Gong, S.; Qiu, J. and Thayumanavan S. “Self-Assembly of Epitope-Tagged Proteins and Antibodies for Delivering Biologics to Antigen Presenting Cells” J. Am. Chem. Soc. 2024, 146, 1, 33–38 (DOI: 10.1021/jacs.3c09334)


Liu, H.*; Lu, H.H.*; Alp, Y.; Wu, R. and Thayumanavan S. “Structural Determinants of Stimuli-Responsiveness in Amphiphilic Macromolecular Nano-Assemblies” Progress in Polymer Science, 2024, 148, 101765 (DOI: 10.1016/j.progpolymsci.2023.101765)


Manafirad, A.; Menendez, C.A.; Perez-Lemus, G.R.; Thayumanavan, S.; de Pablo, J.J.; Dinsmore, A.D. “Structural and Mechanical Response of Two-Component Photoswitchable Lipid Bilayer Vesicles” Langmuir 2023, 39, 45, 15932–15941 (DOI:10.1021/acs.langmuir.3c01764)


Wu, R.; Prachyathipsakul, T.; Zhuang, J.; Liu, H.; Han, Y.; Liu, B.; Gong, S.; Qiu, J.; Wong S.; Ribbe, A.; Medeiros, J.; Bhagabati, J.; Gao, J.; Wu, P.; Dutta, R.; Herrera, R.; Faraci, S.; Xiao H. and Thayumanavan, S. “Conferring Liver Selectivity to a Thyromimetic Using a Novel Nanoparticle Increases Therapeutic Efficacy in a Diet-Induced Obesity Animal Model” PNAS Nexus, 2023, 2, 1–15. (DOI:10.1093/pnasnexus/pgad252)


Kanjilal, P.; Singh, K.; Das, R.; Matte, J. and Thayumanavan, S. “Antibody Polymer Conjugates (APCs) for Active Targeted Therapeutic Delivery” Biomacromolecules 2023, 24, 8, 3638–3646, (DOI:10.1021/acs.biomac.3c00385)


Kurbanov, M.; Kirsch, Z. J.; Krishna, J.; Dutta, R.; Vachet, R. W. and Thayumanavan, S. “Multisite Labeling of Proteins Using the Ligand-Directed Reactivity of Triggerable Michael Acceptors” Bioconjugate Chem. 2023, 34, 6, 1130–1138, (DOI:10.1021/acs.bioconjchem.3c00155)


Wu, P.; Prachyathipsakul, T.; Huynh, U.; Qiu, J.; Jerry, D. J. and Thayumanavan, S. “Optimizing Conjugation Chemistry, Antibody Conjugation Site, and Surface Density in Antibody–Nanogel Conjugates (ANCs) for Cell-Specific Drug Delivery” Bioconjugate Chem. 2023, 34, 4, 707-718, (DOI:10.1021/acs.bioconjchem.3c00034)


Wang, X.; Krishna, J.; Fernandez, A.; Thayumanavan, S. and Abbott, N.L. “Optical Fingerprinting of Dynamic Interfacial Reaction Pathways Using Liquid CrystalsLangmuir 2023, 39, 1793−1803, (DOI:10.1021/acs.langmuir.2c02622)


Huynh, U.; Wu, P.; Qiu, J.; Prachyathipsakul, T.; Singh, K.; Jerry, D.J.; Gao, J. and Thayumanavan, S. “Targeted Drug Delivery Using a Plug-to-Direct Antibody–Nanogel Conjugate” Biomacromolecules 2023, 24, 849−857, (DOI:10.1021/acs.biomac.2c01269)


Fernandez, A.; Krishna, J.; Anson, F.; Dinsmore, A.D. and Thayumanavan, S. “Consequences of Noncovalent Interfacial Contacts between Nanoparticles and Giant VesiclesAngew. Chem.Int. Ed. 2022,61, e2022086, (DOI:10.1002/anie.202208616)


Agrohia D.K.; Wu, P.; Huynh, U.; Thayumanavan, S. and Vachet, R.W. “Multiplexed Analysis of the Cellular Uptake of Polymeric NanocarriersAnal. Chem. 2022, 94, 22, 7901–7908, (DOI:10.1021/acs.analchem.2c00648)


Kanjilal, P.; Dutta, K.; Thayumanavan, S. “Thiol-Disulfide Exchange as a Route for Endosomal Escape of Polymeric Nanoparticles” Angew. Chem.Int. Ed.2022,61, e2022092,  (DOI:10.1002/anie.202209227)


Dutta, R.; Makhaik, S.; Zhao, P.; Cruz, K.G.; Park, KW; Liu, H.; Andrew, T.L.; Hardy, J.A.; Thayumanavan, S. “Colorimetric Cotton Swab for Viral Protease Detection” Anal Chem. 2022, In press. (DOI:10.1021/acs.analchem.2c02033)


Das, R.; Kanjilal, P.; Medeiros, J.; Thayumanavan, S. “What’s Next After LNPs? A Perspective on Enablers of Nucleic Acid Therapeutics” Bioconj. Chem. 2022, 33, In press. (DOI:10.1021/acs.bioconjchem.2c00058)


Singh, K.; Canakci, M.; Kanjilal, P.; Williams, N.; Shanthalingam, S.; Osborne, B.; Thayumanavan, S. “Evaluation of Cellular Targeting by Fab’ vs Full-length Antibodies in Antibody-Nanoparticle Conjugates (ANCs) Using CD4 T-cells” Bioconj. Chem. 2022, 33, In press. (DOI: 10.1021/acs.bioconjchem.2c00024)


Oster, L. M.; Shechter, J.; Strain, B.; Shivrayan, M.; Thayumanavan, S.; Ross, J. L. “Controlling Liquid Crystal Configuration and Phase Using Multiple Molecular Triggers” Molecules 2022, 27, 878. (DOI: 10.3390/molecules27030878)


Liu, H.; Prachyathipsakul, T.; Koyasseril-Yehiya, T.M.; Le, S.P.; Thayumanavan, S. “Molecular bases for temperature sensitivity in supramolecular assemblies and their applications as thermoresponsive soft materials” Mater. Horiz., 2021, 9, 164-193. (DOI:10.1039/D1MH01091C)


Liu, H.; Kanjilal, P.; Thayumanavan, S. “Self-assembly of Polymers from Multicomponent Reactions” Polymer International, 2022, In Press . (DOI:10.1002/pi.6352)


Wu, P.; Gao, J.; Prasad, P.; Dutta, K.; Kanjilal, P.; Thayumanavan, S. “Influence of Polymer Structure and Architecture on Drug Loading and Redox-Triggered Release” Biomacromolecules, 2021, 23, 1, 339–348 . (DOI:10.1021/jacs.1c08574)


Liu, H.; Lu, H.H.; Zhuang, J.; Thayumanavan, S. “Three-Component Dynamic Covalent Chemistry: From Janus Small Molecules to Functional Polymers” J. Am. Chem. Soc., 2021, 143, 20735-20746. (DOI:10.1021/jacs.1c08574)


Gao, J.*; Prachyathipsakul, T.*; Thayumanavan, S. “Multichannel Dual Protein Sensing Using Amphiphilic Supramolecular Assemblies” Chem. Commun., 2021, 57, 12828-12831. (DOI:10.1039/D1CC05407D)


Gao, J.; Le, S.; Thayumanavan, S. “Enzyme Catalysis in Non-Native Environment with Unnatural Selectivity using Polymeric Nanoreactors” Angew. Chem. Int. Ed., 2021, 60, 27189–27194. (DOI:10.1002/anie.202109477)


Lionello, C.; Gardin, A.; Cardellini, A.; Bochicchio, D.; Shivrayan, M.; Fernandez, A.; Thayumanavan, S.; and Pavan, G.M. “Toward Chemotactic Supramolecular Nanoparticles: From Autonomous Surface Motion Following Specific Chemical Gradients to Multivalency-Controlled Disassembly” ACS Nano, 2021, 15, 10, 16149-16161 . (DOI:10.1021/acsnano.1c05000)


Nandi, D.; Shivrayan, M.; Gao, J.; Krishna, J.; Das, R.; Liu, B.; Thayumanavan, S.; and Kulkarni, A. “Core Hydrophobicity of Supramolecular Nanoparticles Induces NLRP3 Inflammasome Activation” ACS Appl. Mater. Interfaces, 2021, 13, 38, 45300-45314. (DOI:10.1021/acsami.1c14082)


Liu, H.; Westley, J.; Thayumanavan, S. “Excimer-monomer fluorescence changes by supramolecular disassembly for protein sensing and quantification” Chem. Commun., 2021, 57, 9776-9779. (DOI:10.1039/D1CC03944J)


Cao, R.; Gao, J.; Thayumanavan, S.; Dinsmore, A.D. “Triggered interactions between nanoparticles and lipid membranes: design principles for gel formation or disruption-and-release” Soft Matter, 2021, 17, 7069-7075. (DOI:10.1039/D1SM00864A)


Anson, F.; Thayumanavan, S.; Hardy, J.A. “Exogenous Introduction of Initiator and Executioner Caspases Results in Different Apoptotic Outcomes” JACS Au, 2021,1, 8, 1240–1256 . (DOI:10.1021/jacsau.1c00261)


Dutta, K.; Das, R.; Medeiros, J.; Kanjilal, K.; Thayumanavan, S.“Charge-Conversion Strategies for Nucleic Acid Delivery” Adv. Funct. Mater., 2021, 31, 2011103. (DOI:10.1002/adfm.202011103)


Liu, H.; Lionello, C.; Westley, J.; Cardellini, A.; Huynh, U.; Pavan, G.M.; Thayumanavan, S. “Understanding functional group and assembly dynamics in temperature responsive systems leads to design principles for enzyme responsive assemblies” Nanoscale, 2021 , 13, 11568-11575 . (DOI:10.1039/D1NR02000E)


Liu, B.; Singh, K.; Gong, S.; Canakci, M.; Osborne, B.A.; Thayumanavan, S. “Protein-Antibody Conjugates (PACs): A Plug-and-Play Strategy for Covalent Conjugation and Targeted Intracellular Delivery of Pristine Proteins” Angew. Chemie. Int. Ed., 2021 , 60, 12813-12818 . (DOI:10.1002/anie.202103106)


Anson, F.; Liu, B.; Kanjilal, P.; Wu, P.; Hardy, J. A.; Thayumanavan, S. “Evaluating Endosomal Escape of Caspase-3-Containing Nanomaterials Using Split GFP” Biomacromolecules, 2021 ,22, 3, 1261–1272 . (DOI:10.1021/acs.biomac.0c01767)


Dutta, K.; Das, R.; Medeiros, J. M.; Thayumanavan, S. “”Disulfide Bridging Strategies in Viral and Non-viral Platforms for Nucleic Acid Delivery” Biochemistry, 2021, 60, 13, 966–990. (DOI:10.1021/acs.biochem.0c00860)


Gopalakrishnan, S.; Pan, S.; Fernandez, A.; Lee, J.; Bai, Y.; Wang, L-S.; Thayumanavan, S.; Duan, X.; Rotello, V. M. “Hypersound-Assisted Size Sorting of Microparticles on Inkjet-Patterned Protein Films” Langmuir, 2021, 37, 8, 2826–2832 . (DOI:10.1002/pro.3992)


Anson, F.; Kanjilal, P.; Thayumanavan, S.; Hardy, J. “Tracking Exogenous Intracellular Casp-3 Using Split GFP” Prot. Sci., 2020, 30 , 366-380 . (DOI:10.1002/pro.3992)


Liu, B.; Thayumanavan, S. “Mechanistic Investigations on the Oxidative Degradation of ROS Responsive Thio-Acetal/-Ketal Moieties and Their Implications” Cell Rep. Phys. Sci., 2020,1, 100271. (DOI:10.1016/j.xcrp.2020.100271)


Dutta, K.; Kanjilal, P.; Das, R.; Thayumanavan, S. “Synergistic Interplay of Covalent and Non-Covalent Interactions in Reactive Polymer Nanoassembly Facilitates Intracellular Delivery of Antibodies” Angew. Chem. Int. Ed., 2020, 59, 2-12 . (DOI: 10.1002/anie.202010412)


