Responsive Assemblies and Materials


Fernandez, A.; Krishna, J.; Anson, F.; Dinsmore, A.D. and Thayumanavan, S. “Consequences of Noncovalent Interfacial Contacts between Nanoparticles and Giant VesiclesAngew. Chem.Int. Ed.2022,61, e2022086, (DOI:10.1002/anie.202208616)


Agrohia D.K.; Wu, P.; Huynh, U.; Thayumanavan, S. and Vachet, R.W. “Multiplexed Analysis of the Cellular Uptake of Polymeric NanocarriersAnal. Chem. 2022, 94, 22, 7901–7908, (DOI:10.1021/acs.analchem.2c00648)


Kanjilal, P.; Dutta, K.; Thayumanavan, S. “Thiol-Disulfide Exchange as a Route for Endosomal Escape of Polymeric Nanoparticles” Angew. Chem.Int. Ed.2022,61, e2022092,  (DOI:10.1002/anie.202209227)


Dutta, R.; Makhaik, S.; Zhao, P.; Cruz, K.G.; Park, KW; Liu, H.; Andrew, T.L.; Hardy, J.A.; Thayumanavan, S. “Colorimetric Cotton Swab for Viral Protease Detection” Anal Chem. 2022, In press. (DOI:10.1021/acs.analchem.2c02033)


Gao, J.*; Prachyathipsakul, T.*; Thayumanavan, S. “Multichannel Dual Protein Sensing Using Amphiphilic Supramolecular Assemblies” Chem. Commun., 2021, 57, 12828-12831. (DOI:10.1039/D1CC05407D)


Lionello, C.; Gardin, A.; Cardellini, A.; Bochicchio, D.; Shivrayan, M.; Fernandez, A.; Thayumanavan, S.; and Pavan, G.M. “Toward Chemotactic Supramolecular Nanoparticles: From Autonomous Surface Motion Following Specific Chemical Gradients to Multivalency-Controlled Disassembly” ACS Nano, 2021, 15, 10, 16149-16161 . (DOI:10.1021/acsnano.1c05000)


Liu, H.; Westley, J.; Thayumanavan, S. “Excimer-monomer fluorescence changes by supramolecular disassembly for protein sensing and quantification” Chem. Commun., 2021, 57, 9776-9779. (DOI:10.1039/D1CC03944J)


Cao, R.; Gao, J.; Thayumanavan, S.; Dinsmore, A.D. “Triggered interactions between nanoparticles and lipid membranes: design principles for gel formation or disruption-and-release” Soft Matter, 2021, 17, 7069-7075. (DOI:10.1039/D1SM00864A)


Anson, F.; Thayumanavan, S.; Hardy, J.A. “Exogenous Introduction of Initiator and Executioner Caspases Results in Different Apoptotic Outcomes” JACS Au, 2021,1, 8, 1240–1256 . (DOI:10.1021/jacsau.1c00261)


Liu, B.; Thayumanavan, S. “Mechanistic Investigations on the Oxidative Degradation of ROS Responsive Thio-Acetal/-Ketal Moieties and Their Implications” Cell Rep. Phys. Sci., 2020,1, 100271. (DOI:10.1016/j.xcrp.2020.100271)


Kumar, V.; Munkhbat, O.; Secinti, H.; Thayumanavan, S “Disassembly of Polymeric Nanoparticles with Enzyme-Triggered Polymer Unzipping: Polyelectrolyte Complexes vs. Amphiphilic Nanoassemblies” Chem. Commun., 2020, 56, 8456-8459 . (DOI: 10.1039/D0CC03257C)


Kumar, V.; Koyasseril-Yehiya, T. M.; Thayumanavan, S. “Enzyme-Triggered Nanomaterials and Their Applications” Molecular Assemblies: Characterization and Applications (ACS Symposium Series Ed. R. Nagarajan) 2020, 1355, 95-107 . (DOI:10.1021/bk-2020-1355.ch007 )


Zhuang, J. and Thayumanavan, S. “Triblock–Diblock Composite Nanoassemblies with Sequentially Addressable Host–Guest Properties for Hydrophobics and Hydrophilics” ACS Macro Lett, 2020, 9, 1019-1023 . (DOI: 10.1021/acsmacrolett.0c00290)


