rotello, V. M. “Surface Modification via ‘Lock and Key’ Specific Self-Assembly of Polyhedral Oligomeric Silsequioxane (POSS) Derivatives to Modified Gold Surfaces”
    Chem. Commun. 2002, 1510-1511.
  • 108) Duffy, D. J.; Das, K.; Hsu, S. L.; Penelle, J.; Rotello, V. M.; Stidham, H. D. “Binding Efficiency and Transport Properties of Molecularly Imprinted Polymer Thin Films”
    J. Am. Chem. Soc. 2002, 124, 8290-8296.
  • 107) Credo, G. M.; Boal, A. K.; Das, K.; Galow, T. H.; Rotello, V. M.; Feldheim, D. L.; Gorman, C. B. “Supramolecular Assembly on Surfaces: Manipulating Conductance in Noncovalently Modified Mesoscale Structures”
    J. Am. Chem. Soc. 2002, 124, 9036-9037.
  • 106) Cooke, G.; Rotello, V. M. “Methods of Modulating Hydrogen Bonded Interactions in Synthetic Host-Guest Systems”
    Chem. Soc. Rev. 2002, 31, 275-286.
  • 105) Galow, T. H.; Drechsler, U.; Hanson, J. A.; Rotello, V. M. “Highly Reactive Heterogeneous Heck and Hydrogenation Catalysts Constructed Through ‘Bottom-Up’ Nanoparticle Self-Assembly”
    Chem. Commun. 2002, 1076-1077.
  • 104) Fischer, N. O.; McIntosh, C. M.; Simard, J. M.; Rotello, V. M. “Inhibition of Chymotrypsin through Surface Binding Using Nanoparticle-Based Receptors”
    Proc. Natl. Acad. Sci. USA 2002, 99, 5018-5023.
  • 103) Boal, A. K.; Das, K.; Gray, M.; Rotello, V. M. “Monolayer Exchange Chemistry of γ-Fe2O3 Nanoparticles”
    Chem. Mater. 2002, 14, 2628-2636.
  • 102) Boal, A. K.; Rotello, V. M. “Radial Control of Recognition and Redox Processes with Multivalent Nanoparticle Hosts”
    J. Am. Chem. Soc. 2002, 124, 5019-5024.
  • 101) Paulini, R.; Frankamp, B. L.; Rotello, V. M. “Effects of Branched Ligands on the Structure and Stability of Monolayers on Gold Nanoparticles”
    Langmuir 2002, 18, 2368-2373.
  • 100) Rotello, V. M. “Recognition-Mediated Self-Assembly of Organic Systems – Preface”
    Tetrahedron 2002, 58(4), XI-XI.
  • 99) Boal, A. K.; Gray, M.; Ilhan, F.; Clavier, G. M.; Kapitzky, L.; Rotello, V. M. “Bricks and Mortar Self-Assembly of Nanoparticles”
    Tetrahedron 2002, 58, 765-770.
  • 98) Sandhu, K. K.; McIntosh, C. M.; Simard, J. M.; Smith, S. W.; Rotello, V. M. “Gold Nanoparticle-Mediated Transfection of Mammalian Cells”
    Bioconjugate Chem. 2002, 13, 3-6.
  • 97) Frankamp, B. L.; Uzun, O.; Ilhan, F.; Boal, A. K.; Rotello, V. M. “Recognition-Mediated Assembly of Nanoparticles into Micellar Structures with Diblock Copolymers”
    J. Am. Chem. Soc. 2002, 124, 892-893.
  • 2001

    • 96) Boal, A. K.; Galow, T. H.; Ilhan, F.; Rotello, V. M. “Binary and Ternary Polymer-mediated “Bricks and Mortar” Self-assembly of Gold and Silica Nanoparticles”
      Adv. Funct. Mater. 2001, 11, 461-465.
    • 95) Rotello, V.M. “Nanoparticles Building Blocks”
      Mater. Today 2001, 24-29.
    • 94) de Cremiers, H. A.; Clavier, G.; Ilhan, F.; Cooke, G.; Rotello, V. M. “Tuneable Electrochemical Interactions between Polystyrenes with Anthracenyl and Tetrathiafulvalenyl Sidechains”
      Chem. Commun. 2001, 2232-2233.
    • 93) Swenson, R.; Rotello, V. “Organic Redox Cofactors”
      Antiox. Redox Signaling 2001, 721.
    • 92) Bourgel, C.; Boyd, A. S. F.; Cooke, G.; de Cremiers, H. A.; Duclairoir, F. M. A.; Rotello, V. M. “The First Redox Controlled Hydrogen Bonded Three-pole Switch”
      Chem. Commun. 2001, 1954-1955.
    • 91) Jeoung, E.; de Cremiers, H. A.; Deans, R.; Cooke, G.; Heath, S. L.; Vanderstraeten, P. E.; Rotello, V. M. “Control of Host Dimerization and Flavin Recognition via Intramolecular Receptor Self-assembly”
      Tetrahedron Lett. 2001, 42, 7357-7359.