Koyasseril-Yehiya, T. M.; García-Heredia, A.; Anson, F.; Rangadurai, P.; Siegrist, M. S.; Thayumanavan, S. “Supramolecular Antibiotics: A Strategy for Conversion of Broad-Spectrum to Narrow-Spectrum Antibiotics for Staphylococcus aureus” Nanoscale, 2020, 12, 20693-20698 . (DOI: 10.1039/D0NR04886K)


Jiang, Z.; He, H.; Liu, H.; Thayumanavan, S. “Azide-terminated RAFT Polymers for Biological Applications” Curr. Protocols Chem. Biol., 2020, 12, e85 . (DOI: 10.1002/cpch.85)
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Gao, J.; Dutta, K.; Zhuang, J.; Thayumanavan, S. “Cellular and subcellular targeted delivery using a simple all-in-one polymeric nanoassembly” Angew. Chem. Int. Ed., 2020, 59, 23466-23470 . (DOI: 10.1002/anie.202008272)


Kumar, V.; Munkhbat, O.; Secinti, H.; Thayumanavan, S “Disassembly of Polymeric Nanoparticles with Enzyme-Triggered Polymer Unzipping: Polyelectrolyte Complexes vs. Amphiphilic Nanoassemblies” Chem. Commun., 2020, 56, 8456-8459 . (DOI: 10.1039/D0CC03257C)


Kumar, V.; Koyasseril-Yehiya, T. M.; Thayumanavan, S. “Enzyme-Triggered Nanomaterials and Their Applications” Molecular Assemblies: Characterization and Applications (ACS Symposium Series Ed. R. Nagarajan) 2020, 1355, 95-107 . (DOI:10.1021/bk-2020-1355.ch007 )


Dutta, K.; Das, R.; Ling, J.; Monibas, R.M.; Carballo-Jane, E.; Kekec, A.; Feng, D.D.; Lin, S.; Mu, J.; Saklatvala, R.; Thayumanavan, S.; Liang, Y. “In Situ Forming Injectable Thermoresponsive Hydrogels for Controlled Delivery of Biomacromolecules” ACS Omega, 2020, 5, 17531-17542 . (DOI: 10.1021/acsomega.0c02009)


Zhuang, J. and Thayumanavan, S. “Triblock–Diblock Composite Nanoassemblies with Sequentially Addressable Host–Guest Properties for Hydrophobics and Hydrophilics” ACS Macro Lett, 2020, 9, 1019-1023 . (DOI: 10.1021/acsmacrolett.0c00290)


Addy, P.; Shivrayan, M.; Cencer, M.; Zhuang, J.; Moore, J.; Thayumanavan, S. “A Polymer with Competing Depolymerization Pathways: Chain Unzipping vs. Chain Scission” ACS Macro Lett, 2020, 9, 855–859 . (DOI: 10.1021/acsmacrolett.0c00250)


Liu, B.; Wu, R.; Gong, S.; Xiao, H.; Thayumanavan, S. “In Situ Formation of Polymeric Nanoassemblies Using an Efficient reversible Click Reaction” Angew. Chem. Int. Ed., 2020, 59, 15135 –15140 . (DOI: 10.1002/anie.202004017)


Fernandez, A.; Zentner, C.; Shivrayan, M.; Samson, E.; Savagatrup, S.; Zhuang, J.; Swager, T.M.; Thayumanavan, S. “Programmable Emulsions via Nucleophile-Induced Covalent Surfactant Modifications” Chem. Mater., 2020, 32, 4663–4671 . (DOI: 10.1021/acs.chemmater.0c01107)


Canakci, M.; Singh, K.; Munkhbat, O.; Santhalingam, S.; Mitra, A.; Gordon, M.; Osborne, B.; Thayumanavan, S. “Targeting CD4+ Cells with Anti-CD4 Conjugated mertansine Loaded Nanogels” Biomacromolecules, 2020, 21, 2473–2481 . (DOI: 10.1021/acs.biomac.0c00442)


Liu, B.; Ejaz, W.; Gong, S.; Kurbanov, M.; Canakci, M.; Anson, F.; Thayumanavan, S. ” Engineered Interactions with Mesoporous Silica Facilitate Intracellular Delivery of Proteins and Gene Editing” Nano Lett., 2020, 20, 4014-4021 (DOI: 10.1021/acs.nanolett.0c01387)


Zhao, B.; Zhuang, J.; Xu, M.; Liu, T.; Limpikirati, P.; Thayumanavan, S.; Vachet, R.W. “Covalent Labeling with an α, β Unsaturated Carbonyl Scaffold for Studying Protein Structure and Interactions by Mass Spectrometry” Anal. Chem., 2020, 92, 6637−6644 . (DOI: 10.1021/acs.analchem.0c00463 )


Mitra, A.; Shanthalingam, S.; Sherman, H.; Singh, K.; Canakci, M.; Torres, J.A.; Lawlor, R.; Ran, Y.; Golde, T.; Miele, L.; Thayumanavan, S.; Minter, L.M.; Osborne, B.A. “Regulation of Notch ligand expression on CD4 T cells” Frontiers in Immunology, 2020, 11, 735 . (DOI: 10.3389/fimmu.2020.00735)


Jiang, Z.; Liu, H.; He, H.; Yadava, N.; Chambers, J. “Anionic Polymers Promote Mitochondrial Targeting of Delocalized Lipophilic Cations” Bioconjugate Chem., 2020, 31, 1344–1353. (DOI: 10.1021/acs.bioconjchem.0c00079)
[Video] [Featured as the Cover Art]


Gao, J.; Wu, P.; Fernandez, A.; Zhuang, J.; Thayumanavan, S. “Cellular AND Gates: Synergistic Recognition to Boost Selective Uptake of Polymeric Nanoassemblies” Angew.Chem.Int.Ed., 2020, 59, 1-6. (DOI: 10.1002/anie.202002748)


Jiang, Z.; Liu, H. (co-first); He, H.; Ribbe, A.E.; Thayumanavan, S. “Blended Assemblies of Amphiphilic Random and Block Copolymers for Tunable Encapsulation and Release of Hydrophobic Guest Molecules” Macromolecules, 2020, 53, 2713–2723 . (DOI: 10.1021/acs.macromol.9b02595)


Tsuei, M.; Shivrayan, M.; Kim, Y.; Thayumanavan, S.; Abbott, N.L. “Optical “Blinking” Triggered by Collisions of Single Supramolecular Assemblies of Amphiphilic Molecules with Interfaces of Liquid Crystals” J. Am. Chem. Soc., 2020, 142, 6139–6148 . (DOI: 10.1021/jacs.9b13360)


Kumar, V.; Harris, J.T.; Ribbe, A.; Franc, M.; Bae, Y.; McNeil, A.J.; Thayumanavan, S. “Construction from Destruction: Hydrogel Formation from Triggered Depolymerization-Based Release of an Enzymatic Catalyst” ACS Macro Lett., 2020, 9, 377-381. (DOI: 10.1021/acsmacrolett.0c00023)


Zhuang, J.; Zhao, B.; Meng, X.; Schiffman, J.; Perry, S.L.; Vachet, R.W.; Thayumanavan, S. “A programmable chemical switch based on triggerable Michael acceptors” Chem. Sci., 2020, 11, 2103-2111. (DOI: 10.1039/C9SC05841A)


Jiang, Z. and Thayumanavan, S. “Disulfide‐containing Macromolecules for Therapeutic Delivery” Isr. J. of Chem., 2020, 60, 132-139. (DOI: 10.1002/ijch.201900160)


Jiang, Z. and Thayumanavan, S. “Noncationic Material Design for Nucleic Acid Delivery” Advanced Therapeutics, 2020 ,1900206 . (DOI: 10.1002/adtp.201900206)


Park, C.S.; Iwabata, K.; Sridhar, U.; Tsuei, M.; Singh, K.; Kim, YK; Thayumanavan, S.; Abbott, N.L. “A New Strategy for Reporting Specific Protein Binding Events at the Aqueous-Liquid Crystal Interfaces in the Presence of Non-Specific Proteins” ACS Appl. Mater. Interfaces 2020 , 12, 7869-7878 . (DOI: 10.1021/acsami.9b16867)


Zhao, B.; Gao, J.; Serrano, M.A.C.; Arcaro, K.F.; Thayumanavan, S.; and Vachet, R.W. “Polymeric nanoassemblies for enrichment and detection of peptides and proteins in human breast milk” Anal Bioanal Chem, 2020, 412, 1027-1035. (DOI: 10.1007/s00216-019-02342-8)


Zentner, C.A.; Anson, F.; Thayumanavan, S.; Swager, T.M. “Dynamic Imine Chemistry at Complex Double Emulsion Interfaces” J.Am.Chem.Soc , 2019, 141, 18048-18055 . (DOI: 10.1021/jacs.9b06852)


Jiang, Z.; He, H.; Liu, H.; Thayumanavan, S. “Cellular Uptake Evaluation of Amphiphilic Polymer Assemblies: Importance of Interplay between Pharmacological and Genetic Approaches” Biomacromolecules, 2019, 20, 4407-4418 . (DOI: 10.1021/acs.biomac.9b01073)


Wang, M.; Gao, J.; Zhao, B.; Thayumanavan, S.and Vachet, R.W. “Efficient enrichment of glycopeptides by supramolecular nanoassemblies that use proximity-assisted covalent binding” Analyst, 2019, 144, 6321-6326 . (DOI: 10.1039/C9AN01113G)


Liu, B. and Thayumanavan, S. “Three-Component Sequential Reactions for Polymeric Nanoparticles with Tailorable Core and Surface Functionalities” Chem, 2019, 5, 3166-3183 . (DOI: 10.1016/j.chempr.2019.09.001)


Hudson, R.; Adhikari, R.; Tuominen, M.; Hanzu, I.; Wilkening, M.; Thayumanavan, S.; Katz, J. L. “Evaluation of Carboxylic, Phosphonic and Sulfonic acid Protogenic Moieties on Tunable Poly(meta-phenylene oxide) Ionomer Scaffolds” J.Poly. Sci. Part A., Poly. Chem. 2019, 57, 2209-2213 . (DOI: 10.1002/pola.29503)


Liu, B.; Ianosi-Irimie, M.; Thayumanavan, S. “Reversible Click Chemistry for Ultrafast and Quantitative Formation of Protein-Polymer Nanoassembly and Intracellular Protein Delivery” ACS Nano, 2019, 13, 9408-9420 . (DOI: 10.1021/acsnano.9b04198)


Dutta, K.; Bochicchio, D.; Ribbe, A.E.; Alfandari, D.; Mager, J.; Pavan, G.M.; Thayumanavan, S. “Symbiotic Self-Assembly Strategy toward Lipid-Encased Cross-Linked Polymer Nanoparticles for Efficient Gene Silencing” ACS Appl. Mater. Interfaces 2019, 11, 24971-24983 . (DOI: 10.1021/acsami.9b04731)


Raghupathi, K.; Kumar, V.; Sridhar, U.; Ribbe, A.E.; He, H.; Thayumanavan, S. “Role of Oligoethylene Glycol Side Chain Length in Responsive Polymeric Nanoassemblies” Langmuir, 2019, 35, 7929-7936 . (DOI: 10.1021/acs.langmuir.9b00676)


Schlueter, J. A.; Homnick, P. J.; Della Pelle, A. M.; Lahti, P. M.; Thayumanavan, S. “Tuning N,N-Diarylanilinosquaraine Crystal Packing: n-Hexylaryl and Fluoroaryl Substitution” Cryst. Growth & Design, 2019, 19, 3633-3638 . (DOI: 10.1021/acs.cgd.8b01621)


Strahan, J.; Popere, B.C.; Khomein, P.; Pointer, C.A.; Martin, S.M.; Oldacre, A.N.; Thayumanavan, S.; Young, E.R. “Modulating absorption and charge transfer in bodipy-carbazole donor-acceptor dyads through molecular design” Dalton Trans., 2019, 48, 8488-8501 . (DOI: 10.1039/C9DT00094A)