Addy, P.; Shivrayan, M.; Cencer, M.; Zhuang, J.; Moore, J.; Thayumanavan, S. “A Polymer with Competing Depolymerization Pathways: Chain Unzipping vs. Chain Scission” ACS Macro Lett, 2020, 9, 855–859 . (DOI: 10.1021/acsmacrolett.0c00250)


Fernandez, A.; Zentner, C.; Shivrayan, M.; Samson, E.; Savagatrup, S.; Zhuang, J.; Swager, T.M.; Thayumanavan, S. “Programmable Emulsions via Nucleophile-Induced Covalent Surfactant Modifications” Chem. Mater., 2020, 32, 4663–4671 . (DOI: 10.1021/acs.chemmater.0c01107)


Gao, J.; Wu, P.; Fernandez, A.; Zhuang, J.; Thayumanavan, S. “Cellular AND Gates: Synergistic Recognition to Boost Selective Uptake of Polymeric Nanoassemblies” Angew.Chem.Int.Ed., 2020, 59, 1-6. (DOI: 10.1002/anie.202002748)


Tsuei, M.; Shivrayan, M.; Kim, Y.; Thayumanavan, S.; Abbott, N.L. “Optical “Blinking” Triggered by Collisions of Single Supramolecular Assemblies of Amphiphilic Molecules with Interfaces of Liquid Crystals” J. Am. Chem. Soc., 2020, 142, 6139–6148 . (DOI: 10.1021/jacs.9b13360)


Kumar, V.; Harris, J.T.; Ribbe, A.; Franc, M.; Bae, Y.; McNeil, A.J.; Thayumanavan, S. “Construction from Destruction: Hydrogel Formation from Triggered Depolymerization-Based Release of an Enzymatic Catalyst” ACS Macro Lett., 2020, 9, 377-381. (DOI: 10.1021/acsmacrolett.0c00023)


Zhuang, J.; Zhao, B.; Meng, X.; Schiffman, J.; Perry, S.L.; Vachet, R.W.; Thayumanavan, S. “A programmable chemical switch based on triggerable Michael acceptors” Chem. Sci., 2020, 11, 2103-2111. (DOI: 10.1039/C9SC05841A)


Zentner, C.A.; Anson, F.; Thayumanavan, S.; Swager, T.M. “Dynamic Imine Chemistry at Complex Double Emulsion Interfaces” J.Am.Chem.Soc , 2019, 141, 18048-18055 . (DOI: 10.1021/jacs.9b06852)


Raghupathi, K.; Kumar, V.; Sridhar, U.; Ribbe, A.E.; He, H.; Thayumanavan, S. “Role of Oligoethylene Glycol Side Chain Length in Responsive Polymeric Nanoassemblies” Langmuir, 2019, 35, 7929-7936 . (DOI: 10.1021/acs.langmuir.9b00676)


Jiang, Z.; Cui, W.; Mager, J.; Thayumanavan, S. “Postfunctionalization of Noncationic RNA-polymer Complexes for RNA Delivery” Ind. Eng. Chem. Res. 2019, 58, 6982-6991. (DOI: 10.1021/acs.iecr.9b00666)


Zhuang, J.; Zhao, B.; Thayumanavan, S. “Cascaded Step-Growth Polymerization for Functional Polyamides with Diverse Architectures and Stimuli Responsive Characteristics” ACS Macro Lett. 2019, 8, 245–249. (DOI: 10.1021/acsmacrolett.9b00094)


Munkhbat, O.; Canakci, M.; Zheng, S.; Hu, W.; Osborne, B.; Bogdanov, A. A.; Thayumanavan, S. “19F MRI Imaging of Polymer Nanogels Aided by Improved Segmental Mobility of Embedded Fluorine Moieties” Biomacromolecules 2019, 20, 790–800. (DOI: 10.1021/acs.biomac.8b01383)


Jiang, Z.; Cui, W.; Prasad, P.; Touve, M. A.; Gianneschi, N. C.; Mager, J.; Thayumanavan, S. “Bait-and-Switch Supramolecular Strategy To Generate Noncationic RNA–Polymer Complexes for RNA Delivery” Biomacromolecules 2019, 20, 435–442. (DOI: 10.1021/acs.biomac.8b01321)


Song, C.; Lin, T.; Zhang, Q.; Thayumanavan, S.; Ren, L. “pH-Sensitive Morphological Transitions in Polymeric Tadpole Assemblies for Programmed Tumor Therapy” J. Control. Release 2019, 293, 1-9. (DOI: 10.1016/j.jconrel.2018.10.033)