    • 90) Rotello, V. M. “From Biology to Devices. The Interdependence of Redox and Molecular Recognition”
      Curr. Org. Chem. 2001, 5, 1079-1090.
    • 89) Batsanov, A. S.; Bryce, M. R.; Chesney, A.; Howard, J. A. K.; John, D. E.; Moore, A. J.; Wood, C. L.; Gershtenman, H.; Becker, J. Y.; Khodorkovsky, V. Y.; Ellern, A.; Bernstein, J.; Perepichka, I. F.; Rotello, V. M.; Gray, M.; Cuello, A. O. “Synthesis and Crystal Engineering of New Halogenated Tetrathiafulvalene (TTF) Derivatives and Their Charge Transfer Complexes and Radical Ion Salts”
      J. Mater. Chem. 2001, 11, 2181-2191.
      Tetrahedron Lett. 2001, 42, 7357-7359.
    • 88) Jeoung, E.; Galow, T. H.; Schotter, J.; Bal, M.; Ursache, A.; Tuominen, M. T.; Stafford, C. M.; Russell, T. P.; Rotello, V. M. “Fabrication and Characterization of Nanoelectrode Arrays Formed via Block Copolymer Self-assembly”
      Langmuir 2001, 17, 6396-6398.
    • 87) Cooke, G.; de Cremiers, H. A.; Duclairoir, F. M. A.; Gray, M.; Vaqueiro, P.; Powell, A. V.; Rosair, G.; Rotello, V. M. “The Charge-Transfer Complexation of Tetrathiafulvalene with Paraquat and Its Oligomeric Derivatives”
      Tetrahedron Lett. 2001, 42, 5089-5091.
    • 86) McIntosh, C. M.; Esposito, E. A.; Boal, A. K.; Simard, J. M.; Martin, C. T.; Rotello, V. M. “Inhibition of DNA Transcription Using Cationic Mixed Monolayer Protected Gold Clusters”
      J. Am. Chem. Soc. 2001, 123, 7626-7629.
    • 85) Bryce, M. R.; Cooke, G.; Devonport, W.; Duclairoir, F. M. A.; Rotello, V. M. “A Stopperless Tetrathiafulvalene Based [2]Pseudorotaxane Molecular Shuttle”
      Tetrahedron Lett. 2001, 42, 4223-4226.
    • 84) Bryce, M. R.; Cooke, G.; Duclairoir, F. M. A.; Rotello, V. M. “An Investigation of the Complexation Behaviour of Structurally Modified Tetrathiafulvalene Derivatives with the Electron Deficient Cyclophane Cyclobis(paraquat-p-phenylene)”
      Tetrahedron Lett. 2001, 42, 1143-1145.
    • 83) Perepichka, D. F.; Bryce, M. R.; Batsanov, A. S.; Howard, J. A. K.; Cuello, A. O.; Gray, M.; Rotello, V. M. “Trialkyltetrathiafulvalene-sigma-tetracyanoanthraquinodimethane (R 3TTF-sigma-TCNAQ) Diads: Synthesis, Intramolecular Charge-transfer Properties, and X-ray Crystal Structure”
      J. Org. Chem. 2001, 66, 4517-4524.
    • 82) Goodman, A. J.; Breinlinger, E. C.; McIntosh, C. M.; Grimaldi, L. N.; Rotello, V. M. “Model Systems for Flavoenzyme Activity. Control of Flavin Recognition via Specific Electrostatic Interactions”
      Org. Lett. 2001, 3, 1531-1534.
    • 81) Vining, W.; Rotello, V. M.; Bak, D.
      “Harcourt Interactive Organic Chemistry” (CD-ROM) Harcort: New York, 2001.
    • 80) Goodman, A.; Breinlinger, E.; Ober, M.; Rotello, V. M. “Controlled Multi-stage Recognition of Guests Using Orthogonal Electro- and Photochemical Inputs”
      J. Am. Chem. Soc. 2001, 123, 6213-6214.
    • 79) Ilhan, F.; Gray, M.; Rotello, V. M. “Reversible Side Chain Modification through Noncovalent Interactions. “Plug and Play” Polymers”
      Macromolecules 2001, 34, 2597-2601.
    • 78) Rotello, V. M. “Redox Modulation by Molecular Recognition”
      Electron Transfer in Chemistry, Wiley-VCH: Weinheim, V. Balzani, ed., 2001, 68-86.
    • 77) Cooke, G.; de Cremiers, H. A.; Rotello, V. M.; Tarbit, B.; Vanderstraeten, P. E. “Synthesis of 6-Aryl-2,4-diamino-pyrimidines and Triazines Using Palladium Catalysed Suzuki Cross-coupling Reactions”
      Tetrahedron 2001, 57, 2787-2789.
    • 2000

    • 76) Clavier, G.; Ilhan, F.; Rotello, V. M. “Photochemical Control of the Macroconformation of Polystyrene Using Azobenzene Side Chains”
      Macromolecules 2000, 33, 9173-9175.
    • 75) Galow, T. H.; Cuello, A. O.; Rotello, V. M. “Vicinal Tricarbonyls as Redox-controlled Molecular Rotors”
      Tetrahedron Lett. 2000, 41, 9489-9492.