Jiang, Z.; Cui, W.; Mager, J.; Thayumanavan, S. “Postfunctionalization of Noncationic RNA-polymer Complexes for RNA Delivery” Ind. Eng. Chem. Res. 2019, 58, 6982-6991. (DOI: 10.1021/acs.iecr.9b00666)


Singh, K.; Ejaz, W.; Dutta, K.; Thayumanavan, S. “Antibody Delivery for Intracellular Targets – Emergent Therapeutic Potential” Bioconjugate Chem. 2019, 30, 1028-1041. (DOI: 10.1021/acs.bioconjchem.9b00025)


Zhuang, J.; Zhao, B.; Thayumanavan, S. “Cascaded Step-Growth Polymerization for Functional Polyamides with Diverse Architectures and Stimuli Responsive Characteristics” ACS Macro Lett. 2019, 8, 245–249. (DOI: 10.1021/acsmacrolett.9b00094)


Khomein, P.; Dutta, K.; Gnanasekaran, K.; Gianneschi, N. C.; Thayumanavan, S. “Spatiotemporal Control over the Host–guest Characteristics of a Stimulus-triggerable Trifunctional Polymer Assembly” Polym. Chem. 2019, 10, 1423-1430 . (DOI: 10.1039/C8PY01788C)


Gao, J.; Wang, H.; Zhuang, J.; Thayumanavan, S. “Tunable Enzyme Responses in Amphiphilic Nanoassemblies through Alterations in the Unimer–aggregate Equilibrium” Chem. Sci. 2019, 10, 3018-3024. (DOI: 10.1039/C8SC04744H)


Munkhbat, O.; Canakci, M.; Zheng, S.; Hu, W.; Osborne, B.; Bogdanov, A. A.; Thayumanavan, S. “19F MRI Imaging of Polymer Nanogels Aided by Improved Segmental Mobility of Embedded Fluorine Moieties” Biomacromolecules 2019, 20, 790–800. (DOI: 10.1021/acs.biomac.8b01383)


Jiang, Z.; Cui, W.; Prasad, P.; Touve, M. A.; Gianneschi, N. C.; Mager, J.; Thayumanavan, S. “Bait-and-Switch Supramolecular Strategy To Generate Noncationic RNA–Polymer Complexes for RNA Delivery” Biomacromolecules 2019, 20, 435–442. (DOI: 10.1021/acs.biomac.8b01321)


Song, C.; Lin, T.; Zhang, Q.; Thayumanavan, S.; Ren, L. “pH-Sensitive Morphological Transitions in Polymeric Tadpole Assemblies for Programmed Tumor Therapy” J. Control. Release 2019, 293, 1-9. (DOI: 10.1016/j.jconrel.2018.10.033)


He, H.; Liu, B.; Wang, M.; Vachet, R. W.; Thayumanavan, S. “Sequential Nucleophilic ‘Click’ Reactions for Functional Amphiphilic Homopolymers” Polym. Chem. 2019, 10, 187-193. (DOI: 10.1039/C8PY01341A)


Zhuang, J.; Secinti, H.; Zhao, B.; Thayumanavan, S. “Propagation of Enzyme Induced Surface Events Inside Polymer Nanoassemblies for a Fast and Tunable Response” Angew. Chem. Int. Ed. 2018, 57, 7111-7115. (DOI: 10.1002/anie.201803029)


Molla, M. R.; Rangadurai, P.; Antony, L.; Swaminathan, S.; de Pablo, J. J.; Thayumanavan, S. “Dynamic Actuation of Glassy Polymersomes through Isomerization of a Single Azobenzene Unit at the Block Copolymer Interface” Nat. Chem. 2018, 10, 659–666. (DOI: 10.1038/s41557-018-0027-6)
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Serrano, M. A. C.; Gao, J.; Kelly, K. A.; Thayumanavan, S.; Vachet, R. W. “Supramolecular Polymeric Assemblies for the Selective Depletion of Abundant Acidic Proteins in Serum” ACS Appl. Mater. Interfaces 2018, 10, 40443–40451. (DOI: 10.1021/acsami.8b15976)


Ramezani-Dakhel, H.; Rahimi, M.; Pendery, J.; Kim, Y.-K.; Thayumanavan, S.; Roux, B.; Abbott, N. L.; de Pablo, J. J. “Amphiphile Induced Phase Transition of Liquid Crystals at Aqueous Interfaces” ACS Appl. Mater. Interfaces 2018, 10, 37618–37624. (DOI: 10.1021/acsami.8b09639)


Kim, Y.-K.; Raghupathi, K. R.; Pendery, J. S.; Khomein, P.; Sridhar, U.; de Pablo, J. J.; Thayumanavan, S.; Abbott, N. L. “Oligomers as Triggers for Responsive Liquid Crystals” Langmuir 2018, 34, 10092–10101. (DOI: 10.1021/acs.langmuir.8b01944)


Leriche, G.; Manafirad, A.; Nguyen, S.; Bell, N.; Patterson, J. P.; Thayumanavan, S.; Yang, J.; Dinsmore, A. D.; Gianneschi, N. C. “Water Permeability and Elastic Properties of an Archaea Inspired Lipid Synthesized by Click Chemistry” Chem. Mater. 2018, 30, 3618–3622. (DOI: 10.1021/acs.chemmater.8b00992)


Wanwong, S.; Khomein, P.; Thayumanavan, S. “BODIPY Dyads and Triads: Synthesis, Optical, Electrochemical and Transistor Properties” Chem. Central J. 2018, 12, 60. (DOI: 10.1186/s13065-018-0430-5)


Serrano, M. A. C.; Zhao, B.; He, H.; Thayumanavan, S.; Vachet, R. W. “Molecular Features Influencing the Release of Peptides from Amphiphilic Polymeric Reverse Micelles” Langmuir 2018, 34, 4595–4602. (DOI: 10.1021/acs.langmuir.7b04065)


Zhao, B.; Serrano, M. A. C.; Wang, M.; Liu, T.; Gordon, M. R.; Thayumanavan, S.; Vachet, R. W. “Improved Mass Spectrometric Detection of Acidic Peptides by Variations in the Functional Group pKa Values of Reverse Micelle Extraction Agents” Analyst 2018, 143, 1434-1443. (DOI: 10.1039/C7AN02094E)


Gao, J.; Zhao, B.; Wang, M.; Serrano, M. A. C.; Zhuang, J.; Ray, M.; Rotello, V. M.; Vachet, R. W.; Thayumanavan, S. “Supramolecular Assemblies for Transporting Proteins Across an Immiscible Solvent Interface” J. Am. Chem. Soc. 2018, 7, 2421-2425. (DOI: 10.1021/jacs.7b13245)


Gordon, M. R.; Zhuang, J.; Ventura, J.; Li, L.; Raghupathi, K.; Thayumanavan, S. “Biodistribution Analysis of NIR-Labeled Nanogels using In Vivo FMT Imaging in Triple Negative Human Mammary Carcinoma Models” Mol. Pharmaceutics 2018, 15, 1180–1191. (DOI: 10.1021/acs.molpharmaceut.7b01011)


Gordon, M. R.; Zhao, B.; Anson, F.; Fernandez, A.; Singh, K.; Homyak, C.; Canakci, M.; Vachet, R. W.; Thayumanavan, S. “Matrix Metalloproteinase-9 Responsive Nanogels for Proximal Surface Conversion and Activated Cellular Uptake” Biomacromolecules 2018, 19, 860-871. (DOI: 10.1021/acs.biomac.7b01659)


Gao, J.; Liu, X.; Secinti, H.; Jiang, Z.; Munkhbat, O.; Xu, Y.; Guo, X.; Thayumanavan, S. “Photoactivation of Ligands for Extrinsically and Intrinsically Triggered Disassembly of Amphiphilic Nanoassemblies” Chem. Eur. J. 2018, 24, 1789–1794. (DOI: 10.1002/chem.201705217)


Zhao, B.; Serrano, M. A. C.; Gao, J.; Zhuang, J.; Vachet, R. W.; Thayumanavan, S. “Self-assembly of Random Co-polymers for Selective Binding and Detection of Peptides” Polym. Chem. 2018, 9, 1066-1071. (DOI: 10.1039/C7PY01947E)


Homyak, C. C.; Fernandez, A.; Touve, M. A.; Zhao, B.; Anson, F.; Hardy, J. A.; Vachet, R. W.; Gianneschi, N. C.; Ross, J. L.; Thayumanavan, S. “Lipogels for Encapsulation of Hydrophilic Proteins and Hydrophobic Small Molecules” Biomacromolecules 2018, 19, 132–140. (DOI: 10.1021/acs.biomac.7b01300)


Khomein, P.; Swaminathan, S.; Young, E. R.; Thayumanavan, S. “Fluorescence Enhancement Through Incorporation of Chromophores in Polymeric Nanoparticles” J. Inorg. Organomet. Polym. Mater. 2018, 28, 407-413. (DOI: 10.1007/s10904-017-0670-1)


Zhao, B.; Zhuang, J.; Serrano, M. A. C.; Vachet, R. W.; Thayumanavan, S. “Influence of Charge Density on Host–Guest Interactions within Amphiphilic Polymer Assemblies in Apolar Media” Macromolecules 2017, 50, 9734–9741. (DOI: 10.1021/acs.macromol.7b02434)


Liu, B.; Thayumanavan, S. “Importance of Evaluating Dynamic Encapsulation Stability of Amphiphilic Assemblies in Serum” Biomacromolecules 2017, 18, 4163–4170. (DOI: 10.1021/acs.biomac.7b01220)


Raghupathi, K.; Eron, S. J.; Anson, F.; Hardy, J. A.; Thayumanavan, S. “Utilizing Inverse Emulsion Polymerization to Generate Responsive Nanogels for Cytosolic Protein Delivery” Mol. Pharm. 2017, 14, 4515–4524. (DOI: 10.1021/acs.molpharmaceut.7b00643)


Wang, M.; Zhao, B.; Gao, J.; He, H.; Castellanos, L. J.; Thayumanavan, S.; Vachet, R. W. “Altering the Peptide Binding Selectivity of Polymeric Reverse Micelle Assemblies via Metal Ion Loading” Langmuir 2017, 33, 14004–14010. (DOI: 10.1021/acs.langmuir.7b02488)
[Featured as cover image, ACS Editors’ Choice]


Dutta, K.; Hu, D.; Zhao, B.; Ribbe, A.; Zhuang, J.; Thayumanavan, S. “Templated Self-Assembly of a Covalent Polymer Network for Intracellular Protein Delivery and Traceless Release” J. Am. Chem. Soc. 2017, 139, 5676–5679. (DOI: 10.1021/jacs.7b01214)
[Highlighted by]


Khomein, P.; Thayumanavan, S. “Effect of Incorporating Flat Aromatic Molecules on Spherical Polymeric Nanoparticles” Chem. Commun. 2017, 53, 5190-5192. (DOI: 10.1039/C7CC00963A)


Raghupathi, K.; Thayumanavan, S. “Nano-Armoring of Enzymes: Rational Design of Polymer-Wrapped Enzymes” Methods Enzymol. 2017, 590, 381–411. (DOI: 10.1016/bs.mie.2017.01.007)


Zhuang, J.; Garzoni, M.; Torres, D. A.; Poe, A.; Pavan, P. M.; Thayumanavan, S. “Programmable Nanoassemblies from Non-Assembling Homopolymers Using Ad Hoc Electrostatic Interactions” Angew. Chem. Int. Ed. 2017, 56, 4145–4149. (DOI: 10.1002/anie.201611688)


Liu, B.; Thayumanavan, S. “Substituent Effects on the pH Sensitivity of Acetals and Ketals and Their Correlation with Encapsulation Stability in Polymeric Nanogels” J. Am. Soc. Chem. 2017, 139, 2306–2317. (DOI: 10.1021/jacs.6b11181)


Serrano, M. A. C.; He, H.; Zhao, B.; Ramireddy, R. R.; Vachet, R. W.; Thayumanavan, S. “Polymer-Mediated Ternary Supramolecular Interactions for Sensitive Detection of Peptides” Analyst 2017, 142, 118–122. (DOI: 10.1039/C6AN01591C)