He, H.; Liu, B.; Wang, M.; Vachet, R. W.; Thayumanavan, S. “Sequential Nucleophilic ‘Click’ Reactions for Functional Amphiphilic Homopolymers” Polym. Chem. 2019, 10, 187-193. (DOI: 10.1039/C8PY01341A)


Zhuang, J.; Secinti, H.; Zhao, B.; Thayumanavan, S. “Propagation of Enzyme Induced Surface Events Inside Polymer Nanoassemblies for a Fast and Tunable Response” Angew. Chem. Int. Ed. 2018, 57, 7111-7115. (DOI: 10.1002/anie.201803029)


Molla, M. R.; Rangadurai, P.; Antony, L.; Swaminathan, S.; de Pablo, J. J.; Thayumanavan, S. “Dynamic Actuation of Glassy Polymersomes through Isomerization of a Single Azobenzene Unit at the Block Copolymer Interface” Nat. Chem. 2018, 10, 659–666. (DOI: 10.1038/s41557-018-0027-6)
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Serrano, M. A. C.; Gao, J.; Kelly, K. A.; Thayumanavan, S.; Vachet, R. W. “Supramolecular Polymeric Assemblies for the Selective Depletion of Abundant Acidic Proteins in Serum” ACS Appl. Mater. Interfaces 2018, 10, 40443–40451. (DOI: 10.1021/acsami.8b15976)


Kim, Y.-K.; Raghupathi, K. R.; Pendery, J. S.; Khomein, P.; Sridhar, U.; de Pablo, J. J.; Thayumanavan, S.; Abbott, N. L. “Oligomers as Triggers for Responsive Liquid Crystals” Langmuir 2018, 34, 10092–10101. (DOI: 10.1021/acs.langmuir.8b01944)


Leriche, G.; Manafirad, A.; Nguyen, S.; Bell, N.; Patterson, J. P.; Thayumanavan, S.; Yang, J.; Dinsmore, A. D.; Gianneschi, N. C. “Water Permeability and Elastic Properties of an Archaea Inspired Lipid Synthesized by Click Chemistry” Chem. Mater. 2018, 30, 3618–3622. (DOI: 10.1021/acs.chemmater.8b00992)


Gordon, M. R.; Zhuang, J.; Ventura, J.; Li, L.; Raghupathi, K.; Thayumanavan, S. “Biodistribution Analysis of NIR-Labeled Nanogels using In Vivo FMT Imaging in Triple Negative Human Mammary Carcinoma Models” Mol. Pharmaceutics 2018, 15, 1180–1191. (DOI: 10.1021/acs.molpharmaceut.7b01011)


Gordon, M. R.; Zhao, B.; Anson, F.; Fernandez, A.; Singh, K.; Homyak, C.; Canakci, M.; Vachet, R. W.; Thayumanavan, S. “Matrix Metalloproteinase-9 Responsive Nanogels for Proximal Surface Conversion and Activated Cellular Uptake” Biomacromolecules 2018, 19, 860-871. (DOI: 10.1021/acs.biomac.7b01659)


Gao, J.; Liu, X.; Secinti, H.; Jiang, Z.; Munkhbat, O.; Xu, Y.; Guo, X.; Thayumanavan, S. “Photoactivation of Ligands for Extrinsically and Intrinsically Triggered Disassembly of Amphiphilic Nanoassemblies” Chem. Eur. J. 2018, 24, 1789–1794. (DOI: 10.1002/chem.201705217)


Khomein, P.; Swaminathan, S.; Young, E. R.; Thayumanavan, S. “Fluorescence Enhancement Through Incorporation of Chromophores in Polymeric Nanoparticles” J. Inorg. Organomet. Polym. Mater. 2018, 28, 407-413. (DOI: 10.1007/s10904-017-0670-1)


Raghupathi, K.; Eron, S. J.; Anson, F.; Hardy, J. A.; Thayumanavan, S. “Utilizing Inverse Emulsion Polymerization to Generate Responsive Nanogels for Cytosolic Protein Delivery” Mol. Pharm. 2017, 14, 4515–4524. (DOI: 10.1021/acs.molpharmaceut.7b00643)