    • 74) Boal, A. K.; Rotello, V. M. “Intra- and Intermonolayer Hydrogen Bonding in Amide-functionalized Alkanethiol Self-assembled Monolayers on Gold Nanoparticles”
      Langmuir 2000, 16, 9527-9532.
    • 73) Cooke, G.; Duclairoir, F. M. A.; Rotello, V. M.; Stoddart, J. F. “The Reversible Complexation of A Tetrathiafulavene Functionalised Self-assembled Monolayer by Cyclobis(paraquat-p- phenylene)”
      Tetrahedron Lett. 2000, 41, 8163-8166.
    • 72) Simard, J.; Briggs, C.; Boal, A. K.; Rotello, V. M. “Formation and pH-controlled Assembly of Amphiphilic Gold Nanoparticles”
      Chem. Commun. 2000, 1943-1944.
    • 71) Das, K.; Duffy, D. J.; Hsu, S. L.; Penelle, J.; Rotello, V. M. “Experimental Study of Release and Uptake in Well-defined Imprinted Polymer Films”
      Polymer Preprints 2000, 1173-1174.
    • 70) Ilhan, F.; Boal, A. K.; Rotello, V. “Polymer-mediated “Bricks and Mortar” Self-assembly of Nanoparticles into Discrete Structured Arrays”
      Polymer Preprints, 2000, 1348-1349.
    • 69) Clavier, G.; Ilhan, F.; Galow, T. H.; Gray, M.; Rotello, V. “Control of Polymer Structure: Organization by Non-covalent Interactions”
      Polymer Preprints, 2000, 1322-1323.
    • 68) Ilhan, F.; Galow, T. H.; Gray, M.; Clavier, G.; Rotello, V. M. “Giant Vesicle Formation through Self-assembly of Complementary Random Copolymers”
      J. Am. Chem. Soc. 2000, 122, 5895-5896.
    • 67) Deans, R.; Cuello, A. O.; Galow, T. H.; Ober, M.; Rotello, V. M. “Communication of Electronic Information over Nanometer Distances with Supramolecular Transduction. An Experimental and Density Functional Investigation”
      J. Chem. Soc.-Perkin Trans. 2 2000, 1309-1313.
    • 66) Niemz, A.; Cuello, A.; Steffen, L. K.; Plummer, B. F.; Rotello, V. M. “Electron Confinement in Structurally Constrained sigma-Bonded pi-Systems. An Experimental and Density Functional Investigation”
      J. Am. Chem. Soc. 2000, 122, 4798-4802.
    • 65) Roux, M. V.; Jimenez, P.; Davalos, J. Z.; Martin-Luengo, M. A.; Rotello, V. M.; Cuello, A. O.; Liebman, J. F. “The Plausible Aromaticity of 1,8-Naphthalimides: The Enthalpy of Formation of N-methyl-1,8-naphthalimide”
      Struct. Chem. 2000, 11, 1-7.
    • 64) Galow, T. H.; Ilhan, F.; Cooke, G.; Rotello, V. M. “Recognition and Encapsulation of An Electroactive Guest within A Dynamically Folded Polymer”
      J. Am. Chem. Soc. 2000, 122, 3595-3598.
    • 63) Boal, A. K.; Ilhan, F.; DeRouchey, J. E.; Thurn-Albrecht, T.; Russell, T. P.; Rotello, V. M. “Self-assembly of Nanoparticles into Structured Spherical and Network Aggregates”
      Nature 2000, 404, 746-748.
    • 62) Cuello, A. O.; McIntosh, C. M.; Rotello, V. M. “Model Systems for Flavoenzyme Activity. The Role of N(3)-H Hydrogen Bonding in Flavin Redox Processes”
      J. Am. Chem. Soc. 2000, 122, 3517-3521.
    • 61) Boal, A. K.; Rotello, V. M. “Fabrication and Self-optimization of Multivalent Receptors on Nanoparticle Scaffolds”
      J. Am. Chem. Soc. 2000, 122, 734-735.
    • 60) Galow, T. H.; Boal, A. K.; Rotello, V. M. “A “Building Block” Approach to Mixed-colloid Systems Through Electrostatic Self-organization”
      Adv. Mater. 2000, 12, 576-579.
    • 59) Ilhan, F.; Diamondis, L.; Gautreau, L.; Rotello, V. M. “Kinetic Trapping of Host-guest Complexes in A Polymeric Matrix”
      Chem. Commun. 2000, 447-448.
    • 58) Duffy, D. J.; Das, K.; Hsu, S. L.; Penelle, J.; Rotello, V. M.; Stidham, H. D. “Molecularly Imprinted Polymersystems for Selective Recognition via Hydrogen-bonding Interactions”
      PMSE Preprints, 2000, 82, 69-70.
    • 57) Niemz, A.; Jeoung, E.; Boal, A. K.; Deans, R.; Rotello, V. M. “Divergent Surface Functionalization Using Acid Fluoride-functionalized Self-assembled Monolayers”
      Langmuir 2000, 16, 1460-1462.
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