Homyak, C.; Anson. F.; Thayumanavan, S. “Supramolecular Polymers in Nanomedicine” Comprehensive Supramolecular Chemistry II, 2016, Elsevier Inc. Ed. J. W. Atwood. (DOI: 10.1016/B978-0-12-409547-2.12566-1)


Hendel, S. J.; Poe, A. M.; Khomein, P.; Bae, Y.; Thayumanavan, S.; Young, E. R. “Photophysical and Electrochemical Characterization of BODIPY-Containing Dyads Comparing the Influence of an A–D–A versus D–A Motif on Excited-State Photophysics” J. Phys. Chem. A 2016, 120, 8794–8803. (DOI: 10.1021/acs.jpca.6b06590)


Liu, X.; Ding, H.; Jiang, Z.; Zhuang, J.; Xu, Y.; Guo, X.; Thayumanavan, S. “Multi-Stimuli-Responsive Amphiphilic Assemblies through Simple Postpolymerization Modifications” Macromolecules 2016, 49, 6186–6192. (DOI: 10.1021/acs.macromol.6b01397)


Bai, W.; Jiang, Z.; Ribbe, A. E.; Thayumanavan, S. “Smart Organic Two-Dimensional Materials Based on a Rational Combination of Non-covalent Interactions” Angew. Chem. Int. Ed. 2016, 55, 10707–10711. (DOI: 10.1002/anie.201605050)


Rangadurai, P.; Molla, M. R.; Prasad, P.; Caissy, M.; Thayumanavan, S. “Temporal and Triggered Evolution of Host-Guest Characteristics in Amphiphilic Polymer Assemblies” J. Am. Chem. Soc. 2016, 138, 7508–7511. (DOI: 10.1021/jacs.6b04099)


Munkhbat, O.; Garzoni, M.; Raghupathi, K. R.; Pavan, G. M.; Thayumanavan, S. “Role of Aromatic Interactions in Temperature-Sensitive Amphiphilic Supramolecular Assemblies” Langmuir 2016, 32, 2874–2881. (DOI: 10.1021/acs.langmuir.5b04540)


Wang, H.; Zhuang, J.; Raghupathi, K. R.; Thayumanavan, S. “A Supramolecular Dissociation Strategy for Protein Sensing” Chem. Commun. 2015, 51, 17265–17268. (DOI: 10.1039/C5CC07408H)


Prasad, P.; Molla, M. R.; Cui, W.; Canakci, M.; Osborne, B.; Mager, J.; Thayumanavan, S. “Polyamide Nanogels from GRAS Components and Their Toxicity in Mouse Pre-implantation Embryos” Biomacromolecules 2015, 16, 3491–3498. (DOI: 10.1021/acs.biomac.5b00900)


Li, L.; Yuan, C.; Chen, D.; Ribbe, A. E.; Kittilstved, K. Thayumanavan, S. “Utilizing Reversible Interactions in Polymeric Nanoparticles to Generate Hollow Metal Organic Nanoparticles” Angew. Chem. Int. Ed. 2015, 54, 12991–12995. (DOI: 10.1002/anie.201505242)


Ventura, J.; Eron, S. J.; González-Toro, D. C.; Raghpathi, K. R.; Wang, F.; Hardy, J. A.; Thayumanavan, S. “Reactive Self-Assembly of Polymers and Proteins to Reversibly Silence a Killer Protein” Biomacromolecules 2015, 16, 3161–3171. (DOI: 10.1021/acs.biomac.5b00779)


Gordon, M. R.; Canakci, M.; Li, L.; Zhuang, J.; Osborne, B.; Thayumanavan, S. “Field Guide to Challenges and Opportunities in Antibody-Drug Conjugates for Chemists” Bioconjugate Chem. 2015, 26, 2198–2215. (DOI: 10.1021/acs.bioconjchem.5b00399)


Bell, N. C.; Doyle, S. J.; Battistelli, G.; LeGuyader, C. L. M.; Thompson, M. P.; Poe, A.; Montalti, M.; Thayumanavan, S.; Tauber, M. J.; Gianneschi, N. C. “Dye Encapsulation in Polybornene Micelles” Langmuir 2015, 31, 9707–9717. (DOI: 10.1021/acs.langmuir.5b01822)


Ramireddy, R. R.; Prasad, P.; Fine, A.; Thayumanavan, S. “Zwitterionic Amphiphilic Homopolymer Assemblies” Polym. Chem. 2015, 6, 6083-6087. (DOI: 10.1039/C5PY00879D)


Molla, M. R.; Prasad, P.; Thayumanavan, S. “Protein‐Induced Supramolecular Disassembly of Amphiphilic Polypeptide Nanoassemblies” J. Am. Chem. Soc. 2015, 137, 7286-7289. (DOI: 10.1021/jacs.5b04285) (R,S)170


Song, C.; Li, L.; Dai, L.; Thayumanavan, S. “Responsive Single Chain Polymer Nanoparticles with Host-Guest Features” Polym. Chem. 2015, 6, 4828-4834. (DOI: 10.1039/C5PY00600G) (R)



Raghupathi, K. R.; Sridhar, U.; Byrne, K.; Raghupathi, K. R.; Thayumanavan, S. “Influence of Backbone Conformational Rigidity in Temperature-Sensitive Amphiphilic Supramolecular Assemblies” J. Am. Chem. Soc. 2015, 137, 5308-5311 (DOI: 10.1021/jacs.5b02108). (R, S)168


Wang, Hui; Raghupathi, K.; Zhuang, J.; Thayumanavan, S. “Activatable Dendritic 19F Probes for Enzyme Detection” ACS Macro Letters, 2015, 4, 422-425 (DOI: 10.1021/acsmacrolett.5b00199). (R, S)167


Poe, A.; Della Pelle, A. M.: Byrnes, S.; Thayumanavan, S. “Effective Tuning of Ketocyanine Derivatives Through Acceptor Substitution” Chem. Eur. J. 2015, 21, 7721-7725  (DOI: 10.1002/chem.201406625). (E)



Yuan, C.; Chang, Y.; Mao, J.; Yu, S.; Luo, W.; Xu, Y.; Thayumanavan, S.; Dai, L. “Supramolecular Assembly of Crosslinkable Monomers for Degradable and Fluorescent Polymer Nanoparticles” J. Mater. Chem. B. , 2015, 2858-2866  (DOI: 10.1039/c4tb01880j).  (R,S)





Li, L.; Song, C.; Jennings, M.; Thayumanavan, S. “Photoinduced Heterodisulfide Metathesis for Reagent-free Synthesis of Polymer Nanoparticles” Chem. Commun. 2015, 51, 1425-1428 (DOI: 10.1039/c4cc08000a). (R)



Molla, M. R.; Rangadurai, P.; Pavan, G. M.; Thayumanavan, S. “Experimental and Theoretical Investigations in Stimuli Responsive Dendrimer-based Assemblies” Nanoscale, 2015, 7, 3817-3837 (DOI: 10.1039/C4NR04563G). (R,S)



Molla, M. R.; Marcinko, T.; Prasad, P.; Deming, D.; Garman, S.; Thayumanavan, S. “Unlocking a Caged Lysosomal Protein from a Polymeric Nanogel with a pH Trigger” Biomacromolecules, 2014, 15, 4046-4053 (DOI: 10.1021/bm501091p). (R,S)



Li, L.; Thayumanavan, S. “Environment-Dependent Guest-Exchange in Supramolecular Hosts” Langmuir, 2014, 30, 12384-12390 (DOI: 10.1021/la502760c). (R,S)



Li, L.; Yuan, C.; Dai, L.; Thayumanavan, S. “Thermo-responsive Polymeric Nanoparticles: Nucleation from Cooperative Polymerization Driven by Dative Bonds” Macromolecules, 2014, 47, 5869-5876 (DOI: 10.1021/ma5015808). (R,S)



Karak, S.; Homnick, P.; Della Pelle, A. M.; Bae, Y.; Duzhko, V.; Liu, F.; Russell, T. P.; Lahti, P. M.; Thayumanavan, S. “Crystallinity and Morphology Effects on a Solvent-Processed Solar Cell Using a Triarylamine-Substituted Squaraine” “ACS Appl. Mater. Interfaces, 2014, 6, 11376-11384 (E) 159


Li, L; Raghupathi, K. R.; Song, C.; Prasad, P.; Thayumanavan, S. “Self-assembly of Random Copolymers”  Chem. Commun., 2014, 50, 13417-13432, (Invited Review), DOI: 10.1039/C4CC03688C. (S)



Kokil, A.; Poe, A.; Bae, Y.; Della Pelle, A. M.; Homnick, P.; Lahti, P. M.; Kumar, J.; Thayumanavan, S. “Improved Performances in Polymer BHJ Solar Cells Through Frontier Orbital Tuning of Small Molecule Additives in Ternary Blends” ACS Appl. Mater. Interfaces, 2014, 6, 9920-9924  (DOI: 10.1021/am5021759). (E)



Raghupathi, K.; Guo, J.; Munkhbat, O.; Rangadurai, P.; Thayumanavan, S. “Supramolecular Assembly and Disassembly of Facially Amphiphilic Dendrimers” Acc. Chem. Res. 201447, 2200-2211 (Invited Review)  (DOI: 10.1021/ar500143u) (PMCID# PMC4100797). (R,S)



Amado Torres, D.; Garzoni, M.; Subrahmanyam, A.; Pavan, G. M.; Thayumanavan, S. “Protein-Triggered Supramolecular Disassembly: Insights Based on Variations in Ligand Location in Amphiphilic Dendrons” J. Am. Chem. Soc. 2014, 136, 5385-5399. (DOI: 10.1021/ja500634u ) (R,S) 155


Wanwong, S.; Poe, A.; Ganapathy, B.; Thayumanavan, S. “Effect of Heteroatom and Conformation on Optoelectronic Properties of Cyclopentadithiophenes Derivatives” Org. Biomol. Chem. 2014, 12, 2474-2478. (DOI:10.1039/C3OB41648H) (E)



Guo, J.; Zhuang, J.; Wang, F.; Raghupathi, K.; Thayumanavan, S. “Protein AND Enzyme Gated Supramolecular Disassembly”  J. Am. Chem. Soc. 2014, 136, 2220-2223   (DOI: 10.1021/ja4108676) (R,S). 



Poe, A.; Della Pelle, A. M.; Subrahmanyam, A.; White, W. N.; Wantz, G.; Thayumanavan, S. “Small Molecule BODIPY Dyes as non-Fullerene Acceptors in Bulk Heterojunction Organic Photovoltaics” Chem. Commun. 2014, 50, 2913-2915   (DOI:10.1039/C3CC49648A) (E)



Della Pelle, A. M.; Homnick, P.; Bae, Y.; Lahti, P. M.; Thayumanavan, S. “Effect of Substituents on Optical Properties and Charge Carrier Polarity of Squaraine Dyes” J. Phys. Chem. C.  2014, 118, 1793-1799  (DOI: 10.1021/jp410362d) (E).



Zhuang, J.; Chacko, R.; Amado Torres, D.; Wang, H.; Thayumanavan, S. “Dual Stimuli – Dual Response Nanoassemblies Prepared from a Simple Homopolymer” ACS Macro Lett. 2014, 3, 1-5 (DOI: 10.1021/mz400515s) (R,S).