Dutta, K.; Hu, D.; Zhao, B.; Ribbe, A.; Zhuang, J.; Thayumanavan, S. “Templated Self-Assembly of a Covalent Polymer Network for Intracellular Protein Delivery and Traceless Release” J. Am. Chem. Soc. 2017, 139, 5676–5679. (DOI: 10.1021/jacs.7b01214)
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Raghupathi, K.; Thayumanavan, S. “Nano-Armoring of Enzymes: Rational Design of Polymer-Wrapped Enzymes” Methods Enzymol. 2017, 590, 381–411. (DOI: 10.1016/bs.mie.2017.01.007)


Zhuang, J.; Garzoni, M.; Torres, D. A.; Poe, A.; Pavan, P. M.; Thayumanavan, S. “Programmable Nanoassemblies from Non-Assembling Homopolymers Using Ad Hoc Electrostatic Interactions” Angew. Chem. Int. Ed. 2017, 56, 4145–4149. (DOI: 10.1002/anie.201611688)


Liu, B.; Thayumanavan, S. “Substituent Effects on the pH Sensitivity of Acetals and Ketals and Their Correlation with Encapsulation Stability in Polymeric Nanogels” J. Am. Soc. Chem. 2017, 139, 2306–2317. (DOI: 10.1021/jacs.6b11181)


Liu, X.; Ding, H.; Jiang, Z.; Zhuang, J.; Xu, Y.; Guo, X.; Thayumanavan, S. “Multi-Stimuli-Responsive Amphiphilic Assemblies through Simple Postpolymerization Modifications” Macromolecules 2016, 49, 6186–6192. (DOI: 10.1021/acs.macromol.6b01397)


Rangadurai, P.; Molla, M. R.; Prasad, P.; Caissy, M.; Thayumanavan, S. “Temporal and Triggered Evolution of Host-Guest Characteristics in Amphiphilic Polymer Assemblies” J. Am. Chem. Soc. 2016, 138, 7508–7511. (DOI: 10.1021/jacs.6b04099)


Wang, H.; Zhuang, J.; Raghupathi, K. R.; Thayumanavan, S. “A Supramolecular Dissociation Strategy for Protein Sensing” Chem. Commun. 2015, 51, 17265–17268. (DOI: 10.1039/C5CC07408H)


Prasad, P.; Molla, M. R.; Cui, W.; Canakci, M.; Osborne, B.; Mager, J.; Thayumanavan, S. “Polyamide Nanogels from GRAS Components and Their Toxicity in Mouse Pre-implantation Embryos” Biomacromolecules 2015, 16, 3491–3498. (DOI: 10.1021/acs.biomac.5b00900)


Ventura, J.; Eron, S. J.; González-Toro, D. C.; Raghpathi, K. R.; Wang, F.; Hardy, J. A.; Thayumanavan, S. “Reactive Self-Assembly of Polymers and Proteins to Reversibly Silence a Killer Protein” Biomacromolecules 2015, 16, 3161–3171. (DOI: 10.1021/acs.biomac.5b00779)


Molla, M. R.; Prasad, P.; Thayumanavan, S. “Protein‐Induced Supramolecular Disassembly of Amphiphilic Polypeptide Nanoassemblies” J. Am. Chem. Soc. 2015, 137, 7286-7289. (DOI: 10.1021/jacs.5b04285) (R,S)170


Song, C.; Li, L.; Dai, L.; Thayumanavan, S. “Responsive Single Chain Polymer Nanoparticles with Host-Guest Features” Polym. Chem. 2015, 6, 4828-4834. (DOI: 10.1039/C5PY00600G) (R)



Raghupathi, K. R.; Sridhar, U.; Byrne, K.; Raghupathi, K. R.; Thayumanavan, S. “Influence of Backbone Conformational Rigidity in Temperature-Sensitive Amphiphilic Supramolecular Assemblies” J. Am. Chem. Soc. 2015, 137, 5308-5311 (DOI: 10.1021/jacs.5b02108). (R, S)168


Wang, Hui; Raghupathi, K.; Zhuang, J.; Thayumanavan, S. “Activatable Dendritic 19F Probes for Enzyme Detection” ACS Macro Letters, 2015, 4, 422-425 (DOI: 10.1021/acsmacrolett.5b00199). (R, S)167


Yuan, C.; Chang, Y.; Mao, J.; Yu, S.; Luo, W.; Xu, Y.; Thayumanavan, S.; Dai, L. “Supramolecular Assembly of Crosslinkable Monomers for Degradable and Fluorescent Polymer Nanoparticles” J. Mater. Chem. B. , 2015, 2858-2866  (DOI: 10.1039/c4tb01880j).  (R,S)