Raghupathi, K.; Li, L.; Ventura, J.; Jennings, M.; Thayumanavan, S. “pH Responsive Soft Nanoclusters with Size and Charge Conversional Features” Polym. Chem. 2014, 5, 1737-1742. (DOI:10.1039/C3PY01277H) (R,S)



Yuan, C.; Raghupathi, K.; Popere, B. C.; Ventura, J.; Dai, L.; Thayumanavan, S. “Composite Supramolecular Nanoassemblies with Independent Stimulus Sensitivities”  Chem. Sci. 2014, 5, 229-234. (DOI:10.1039/C3SC52347K) (R,S)




Wang, H.; Zhuang, J.; Thayumanavan, S. ““Functionalizable Amine-based Polymer Nanoparticles” ACS Macro Lett. 2013, 2, 948-951. (DOI: 10.1021/mz4004248) (R,S)



Wang, F.; Gomez-Escudero, A.; Ramireddy, R. R.; Murage, G.; Thayumanavan, S.; Vachet, R. W. “Electrostatic Control of Peptide Side-Chain Reactivity using Amphiphilic Homopolymer-based Supramolecular Assemblies” J. Am. Chem. Soc. 2013, 135, 14179-14188. (DOI: 10.1021/ja404940s) (S)



Ramireddy, R.; Subrahmanyam, A.; Thayumanavan, S. “Zwitterionic Moieties from the Huisgen Reaction-A Case Study with Amphiphilic Dendritic Assemblies” Chem. Eur. J., 2013, 19, 16374-16381. (S)



Li, L.; Raghupathi, K.; Yuan, C.; Thayumanavan, S. “Surface Charge Generation in Nanogels for Activated Cellular Uptake at Tumor-Relevant pH” Chem. Sci. 2013, 4, 3654-3660. (DOI: 10.1039/C3SC50899D) (R,S)144



Fuller, J.; Raghupathi, K.; Ramireddy, R. R.; Subrahmanyam, A.; Yesilyurt, V.; Thayumanavan, S. “Temperature-Sensitive Transitions Below LCST in Amphiphilic Dendritic Assemblies – Host-Guest Implications” J. Am. Chem. Soc. 2013, 135, 8947-8954. (DOI: 10.1021/ja402019c) (R,S)


Zhuang, J.; Gordon, M.; Ventura, J.; Li, L. Thayumanavan, S. “Multi-Stimuli Responsive Macromolecules and Their Assemblies” Chem. Soc. Rev. 2013, 42, 7421-7435. (DOI: 10.1039/C3CS60094G) (R, S)


González-Toro, D.; Thayumanavan, S. “Advances in Polymer and Polymeric Nanostructures for Protein Conjugation” Eur. Poly. J. 2013, 49, 2906-2918. (DOI: 10.1016/j.eurpolymj.2013.05.002) (R)


Matsumoto, N.; Gonzalez-Toro, D.; Chacko, R.; Maynard, H. D.; Thayumanavan, S. “Synthesis of Nanogel-Protein Conjugates” Polymer Chem. 2013, 4, 2464-2469. (DOI: 10.1039/c3py00085k) (R)


Li, L.; Ryu, J.; Thayumanavan, S. “Effect of Hofmeister Ions on the Size and Encapsulation Stability in Polymer Nanogels” Langmuir, 2013, 29, 50-55. (DOI: 10.1021/la3033463) (R)


Bickerton, S.; Jiwpanich, S.; Thayumanavan, S. “Interconnected Roles of Scaffold Hydrophobicity, Drug Loading and Encapsulation Stability in Polymeric Nanocarriers” Mol. Pharm. 2012, 9, 3569-3578. (DOI: 1021/mp3004226) (R, S)


Siripornnopakhun, W.; Niamnont, N.; Krumsri, A.; Tumcharern, G.; Vilaivan, T.; Rashatasakhon, P.; Thayumanavan, S.; Sukwattanasinitt, M. “Inclusion Complexes between Amphiphilic Phenylene-Ethynylene Fluorophores and Cyclodextrins in Aqueous Media” J. Phys. Chem. B. 2012, 116, 12268-12274. (DOI: 10.1021/jp3057652) (S)


Popere, B.; Della Pelle, A.; Poe, A.; Balaji, G.; Thayumanavan, S. “Predictably Tuning the Frontier Molecular Orbital Energy Levels of Panchromatic BODIPY-Based Conjugated Polymers Chem. Sci. 2012, 3, 3093-3102. (DOI: 10.1039/C2SC20731A) (E)


Della Pelle, A.; Maliakal, A.; Sidorenko, A.; Thayumanavan, S. “Effect of Titanium Oxide-Polystyrene Nanocomposite Dielectrics on Morphology and Thin Film Transistor Performance for Organic and Polymeric Semiconductors” Thin Solid Films, 2012, 520, 6262-6267. (DOI: 10.1016/j.tsf.2012.05.075) (E)


Gonzalez-Toro, D.; Ryu, J.-H.; Chacko, R.; Zhuang, J.; Thayumanavan, S. “Concurrent Binding and Delivery of Proteins and Lipophilic Small Molecules Using Polymeric Nanogels” J. Am. Chem. Soc. 2012, 134, 6964-6967. (DOI: 10.1021/ja3019143) (R)


Ryu, J.; Bickerton, S.; Zhuang, J.; Thayumanavan, S. “Ligand-Decorated Nanogels: Fast One-Pot Synthesis and Cellular Targeting” Biomacromolecules, 2012, 13, 1515-1522. (DOI: 10.1021/bm300201x) (R)


Amado Torres, D.; Azagarsamy, M.; Thayumanavan, S. “Supramolecular Displacement-Mediated Activation of a Silent Fluorescence Probe for Label-free Ligand Screening” J. Am. Chem. Soc. 2012, 134, 7235-7237. (DOI: 10.1021/ja301204z) (S)


Ganapathy, B.; Della Pelle, A.; Popere, B.; Chandrasekaran, A.; Thayumanavan, S. “Synthesis and Properties of Thienopyrrole Based Heteroacenes – Indolodibenzothienopyrrole and Dicarbazolodithieno-pyrrole” Org. Biomol. Chem. 2012, 10, 3455-3462. (DOI: 10.1039/C2OB25087J) (E)


Chacko, R.; Ventura, J.; Zhuang, J.; Thayumanavan, S. “Polymer Nanogels: A Versatile Nanoscopic Drug Delivery Platform” Adv. Drug Deliv. Rev. 2012, 64, 836-851. (Invited Perspective) (DOI: 10.1016/j.addr.2012.02.002) (R)


Ramireddy, R.; Raghupathi, K. R.; Torres, D. A.; Thayumanavan, S. “Stimuli Sensitive Amphiphilic Dendrimers” New J. Chem. 2012, 26, 340-349. (Invited Perspective). (DOI: 10.1039/C2NJ20879B) (S)


Popere, B.; Della Pelle, A.; Poe, A.; Thayumanavan, S. “Macromolecular Architectures for Organic Photovoltaics” Phys. Chem., Chem. Phys. 2012, 14, 4043-4057 (Invited Perspective). (DOI: 10.1039/C2CP23422J) (E)


Zhuang, J.; Jiwpanich, S.; Deepak, V. D.; Thayumanavan, S. “Facile Preparation of Nanogels Using Activated Ester Containing Polymers” ACS Macro Lett. 2012, 1, 175-179. (DOI: 10.1021/mz200123f) (R)


Getmanenko, Y. A.; Hales, J. M.; Bahu, M.; Fu, J.; Zojer, E.; Kwon, O.; Mendez, J.; Thayumanavan, S.; Walker, G.; Zhang, Q.; Bunge, S. D.; Porter III, W. W.; Matzger, A. J.; Brédas, J.-L.; Hagan, D. J.; Van Stryland, E. W.; Barlow, S.; Marder, S. R. “Characterisation of a Dipolar Chromophore with Third-Harmonic Generation Applications in the Near-IR” J. Mater. Chem. 2012, 22, 4371-4382. (DOI: 10.1039/C2JM15599K) (E)


Rodthongkum, N.; Ramireddy, R.; Thayumanavan, S.; Vachet, R. W. “Selective Enrichment and Sensitive Detection of Peptide and Protein Biomarkers in Human Serum Using Polymeric Reverse Micelles and MALDI-MS” Analyst 2012, 137, 1024-1030. (DOI: 10.1039/C2AN16089G) (S)


Nagamani, C.; Guo, J.; Thayumanavan, S. “Synthesis and Characterization of Phenol-Based Biaryl Proton Conducting Polymers” J. Poly. Sci. Part A., Poly. Chem. 2012, 50, 1187-1196. (DOI: 10.1002/pola.25880) (E)


Yesilyurt, V.; Ramireddy, R.; Azhagarsamy, M. A.; Thayumanavan, S. “Accessing Lipophilic Ligands in Dendrimer-based Amphiphilic Supramolecular Assemblies for Protein-Induced Disassembly” Chem. Eur. J. 2012, 18, 223-229. (DOI: 10.1002/chem.201102727) (S)


Wang, F.; Klaikherd, A.; Thayumanavan, S. “Temperature Sensitivity Trends and Multi-Stimuli-Sensitive Behavior in Amphiphilic Oligomers” J. Am. Chem. Soc. 2011, 133, 13496-13503. (DOI: 10.1021/ja204121a) (S)


Popere, B.; Della Pelle, A.; Thayumanavan, S. “BODIPY-based Donor-Acceptor π-Conjugated Alternating Copolymers” Macromolecules, 2011, 44, 4767-4776. (DOI: 10.1021/ma200839q) (E)


Raghupathi, K. R.; Azagasarmy, M. A.; Thayumanavan, S. “Guest Release Control in Enzyme-Sensitive Amphiphilic Dendrimer-based Nanoparticles through Photochemical Crosslinking” Chem. Eur. J. 2011, 17, 11752-11760. (DOI: 10.1002/chem.201101066) (S)


Nagamani, C.; Viswanathan, U.; Versek, C.; Tuominen, M.; Auerbach, S. M.; Thayumanavan, S. “”Importance of Dynamic Hydrogen Bonds and Reorientation Barriers in Proton Transport” Chem. Commun. 2011, 47, 6638-6640. (DOI: 10.1039/C1CC11207D) (E, S)


Reddy, J. S.; Kale, T. S.; Balaji, G.; Chandrasekaran, A.; Thayumanavan, S. “Cyclopentadithiophene-Based Organic Semiconductors: Effect of Fluorinated Substituents on Electrochemical and Charge Transport Properties” J. Phys. Chem. Lett. 2011, 2, 648-654. (DOI: 10.1021/jz200126s) (E)


Yesilyurt, V.; Ramireddy, R.; Thayumanavan, S. “Photo-Regulated Release of Non-covalent Guests from Dendritic Amphiphilic Nanocontainers” Angew. Chem. It. Ed. 2011, 50, 3038-3042. (DOI: 10.1002/anie.201006193) (S)


Ganapathy, B.; Kale, T.; Keerthi, A.; Della Pelle, A.; Thayumanavan, S.; Valiyaveetil, S. “Low Bandgap Thiophene-Perylene Diimide Systems with Tunable Charge Transport Properties” Org. Lett. 2011, 13, 18-21. (DOI: 10.1021/ol1023486) (E)


Ryu, J.-H.; Chacko, R.; Jiwpanich, S.; Bickerton, S.; Babu, R. P.; Thayumanavan, S. “Self-Crosslinked Polymer Nanogels: a Versatile Nanoscopic Drug Delivery Platform” J. Am. Chem. Soc. 2010, 132, 17227-17235. (DOI: 10.1021/ja1069932) (R)


Jiwpanich, S.; Ryu, J.-H.; Bickerton, S.; Thayumanavan, S. “Noncovalent Encapsulation Stability in Supramolecular Nanoassemblies” J. Am. Chem. Soc. 2010, 132, 10683-10685. (DOI: 10.1021/ja105059g) (R, S)


Rodthongkum, N.; Chen, Y.; Thayumanavan, S.; Vachet, R. W. “Selective Enrichment and Analysis of Acidic Peptides and Proteins Using Polymeric Reverse Micelles and MALDI-MS” Anal. Chem. 2010, 82, 8686-8691. (DOI: 10.1021/ac101922b) (S)


Subrahmanyam, A. V.; Thayumanavan, S.; Huber, G. W. “C-C Bond Formation Reactions for Biomass-Derived Molecules” Chem. SusChem. 2010, 3, 1158-1161. (DOI: 10.1002/cssc.201000136) (E)


Satav, S.; Bhat, S.; Thayumanavan, S. “Feedback Regulated Drug Delivery Vehicles: Carbon Dioxide Responsive Cationic Hydrogels for Antidote Release” Biomacromolecules, 2010, 11, 1735-1740. (DOI: 10.1021/bm1005454) (R)