Li, L.; Song, C.; Jennings, M.; Thayumanavan, S. “Photoinduced Heterodisulfide Metathesis for Reagent-free Synthesis of Polymer Nanoparticles” Chem. Commun. 2015, 51, 1425-1428 (DOI: 10.1039/c4cc08000a). (R)



Molla, M. R.; Rangadurai, P.; Pavan, G. M.; Thayumanavan, S. “Experimental and Theoretical Investigations in Stimuli Responsive Dendrimer-based Assemblies” Nanoscale, 2015, 7, 3817-3837 (DOI: 10.1039/C4NR04563G). (R,S)



Molla, M. R.; Marcinko, T.; Prasad, P.; Deming, D.; Garman, S.; Thayumanavan, S. “Unlocking a Caged Lysosomal Protein from a Polymeric Nanogel with a pH Trigger” Biomacromolecules, 2014, 15, 4046-4053 (DOI: 10.1021/bm501091p). (R,S)



Li, L.; Thayumanavan, S. “Environment-Dependent Guest-Exchange in Supramolecular Hosts” Langmuir, 2014, 30, 12384-12390 (DOI: 10.1021/la502760c). (R,S)



Li, L.; Yuan, C.; Dai, L.; Thayumanavan, S. “Thermo-responsive Polymeric Nanoparticles: Nucleation from Cooperative Polymerization Driven by Dative Bonds” Macromolecules, 2014, 47, 5869-5876 (DOI: 10.1021/ma5015808). (R,S)



Raghupathi, K.; Guo, J.; Munkhbat, O.; Rangadurai, P.; Thayumanavan, S. “Supramolecular Assembly and Disassembly of Facially Amphiphilic Dendrimers” Acc. Chem. Res. 201447, 2200-2211 (Invited Review)  (DOI: 10.1021/ar500143u) (PMCID# PMC4100797). (R,S)



Amado Torres, D.; Garzoni, M.; Subrahmanyam, A.; Pavan, G. M.; Thayumanavan, S. “Protein-Triggered Supramolecular Disassembly: Insights Based on Variations in Ligand Location in Amphiphilic Dendrons” J. Am. Chem. Soc. 2014, 136, 5385-5399. (DOI: 10.1021/ja500634u ) (R,S) 155


Guo, J.; Zhuang, J.; Wang, F.; Raghupathi, K.; Thayumanavan, S. “Protein AND Enzyme Gated Supramolecular Disassembly”  J. Am. Chem. Soc. 2014, 136, 2220-2223   (DOI: 10.1021/ja4108676) (R,S). 



Zhuang, J.; Chacko, R.; Amado Torres, D.; Wang, H.; Thayumanavan, S. “Dual Stimuli – Dual Response Nanoassemblies Prepared from a Simple Homopolymer” ACS Macro Lett. 2014, 3, 1-5 (DOI: 10.1021/mz400515s) (R,S).



Raghupathi, K.; Li, L.; Ventura, J.; Jennings, M.; Thayumanavan, S. “pH Responsive Soft Nanoclusters with Size and Charge Conversional Features” Polym. Chem. 2014, 5, 1737-1742. (DOI:10.1039/C3PY01277H) (R,S)



Yuan, C.; Raghupathi, K.; Popere, B. C.; Ventura, J.; Dai, L.; Thayumanavan, S. “Composite Supramolecular Nanoassemblies with Independent Stimulus Sensitivities”  Chem. Sci. 2014, 5, 229-234. (DOI:10.1039/C3SC52347K) (R,S)




Wang, H.; Zhuang, J.; Thayumanavan, S. ““Functionalizable Amine-based Polymer Nanoparticles” ACS Macro Lett. 2013, 2, 948-951. (DOI: 10.1021/mz4004248) (R,S)



Li, L.; Raghupathi, K.; Yuan, C.; Thayumanavan, S. “Surface Charge Generation in Nanogels for Activated Cellular Uptake at Tumor-Relevant pH” Chem. Sci. 2013, 4, 3654-3660. (DOI: 10.1039/C3SC50899D) (R,S)144