Ryu, J.-H.; Jiwpanich, S.; Chacko, R.; Bickerton, S.; Thayumanavan, S. “Surface-Functionalizable Polymer Nanogels with Facile Hydrophobic Guest Encapsulation Capabilities” J. Am. Chem. Soc. 2010, 132, 8246-8247. (DOI: 10.1021/ja102316a) (R)


Rodthongkum, N.; Chen, Y.; Thayumanavan, S.; Vachet, R. W. “MALDI-MS Signal Enhancement of Peptides after Selective Extraction with Polymeric Reverse Micelles” Anal. Chem. 2010, 82, 3686-3691. (DOI: 10.1021/ac1000256) (S)


Azagarsamy, M.; Yesilyurt, V.; Thayumanavan, S. “Disassembly of Dendritic Micellar Containers due to Protein Binding” J. Am. Chem. Soc. 2010, 132, 4550-4551. (DOI: 10.1021/ja100746d) (S)


Kale, T.; Krishnamoorthy, K.; Thelakkat, M.; Thayumanavan, S. “Charge Mobility in Non-Conjugated Dendrons with Charge Transport Functionality in Every Layer” J. Phys. Chem. Lett. 2010, 1, 1116-1121. (DOI: 10.1021/jz1002204) (E)


Chen, Y.; Thorn, M.; Christensen, S.; Versek, C.; Poe, A.; Hayward, R. C.; Tuominen, M. T.; Thayumanavan, S. “Enhancement of Anhydrous Proton Transport by Supramolecular Nanochannels in Comb Polymers” Nature Chem. 2010, 2, 503-508. (DOI: 10.1038/nchem.629) (E, S)


Chikkanagari, N.; Versek, C.; Thorn, M.; Tuominen, M. T.; Thayumanavan, S. “Proton Conduction in 1H-1,2,3-triazole Polymers: Imidazole-like or Pyrazole-like?” J. Poly. Sci. Part A. Poly Chem. 2010, 48, 1851-1858. (DOI: 10.1002/pola.23932) (E)


Ryu, J.; Roy, R.; Ventura, J.; Thayumanavan, S. “Redox-Sensitive Disassembly of Amphiphilic Copolymer Based Micelles” Langmuir, 2010, 26, 7086-7092. (DOI: 10.1021/la904437u) (S)


Nantalaksakul, A.; Krishnamoorthy, K.; Thayumanavan, S. “Broadening Absorption in Conductive Polymers through Cross-linkable Side Chains in a Non-conjugated Polymer Backbone” Macromolecules, 2010, 43, 37-43. (DOI: 10.1021/ma901850z) (E)


Azagarsamy, M.; Krishnamoorthy, K.; Sivanandan, K.; Thayumanavan, S. “Site-specific Installation and Study of Electroactive Units in Every Layer of Dendrons” J. Org. Chem. 2009, 74, 9475-9485. (DOI: 10.1021/jo902109u) (S)


Azagarsamy, M.; Sokkalingam, P.; Thayumanavan, S. “Enzyme Triggered Disassembly of Dendrimer-based Amphiphilic Nanocontainers” J. Am. Chem. Soc. 2009, 131, 14184-14185. (DOI: 10.1021/ja906162u) (S)


Azagarsamy, M.; Thayumanavan, S. “Magnetic Resonance Imaging: Making Sense of Disassembly” Nature Chemistry, 2009, 1, 523-524. (DOI:10.1038/nchem.383) (S)


Ryu, J.; Park, S.; Kim, B.; Klaikherd, A.; Russell, T. P.; Thayumanavan, S. “Highly Ordered Gold Nanotubes using Thiols at a Cleavable Block Copolymer Interface” J. Am. Chem. Soc. 2009, 131, 9870-9871. (DOI: 10.1021/ja902567p) (R)


Chen, Y.; Thayumanavan, S. “Amphiphilicity in Homopolymer Surfaces Reduces Non-specific Protein Adsorption” Langmuir, 2009, 25, 13795-13799 (Invited manuscript for the 25th year anniversary of Langmuir). (DOI: 10.1021/la901692a) (S)


Roy, R.; Jerry, D. J.; Thayumanavan, S. “Virus-Inspired Approach to Nonviral Gene Delivery Vehicles” Biomacromolecules, 2009, 10, 2189-2193. (DOI: 10.1021/bm900370p) (R)


Rodthongkum, N.; Washington, J. D.; Savariar, E. N.; Thayumanavan, S.; Vachet, R. W. “Generating Peptide Titration-type Curves Using Polymeric Reverse Micelles as Selective Extraction Agents Along with MALDI-MS Detection” Anal. Chem. 2009, 81, 5046-5053. (DOI: 10.1021/ac900661e) (S)


Kale, T.; Klaikherd, A.; Popere, B.; Thayumanavan, S. “Supramolecular Assemblies of Amphiphilic Homopolymers” Langmuir, 2009, 25, 9660-9670 (Invited Feature Article). (DOI:10.1021/la900734d) (S)


González, D. C; Savariar, E. N.; Thayumanavan, S. “Fluorescence Patterns from Supramolecular Polymer Assembly and Disassembly for Sensing of Metallo- and Non-metalloproteins” J. Am. Chem. Soc. 2009, 131, 7708-7716. (DOI: 10.1021/ja900579g) (S)


Azagarsamy, M.A.; Gomez-Escudero, A.; Yesilyurt, V.; Vachet, R.W.; Thayumanavan, S. “Amphiphilic Nanoassemblies for the Detection of Peptides and Proteins Using Fluorescence and Mass Spectrometry” Analyst, 2009, 134, 635-649 (Invited Review). (DOI: 10.1039/B818484D) (S)


Klaikherd, A.; Chikkanagari, N.; Thayumanavan, S. “Multi-Stimuli Sensitive Amphiphilic Block Copolymer Assemblies” J. Am. Chem. Soc. 2009, 131, 4830-4838. (DOI: 10.1021/ja809475a) (R)


Nantalaksakul, A.; Mueller, A.; Klaikherd, A.; Bardeen, C. J.; Thayumanavan, S. “Dendritic and Linear Macromolecular Architectures for Photovoltaics: A Photoinduced Charge Transfer Investigation” J. Am. Chem. Soc. 2009, 131, 2727-2738. (DOI: 10.1021/ja809194u) (E)


Jiwpanich, S.; Sandanararj, B. S.; Thayumanavan, S. “Fluorophore-Cored Dendrimers for Patterns in Metalloprotein Sensing” Chem. Commun. 2009, 806-808. (DOI: 10.1039/B815263B) (S)


Ghosh, S.; Yesilyurt, V.; Savariar, E. N.; Irvin, K.; Thayumanavan, S. “Redox, Ionic Strength, and pH Sensitive Supramolecular Polymer Assemblies” J. Poly. Sci. Part A: Poly. Chem. 2009, 47, 1052-1060. (DOI: 10.1002/pola.23204) (R)


Savariar, E. N.; Kopelman, J.; Thayumanavan, S. “Supramolecular Assemblies from Amphiphilic Dendrons for Sensing Metalloproteins Through Pattern Generation” Israel J. Chem. 2009, 49, 41-47 (Invited article). (DOI: 10.1560/IJC.49.1.41) (S)


Savariar, E. N.; Sochat, M. M.; Klaikherd, A.; Thayumanavan, S. “Functional Group Density and Recognition in Polymer Nanotubes” Angew. Chem. Int. Ed. 2009, 48, 110-114. (DOI: 10.1002/anie.200804136) (R)


Gomez-Escudero, A.; Azagarsamy, M.A.; Theddu, N.; Vachet, R.W.; Thayumanavan, S. “Selective Peptide Binding Using Facially Amphiphilic Dendrimers” J. Am. Chem. Soc. 2008, 130, 11156-11163. (DOI: 10.1021/ja803082v) (S)


Savariar, E. N.; Ghosh, S.; González, D. C.; Thayumanavan, S. “Disassembly of Noncovalent Amphiphilic Polymers with Proteins and Utility in Pattern Sensing” J. Am. Chem. Soc. 2008, 130, 5416-5417.  (DOI: 10.1021/ja800164z) (R, S)


Savariar, E.N.; Krishnamoorthy, K.; Thayumanavan, S. “Molecular Discrimination Inside Polymer Nanotubules” Nature Nanotech. 2008, 3, 112-117. (DOI: 10.1038/nnano.2008.6) (S)


Klaikherd, A.; Ghosh, S.; Thayumanavan, S. “A Facile Method for the Synthesis of Cleavable Block Copolymers from ATRP-based Homopolymers” Macromolecules, 2007, 40, 8518-8520. (DOI: 10.1021/ma071852n) (R, S)


Combariza, Y.; Savariar, E. N.; Vutukuri, D. R; Thayumanavan, S.; Vachet, R. W. “Polymeric Inverse Micelles as Selective Peptide Extraction Agents for MALDI-MS Analysis” Anal. Chem. 2007, 79, 7124-7130. (DOI: 10.1021/ac071001d) (S)


Ambade, A.; Aathimanikandan, S. V.; van der Poll, D.; Thayumanavan, S. “Smaller Building Blocks Form Larger Assemblies: Aggregation Behavior of Biaryl-based Dendritic Facial Amphiphiles” J. Org. Chem. 2007, 72, 8167-8174. (DOI: 10.1021/jo070447r) (S)


Ghosh, S.; Irvin, K.; Thayumanavan, S. “Tunable Disassembly of Micelles Using a Redox Trigger” Langmuir 2007, 23, 7916-7919. (DOI: 10.1021/la700981z) (R)


Kim, Y.J.; Shin, D.; Vutukuri, D.; Savariar, E.N.; Kim, S.Y.; Thayumanavan, S.; Russell, T.P. “Globular Organization of Multifunctional Linear Homopolymer Using Trifunctional Molecules” Macromolecules, 2007, 40, 4267-4275. (DOI: 10.1021/ma070170x) (R)


Ambade, A.; Chen, Y.; Thayumanavan, S. “”Controlled Functional Group Presentations in Dendrimers as a Tool to Probe the Hyperbranched Architecture” New J. Chem. 2007, 31, 1052-1063 (invited review). (DOI: 10.1039/B617628C) (S)


Sandanaraj, B. S.; Demont, R.; Thayumanavan, S. “Generating Patterns for Sensing Using a Single Receptor Scaffold” J. Am. Chem. Soc. 2007, 129, 3506-3507. (DOI: 10.1021/ja070229f) (S)


Sandanaraj, B. S.; Bayraktar, H.; Krishnamoorthy, K.; Knapp, M. J.; Thayumanavan, S. “Recognition and Modulation of Cytochrome c‘s Redox Properties using an Amphiphilic Homopolymer” Langmuir, 2007, 23, 3891-3897. (DOI: 10.1021/la063063p) (S)


Ambade, A. V.; Savariar, E. N.; Thayumanavan, S. “Dendritic Nanostructures for Cancer Therapy” Nanotechnology for Cancer Therapy, 2007, 509-521. (invited review). (DOI: 10.1201/9781420006636.ch26) (R, S)


Krishnamoorthy, K.; Reddy, D. R.; Nantalaksakul, A.; Thayumanavan, S. “Probing the Periphery of Dendrimers by Heterogeneous Electron Transfer” Chem. Commun. 2007, 739-741. (DOI: 10.1039/B614236B) (S)


Arumugam, S.; Vutukuri, D. R.; Thayumanavan, S.; Ramamurthy, V. “A Styrene Based Water Soluble Polymer as a Reaction Medium for Photodimerization of Aromatic Hydrocarbons in Water” J. Photochem. Photobiol. A: Chem. 2007, 185, 168-171. (DOI: 10.1016/j.jphotochem.2006.05.032) (S)


Ambade, A. V.; Sandanaraj, B. S.; Klaikherd, A.; Thayumanavan, S. “Fluorescent Polyelectrolytes as Protein Sensors” Polymer International, 2007, 56, 474-481 (Invited review). (DOI: 10.1002/pi.2185) (S)