Fuller, J.; Raghupathi, K.; Ramireddy, R. R.; Subrahmanyam, A.; Yesilyurt, V.; Thayumanavan, S. “Temperature-Sensitive Transitions Below LCST in Amphiphilic Dendritic Assemblies – Host-Guest Implications” J. Am. Chem. Soc. 2013, 135, 8947-8954. (DOI: 10.1021/ja402019c) (R,S)


Zhuang, J.; Gordon, M.; Ventura, J.; Li, L. Thayumanavan, S. “Multi-Stimuli Responsive Macromolecules and Their Assemblies” Chem. Soc. Rev. 2013, 42, 7421-7435. (DOI: 10.1039/C3CS60094G) (R, S)


González-Toro, D.; Thayumanavan, S. “Advances in Polymer and Polymeric Nanostructures for Protein Conjugation” Eur. Poly. J. 2013, 49, 2906-2918. (DOI: 10.1016/j.eurpolymj.2013.05.002) (R)


Matsumoto, N.; Gonzalez-Toro, D.; Chacko, R.; Maynard, H. D.; Thayumanavan, S. “Synthesis of Nanogel-Protein Conjugates” Polymer Chem. 2013, 4, 2464-2469. (DOI: 10.1039/c3py00085k) (R)


Li, L.; Ryu, J.; Thayumanavan, S. “Effect of Hofmeister Ions on the Size and Encapsulation Stability in Polymer Nanogels” Langmuir, 2013, 29, 50-55. (DOI: 10.1021/la3033463) (R)


Bickerton, S.; Jiwpanich, S.; Thayumanavan, S. “Interconnected Roles of Scaffold Hydrophobicity, Drug Loading and Encapsulation Stability in Polymeric Nanocarriers” Mol. Pharm. 2012, 9, 3569-3578. (DOI: 1021/mp3004226) (R, S)


Gonzalez-Toro, D.; Ryu, J.-H.; Chacko, R.; Zhuang, J.; Thayumanavan, S. “Concurrent Binding and Delivery of Proteins and Lipophilic Small Molecules Using Polymeric Nanogels” J. Am. Chem. Soc. 2012, 134, 6964-6967. (DOI: 10.1021/ja3019143) (R)


Ryu, J.; Bickerton, S.; Zhuang, J.; Thayumanavan, S. “Ligand-Decorated Nanogels: Fast One-Pot Synthesis and Cellular Targeting” Biomacromolecules, 2012, 13, 1515-1522. (DOI: 10.1021/bm300201x) (R)


Chacko, R.; Ventura, J.; Zhuang, J.; Thayumanavan, S. “Polymer Nanogels: A Versatile Nanoscopic Drug Delivery Platform” Adv. Drug Deliv. Rev. 2012, 64, 836-851. (Invited Perspective) (DOI: 10.1016/j.addr.2012.02.002) (R)


Zhuang, J.; Jiwpanich, S.; Deepak, V. D.; Thayumanavan, S. “Facile Preparation of Nanogels Using Activated Ester Containing Polymers” ACS Macro Lett. 2012, 1, 175-179. (DOI: 10.1021/mz200123f) (R)


Ryu, J.-H.; Chacko, R.; Jiwpanich, S.; Bickerton, S.; Babu, R. P.; Thayumanavan, S. “Self-Crosslinked Polymer Nanogels: a Versatile Nanoscopic Drug Delivery Platform” J. Am. Chem. Soc. 2010, 132, 17227-17235. (DOI: 10.1021/ja1069932) (R)


Jiwpanich, S.; Ryu, J.-H.; Bickerton, S.; Thayumanavan, S. “Noncovalent Encapsulation Stability in Supramolecular Nanoassemblies” J. Am. Chem. Soc. 2010, 132, 10683-10685. (DOI: 10.1021/ja105059g) (R, S)


Satav, S.; Bhat, S.; Thayumanavan, S. “Feedback Regulated Drug Delivery Vehicles: Carbon Dioxide Responsive Cationic Hydrogels for Antidote Release” Biomacromolecules, 2010, 11, 1735-1740. (DOI: 10.1021/bm1005454) (R)


Ryu, J.-H.; Jiwpanich, S.; Chacko, R.; Bickerton, S.; Thayumanavan, S. “Surface-Functionalizable Polymer Nanogels with Facile Hydrophobic Guest Encapsulation Capabilities” J. Am. Chem. Soc. 2010, 132, 8246-8247. (DOI: 10.1021/ja102316a) (R)


Ryu, J.; Park, S.; Kim, B.; Klaikherd, A.; Russell, T. P.; Thayumanavan, S. “Highly Ordered Gold Nanotubes using Thiols at a Cleavable Block Copolymer Interface” J. Am. Chem. Soc. 2009, 131, 9870-9871. (DOI: 10.1021/ja902567p) (R)


Roy, R.; Jerry, D. J.; Thayumanavan, S. “Virus-Inspired Approach to Nonviral Gene Delivery Vehicles” Biomacromolecules, 2009, 10, 2189-2193. (DOI: 10.1021/bm900370p) (R)


Klaikherd, A.; Chikkanagari, N.; Thayumanavan, S. “Multi-Stimuli Sensitive Amphiphilic Block Copolymer Assemblies” J. Am. Chem. Soc. 2009, 131, 4830-4838. (DOI: 10.1021/ja809475a) (R)


Ghosh, S.; Yesilyurt, V.; Savariar, E. N.; Irvin, K.; Thayumanavan, S. “Redox, Ionic Strength, and pH Sensitive Supramolecular Polymer Assemblies” J. Poly. Sci. Part A: Poly. Chem. 2009, 47, 1052-1060. (DOI: 10.1002/pola.23204) (R)


Savariar, E. N.; Sochat, M. M.; Klaikherd, A.; Thayumanavan, S. “Functional Group Density and Recognition in Polymer Nanotubes” Angew. Chem. Int. Ed. 2009, 48, 110-114. (DOI: 10.1002/anie.200804136) (R)


Savariar, E. N.; Ghosh, S.; González, D. C.; Thayumanavan, S. “Disassembly of Noncovalent Amphiphilic Polymers with Proteins and Utility in Pattern Sensing” J. Am. Chem. Soc. 2008, 130, 5416-5417.  (DOI: 10.1021/ja800164z) (R, S)


Klaikherd, A.; Ghosh, S.; Thayumanavan, S. “A Facile Method for the Synthesis of Cleavable Block Copolymers from ATRP-based Homopolymers” Macromolecules, 2007, 40, 8518-8520. (DOI: 10.1021/ma071852n) (R, S)


Ghosh, S.; Irvin, K.; Thayumanavan, S. “Tunable Disassembly of Micelles Using a Redox Trigger” Langmuir 2007, 23, 7916-7919. (DOI: 10.1021/la700981z) (R)


Kim, Y.J.; Shin, D.; Vutukuri, D.; Savariar, E.N.; Kim, S.Y.; Thayumanavan, S.; Russell, T.P. “Globular Organization of Multifunctional Linear Homopolymer Using Trifunctional Molecules” Macromolecules, 2007, 40, 4267-4275. (DOI: 10.1021/ma070170x) (R)


Ambade, A. V.; Savariar, E. N.; Thayumanavan, S. “Dendritic Nanostructures for Cancer Therapy” Nanotechnology for Cancer Therapy, 2007, 509-521. (invited review). (DOI: 10.1201/9781420006636.ch26) (R, S)


Ghosh, S.; Basu, S.; Thayumanavan, S. “Simultaneous and Reversible Functionalization of Copolymers for Biological Applications” Macromolecules, 2006, 39, 5595-5597. (DOI: 10.1021/ma061420x) (R, S)


Roy, R.; Sandanaraj, B. S.; Klaikherd, A.; Thayumanavan, S. “Tuning Substrate Selectivity of a Cationic Enzyme Using Cationic Polymers” Langmuir, 2006, 22, 7695-7700. (DOI: 10.1021/la060496j) (R, S)


Jiang, J.; Thayumanavan, S. “Synthesis and Characterization of Amine-Functionalized Polystyrene Nanoparticles” Macromolecules, 2005, 38, 5886-5891. (DOI: 10.1021/ma0507286) (S, R)


Savariar, E. N.; Thayumanavan, S. “Controlled Polymerization of N-isopropylacrylamide with an Activated Methacrylic Ester” J. Poly. Sci. Part A: Poly. Chem. 2004, 42, 6340-6345. (DOI:10.1002/pola.20467) (S, R)


Basu, S.; Vutukuri, D.; Shyamroy, S.; Sandanaraj, B.S.; Thayumanavan, S. “Invertible Amphiphilic Polymers” J. Am. Chem. Soc. 2004, 126, 9890-9891. (DOI: 10.1021/ja047816a) (S, R)