Rotello, V.; Thayumanavan, S. “Editorial (Special issue on ‘Recognition Mediated Self-Assembly of Polymers’)” Polymer International, 2007, 56, 435. (DOI: 10.1002/pi.2288) (S)


Chen, Y.; Vutukuri, D. R.; Ambade, A. V.; Thayumanavan, S. “Self-Assembly of Facially Amphiphilic Dendrimers on Surfaces” J. Am. Chem. Soc. 2006, 128, 14760-14761. (DOI: 10.1021/ja065625x) (S)


Savariar, E. N.; Aathimanikandan, S. V.; Thayumanavan, S. “Supramolecular Assemblies from Amphiphilic Homopolymers: Testing the Scope” J. Am. Chem. Soc. 2006, 128, 16224-16230. (DOI: 10.1021/ja065213o) (S)


Ahn, T.-S.; Nantalaksakul, A.; Reddy, D. R.; Al-Kaysi, R.; Müller, A.M.; Thayumanavan, S.; Bardeen, C. J. “Energy and Charge Transfer Dynamics in Fully Decorated Benzyl Ether Dendrimers and Their Di-substituted Analogs” J. Phys. Chem. B. 2006, 110, 24331-24339. (DOI: 10.1021/jp0649706) (E)


Ghosh, S.; Basu, S.; Thayumanavan, S. “Simultaneous and Reversible Functionalization of Copolymers for Biological Applications” Macromolecules, 2006, 39, 5595-5597. (DOI: 10.1021/ma061420x) (R, S)


Roy, R.; Sandanaraj, B. S.; Klaikherd, A.; Thayumanavan, S. “Tuning Substrate Selectivity of a Cationic Enzyme Using Cationic Polymers” Langmuir, 2006, 22, 7695-7700. (DOI: 10.1021/la060496j) (R, S)


Sandanaraj, B. S.; Demont, R.; Aathimanikandan, S. V.; Savariar, E. N.; Thayumanavan, S. “Selective Sensing of Metalloproteins from Non-selective Binding using a Fluorogenic Amphiphilic Polymer” J. Am. Chem. Soc. 2006, 128, 10686-10687. (DOI: 10.1021/ja063544v) (S)


Nantalaksakul, A.; Reddy, D. R.; Ahn, T.-S.; Al-Kaysi, R.; Bardeen, C. J.; Thayumanavan, S. “Dendrimer Analogues of Linear Molecules to Evaluate Energy and Charge-Transfer Properties” Org. Lett. 2006, 8, 2981-2984. (DOI: 10.1021/ol0608956) (E)


Klaikherd, A.; Sandanaraj, B. S.; Vutukuri, D.; Thayumanavan, S. “Comparison of Facially Amphiphilic Biaryl Dendrimers with Classical Amphiphilic Ones Using Protein Surface Recognition as the Tool” J. Am. Chem. Soc. 2006, 128, 9231-9237. (DOI: 10.1021/ja0622406) (S)


Nantalaksakul, A.; Reddy, D. R.; Bardeen, C. J.; Thayumanavan, S. “Light Harvesting Dendrimers” Photosynthesis Research, 2006, 87, 133-150. (invited review). (DOI: 10.1007/s11120-005-8387-3) (E)


Basu, S.; Vutukuri, D.; Thayumanavan, S. “Homopolymer Micelles in Heterogeneous Solvent Mixtures” J. Am. Chem. Soc. 2005, 127, 16794-16795. (DOI: 10.1021/ja056042a) (S)


Thompson, A.L.; Ahn, T.-S.; Thomas, K. R. J.; Thayumanavan, S.; Martinez, T. J.; Bardeen, C. J. “Using Meta Conjugation to Enhance Charge Separation versus Charge Recombination in Phenylacetylene Donor-Bridge-Acceptor Complexes” J. Am. Chem. Soc., 2005, 127, 16348-16349. (DOI: 10.1021/ja054543q) (E)


Lee, S.; Thomas, K. R. J.; Thayumanavan, S.; Bardeen, C. J. “Dependence of the Two-Photon Absorption Cross Section on the Conjugation of the Phenylacetylene Linker in Dipolar Donor-Acceptor Chromophores” J. Phys. Chem. A. 2005, 109, 9767-9774. (DOI: 10.1021/jp053864l) (E)


Arumugam, S.; Vutukuri, D. R.; Thayumanavan, S.; Ramamurthy, V. “Amphiphilic Homopolymer as a Reaction Medium in Water: Product Selectivity Within Polymeric Nanopockets” J. Am. Chem. Soc. 2005, 127, 13200-13206. (DOI: 10.1021/ja051107v) (S)


Aathimanikandan, S. V.; Savariar, E. N.; Thayumanavan, S. “Temperature-Sensitive Dendritic Micelles” J. Am. Chem. Soc. 2005, 127, 14922-14929. (DOI: 10.1021/ja054542y) (S)


Sandanaraj, B. S.; Vutukuri, D.; Simard, J.; Klaikherd, A.; Hong, R.; Rotello, V. M.; Thayumanavan, S. “Non-Covalent Modification of Chymotrypsin Surface using Amphiphilic Polymeric Scaffold: Implications in Modulating Protein Function” J. Am. Chem. Soc. 2005, 127, 10693-10698. (DOI: 10.1021/ja051947+) (S)


Ambade, A.; Savariar, E. N.; Thayumanavan, S. “Dendrimeric Micelles for Controlled Drug Release and Targeted Delivery” Mol. Pharm. 2005, 2, 264-272 (invited review). (DOI: 10.1021/mp050020d) (S)


Jiang, J.; Thayumanavan, S. “Synthesis and Characterization of Amine-Functionalized Polystyrene Nanoparticles” Macromolecules, 2005, 38, 5886-5891. (DOI: 10.1021/ma0507286) (S, R)


Sivakumar, A. V.; Sandanaraj, B. S.; Arges, C. G.; Bardeen, C. J.; Thayumanavan, S. “Effect of Guest Molecule Flexibility in Access to Dendritic Interiors” Org. Lett. 2005, 7, 2809-2812. (DOI: 10.1021/ol050579b) (S)


Sivanandan, K.; Aathimanikandan, S. V.; Arges, C. G.; Bardeen, C. J.; Thayumanavan, S. “Probing Every Layer in Dendrons” J. Am. Chem. Soc.2005, 127, 2020-2021. (DOI: 10.1021/ja043356+) (S, E)


Thomas, K. R. J.; Thompson, A. L.; Aathimanikandan, S. V.; Bardeen, C. J.; Thayumanavan, S. “Energy and Electron Transfer in Bifunctional Non-conjugated Dendrimers” J. Am. Chem. Soc. 2005, 127, 373-383. (DOI: 10.1021/ja044778m) (E)


Jayakumar, K. N.; Thayumanavan, S. “Comparison of AB2 and AB4 Monomers in Ferrocene-cored Benzyl Ether Dendrimers” Tetrahedron, 2005, 61, 603-608. (DOI: 10.1016/j.tet.2004.11.002) (S)


Vutukuri, D. R.; Basu, S.; Thayumanavan, S. “Dendrimers with both Polar and Apolar Nanocontainer Characteristics” J. Am. Chem. Soc. 2004, 126, 15636-15637. (DOI: 10.1021/ja0449628) (S)


Savariar, E. N.; Thayumanavan, S. “Controlled Polymerization of N-isopropylacrylamide with an Activated Methacrylic Ester” J. Poly. Sci. Part A: Poly. Chem. 2004, 42, 6340-6345. (DOI:10.1002/pola.20467) (S, R)


Basu, S.; Vutukuri, D.; Shyamroy, S.; Sandanaraj, B.S.; Thayumanavan, S. “Invertible Amphiphilic Polymers” J. Am. Chem. Soc. 2004, 126, 9890-9891. (DOI: 10.1021/ja047816a) (S, R)


Jayakumar, K. N.; Thayumanavan, S. “Dendrimers Based on a Three-dimensionally Disposed AB4 Monomer” Org. Lett. 2004, 6, 2547-2550. (DOI: 10.1021/ol049147b) (S)


Sivanandan, K.; Britto,S.S.; Thayumanavan, S. “Sequences in Dendrons and Dendrimers” J. Org. Chem. 2004, 69, 2937-2944. (DOI: 10.1021/jo049878p) (S)


Thayumanavan, S.; Bharathi, P.; Sivanandan, K.; Vutukuri, D.R. “Towards Dendrimers as Biomimetic Macromolecules” Comptes Rendus Chimie, 2003, 6, 767-778 (invited review). (DOI: 10.1016/j.crci.2003.08.007) (S)


Bronk, K.; Thayumanavan, S. “Synthesis of Non-conjugated Dendrons with a Redox Gradient” J. Org. Chem. 2003, 68, 5559-5567. (DOI: 10.1021/jo034066z) (E)


Vutukuri, D.; Sivanandan, K.; Thayumanavan, S. ” Synthesis of dendrimers with multifunctional periphery using an ABB’ monomer” Chem. Commun. 2003, 796-797. (DOI: 10.1039/B212206P) (S)


Vutukuri, D.; Bharathi, P.; Yu, Z.; Rajasekaran, K.; Tran, M.-H.; Thayumanavan, S. “A Mild Deprotection Strategy for Allyl-Protecting Groups and Its Implications in Sequence Specific Dendrimer Synthesis” J. Org. Chem. 2003, 68, 1146-1149.  (DOI: 10.1021/jo026469p) (S)


Sivanandan, K.; Vutukuri, D.; Thayumanavan, S. “Functional Group Diversity in Dendrimers” Org. Lett. 2002, 4, 3751-3753. (DOI: 10.1021/ol026746e) (S)


Ganesh, R.N.; Shraberg, J.; Sheridan, P.G.; Thayumanavan, S. “Synthesis of Difunctionalized Dendrimers: An Approach to Main Chain Poly(dendrimers)” Tetrahedron Lett. 2002, 43, 7217-7220. (DOI: 10.1016/S0040-4039(02)01656-8) (S)


Basu, A.; Thayumanavan, S. “Configurational Stability and Transfer of Stereochemical Information in the Reactions of Enantioenriched Organolithium Reagents” Angew. Chem., Int. Ed. 2002, 41, 716-738. (DOI: 10.1002/1521-3773(20020301)41:5<716::AID-ANIE716>3.0.CO;2-Z) (Misc.)


Bharathi, P.; Zhao, H.; Thayumanavan, S. “Toward Globular Macromolecules with Functionalized Interiors: Design and Synthesis of Dendrons with an Interesting Twist” Org. Lett. 2001, 3, 1961-1964. (DOI: 10.1021/ol016064b) (S)


Bronk, K.; Thayumanavan, S. “Design and Synthesis of Non-Conjugated Monodendrons with Triarylamine Repeating Units” Org. Lett. 2001, 3, 2057-2060. (DOI: 10.1021/ol0160203) (E)


Zhao, H.; Tanjutco, C.; Thayumanavan, S. “Design and Synthesis of Stable Triarylamines for Hole-Transport Applications” Tetrahedron Lett. 2001, 42, 4421-4424. (DOI: 10.1016/S0040-4039(01)00702-X) (E)


Lancaster, K.; Odom, S.; Jones, S.; Thayumanavan, S.; Marder, S. R.; Bredas, J.-L.; Coropceanu, V.; Barlow, S. “Intramolecular Electron-Transfer Rates in Mixed-Valence Triarylamines: Measurement by Variable-Temperature ESR Spectroscopy and Comparison with Optical Data” J. Am. Chem. Soc. 2009, 131, 1717-1723. (DOI: 10.1021/ja808465c)


Ramos-Ortiz, G.; Cha, M.; Thayumanavan, S.; Mendez, J.; Marder, S.R.; Kippelen, B. “Ultrafast-Pulse Diagnostic Using Third-Order Frequency-Resolved Optical Gating n Organic Films” Appl. Phys. Lett. 2004, 85, 2809-2812. (DOI: 10.1063/1.1807952)


Dyer, D. J.; Cumpston, B. H.; McCord-Maughon, D.; Thayumanavan, S.; Barlow, S.; Perry, J. W.; Marder, S. R.  “Turning on Fluorescence by Two-Photon Excitation and Polymerization: Toward a 3-D Optical Memory Device” Nonlinear Optics, Quant. Opt. 2004, 31(1-4), 175-184.


Ramos-Ortiz, G.; Cha, M.; Thayumanavan, S.; Mendez, J.C.; Marder, S.R.; Kippelen, B. “Third-order optical autocorrelator for time-domain operation at telecommunication wavelengths” Appl. Phys. Lett. 2004, 85, 179-181.  (DOI: 10.1063/1.1771809)


Maldonado, J.-L.; Bishop, M.; Fuentes-Hernandez, C.; Caron, P.; Domercq, B.; Zhang, Y.-D.; Barlow, S.; Thayumanavan, S.; Malagoli, M.; Bredas, J.-L.; Marder, S.R.; Kippelen, B. “Effect of Substitution on the Hole Mobility of Bis(diarylamino)biphenyl Derivatives Doped in Poly(Styrene)” Chem. Mat. 2003, 15, 994-999. (DOI: 10.1021/cm0207907)


Cha, M.; Ramos-Ortiz, G.; Kim, H. T.; Choi, H.; Thayumanavan, S.; Mendez, J.; Marder, S. R.; Kippelen, B.  “Broadband Efficient Third-harmonic Generation in an Organic Film” Trends in Optics and Photonics, 2003, 88.


Ehrlich, J.E.; Ananthavel, S.P.; Barlow, S.; Mansour, K.; Mohanalingam,K.; Marder,S.R; Perry, J.W.; Rumi, M.; Thayumanavan, S. “Nonlinear Optical Absorption Properties Of Bis-Diarylaminobiphenyl Chromophores” MCLC S&T, Section B: Nonlinear Optics, 2001, 27, 121-131.


Cornil, J.; Gruhn, N.E.; dos Santos, D.A.; Malagoli, M.; Lee, P.A.; Barlow, S.; Thayumanavan, S.; Marder, S.R.; Armstrong, N.R.; Brédas, J.L. “Joint Experimental and Theoretical Characterization of the Electronic Structure of 4,4′-Bis(N-m-tolyl-N-phenylamino)biphenyl (TPD) and Substituted Derivatives” J. Phys. Chem. A. 2001, 105, 5206-5211. (DOI: 10.1021/jp003142o)


Galvan-Gonzalez, A.; Stegeman, G.I.; Jen, A.K.Y.; Wu, X.; Canva, M.; Kowalczyk, A.C.; Zhang, X.Q.; Lackritz, H.S.; Marder, S.; Thayumanavan, S.; Levina, G. “Photostability of electro-optic polymers possessing chromophores with efficient amino donors and cyano-containing acceptors” J. Opt. Soc. Am. B., Opt. Phys. 2001, 18, 1846-1853. (DOI: 10.1364/JOSAB.18.001846)


Kuebler, S.M.; Rumi, M.; Watanabe, T.; Braun, K.; Cumpston, B.H.; Heikal, A.A.; Erskine, L.L.; Thayumanavan, S.; Barlow, S.; Marder, S.R.; Perry, J.W. “Optimizing Two-Photon Initiators and Exposure Conditions for Three-Dimensional Lithographic Microfabrication” J. Photopolym. Sci. Tech. 2001, 14, 657-668. (DOI: 10.2494/photopolymer.14.657)


Rumi, M.; Ehrlich, J.E.; Heikal, A.A.; Perry, J.W.; Barlow, S.; Hu, Z.; McCord-Maughon, D.; Parker, T.C.; Röckel, H.; Thayumanavan, S.; Marder, S.R.; Beljonne, D.; Brédas, J.L. “Structure-Property Relationships for Two-Photon Absorbing Chromophores: Bis-Donor Diphenylpolyene and Bis(styryl)benzene Derivatives” J. Am. Chem. Soc. 2000, 122, 9500-9510. (DOI: 10.1021/ja994497s)


McDonald, E.M.; Anderson, J.D.; Slaterback, A.F.; Thayumanavan, S.; Barlow, S.; Zhang, Y.; Marder, S.R.; Hall, H.K.; Nabor, M.F.; Wang, J.-F.; Mash, E.A.; Armstrong, N.R.; Wightman, R.M. “Electrogenerated Chemiluminescence from Derivatives of Aluminum Quinolate and Quinacridones: Cross-Reactions with Triarylamines Lead to Singlet Emission Through Triplet-Triplet Annihilation Pathways” J. Am. Chem. Soc. 2000, 122, 4972-4979. (DOI: 10.1021/ja0005993)


Hendrickx, E.; Kippelen, B.; Thayumanavan, S.; Marder, S.R.; Persoons, A.P.; Peyghambarian, N. “High Photogeneration Efficiency of Charge-Transfer Complexes Formed Between Low Ionization Potential Arylamines and C60J. Chem. Phys. 2000, 112, 9557-9561. (DOI: 10.1063/1.481572)


Galvan-Gonzalez, A.; Canva, M.; Stegeman, G.I.; Twieg, R.; Chan, K.P.; Kowalczyk, T.C.; Zhang, X.Q.; Lackritz, H.S.; Marder, S.; Thayumanavan, S. “Systematic Behavior of Electro-Optic Chromophore Photostability” Opt. Lett. 2000, 25, 332-334. (DOI: 10.1364/OL.25.000332)


Hendrickx, E.; Kippelen, B.; Thayumanavan, S.; Marder, S. R.; Persoons, A. P.; Peyghambarian, N. “Improved Photogeneration Efficiency of Charge-Transfer Complexes Between C60 and Low Ionization Potential Arylamines” MCLC S&T, Sect. B: Nonlinear Opt. 2000, 25(1-4), 303-308.


Stegeman, G. I.; Van-Gonzales, A. Gal; Canva, M.; Twieg, R.; Kowalczyk, A. C.; Zhang, X. Q.; Lackritz, H. S.; Marder, S.; Thayumanavan, S.; Chan, K. P.; Jen, A. K-Y.; Wu, X. “Photodegradation of various electro-optic polymer families” MCLC S&T, Sect. B: Nonlinear Opt. 2000, 25(1-4), 57-66.


Jabbour, G.E.; Shaheen, S.E.; Morrell, M.M.; Anderson, J.D.; Lee, P.; Thayumanavan, S.; Barlow, S.; Bellmann, E.; Grubbs, R.H.; Kippelen, B.; Marder, S.; Armstrong, N.R.; Peyghambarian, N. “High Tg Hole Transport Polymers for the Fabrication of Bright and Efficient Organic Light-emitting Devices with an Air-stable Cathode” IEEE J. Quant. Elec. 2000, 36, 12-17. (DOI: 10.1109/3.817633)


Thayumanavan, S.; Mendez, J.; Marder, S.R. “Synthesis of Functionalized Organic Second-Order Nonlinear Optical Chromophores for Electro-Optic Applications”, J. Org. Chem. 1999, 64, 4289-4297. (DOI: 10.1021/jo981707v)


Ma, H.; Jen, A.K.-Y.; Wu, J.; Wu, X.; Liu, S.; Shu, C.-F.; Dalton, L.R.; Marder, S.R.; Thayumanavan, S. “A Convenient Modular Approach of Functionalizing Aromatic Polyquinolines for Electro-Optic Devices”, Chem. Mat. 1999, 11, 2218-2225. (DOI: 10.1021/cm9901818)


Perry, J.W.; Barlow, S.; Ehrlich, J.E.; Heikal, A.A.; Hu, Z.-Y.; Lee, I.-Y.S.; Mansour, K.; Marder, S.R.; Röckel, H.; Rumi, M.; Thayumanavan, S.; Wu, X.L. “Two-Photon Absorption and Optical Limiting Properties of Bis-Donor Substituted Conjugated Chromophores” Nonlinear Optics, 1999, 21, 225-243.


Jabbour, G.E.; Shaheen, S.E.; Morrell, M. M.; Anderson, J. D.; Lee, P.; Thayumanavan, S.; Barlow, S.; Marder, S. R.; Bellmann, E.; Grubbs, R. H.; Kippelen, B.; Armstrong, N. R.; Peyghambarian, N. “Hybrid Bilayer Organic Light-emitting Devices Based on High Tg Hole Transport Polymers” Proc. SPIE, 1999, 3623, 20-27. (DOI: 10.1117/12.348406)


Anderson, J.; Lee, P.; McDonald, E.; Wightman, R.M.; Hall, H.K.; Hopkins, T.; Padias, A.; Thayumanavan, S.; Barlow, S.; Marder, S.; Armstrong, N.R. “Electrochemical Models for the Radical Annihilation Reactions in Organic Light-Emitting Diodes”, Proc. SPIE. 1998, 3476-29, 178-187. (DOI: 10.1117/12.332611)


Anderson, J.D.; McDonald, E.M.; Lee, P.A.; Anderson, M.L.; Ritchie, E.L.; Hall, H.K.; Hopkins, T.; Mash, E.A.; Wang, J.; Padias, A.; Thayumanavan, S.; Barlow, S.; Marder, S.R.; Jabbour, G.E.; Shaheen, S.; Kippelen, B.; Peyghambarian, N.; Wightman, R.M.; Armstrong, N.R. “Electrochemistry and Electrogenerated Chemiluminescence Processes of the Components of Aluminum Quinolate / Triarylamine, and Related Organic Light Emitting Diodes” J. Am. Chem. Soc. 1998, 120, 9646-9655. (DOI: 10.1021/ja980707+)


Bellmann, E.; Shaheen, S.E.; Thayumanavan, S.; Barlow, S.; Grubbs, R.H.; Marder, S.R.; Kippelen, B.; Peyghambarian, N. “New Triarylamine-containing Polymers as Hole Transport Materials in Organic Light-emitting Diodes: Effect of Polymer Structure and Crosslinking on Device Characteristics” Chem. Mater. 1998, 10, 1668-1676. (DOI: 10.1021/cm980030p)


Thayumanavan, S.; Barlow, S.; Marder, S.R. “Synthesis of Unsymmetrical Triarylamines for Photonic Applications via One Pot Palladium Catalyzed Aminations” Chem. Mater. 1997, 9, 3231-3235. (DOI: 10.1021/cm970567n)


Barlow, S.; Cumpston, B.H.; Ehrlich, J.; Heikal, A.A.; McCord-Maughon, D.; Marder, S.R.; Perry, J.W.; Röckel, H.; Thayumanavan, S.; Wu, X.L. “Structure/Property Relationships for, and Applications of Two-photon Absorbing Organic Molecules” Proc. SPIE , 1997, 3147, 13.


Beljonne, D.; Bredas, J. -L.; Cumpston, B. H.; Ehrlich, J.; Erskine, L.; Heikal, A. A.; Hu, Z. -Y.; Kogej, T.; Lee, I. -Y. S.; Marder, S. R.; Perry, J. W.; Rockel, H.; Thayumanavan, S.; Wu, X. -L. “Design, synthesis, nonlinear spectroscopy and applications of two-photon absorbing molecules Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1997, 38(2), 497.


Thayumanavan, S.; Basu, A.; Beak, P. “Two Different Pathways of Stereoinformation Transfer: Asymmetric Substitutions in the (-)-Sparteine Mediated Reactions of Laterally Lithiated N,N-Diisopropyl-o-ethylbenzamide and N-pivaloyl-o-ethylaniline” J. Am. Chem. Soc. 1997, 119, 8209-8217. (DOI: 10.1021/ja970930r)


Thayumanavan, S.; Park, Y.S.; Farid, P.; Beak, P. “Fluoride Activated Stereoinformation Transfer from a C-Si bond of a Chiral Benzyl Silane to C-C Bonds”, Tetrahedron Lett. 1997, 38, 5429-5432. (DOI: 10.1016/S0040-4039(97)01214-8)



Beak, P.; Basu, A.; Gallagher, D.J.; Park, Y.S.; Thayumanavan, S. “Regioselective, Diastereoselective, and Enantioselective Lithiation-Substitution Sequences: Reaction Pathways and Synthetic Applications”, Acc. Chem. Res. 1996, 29, 552-559.  (DOI: 10.1021/ar950142b)


Thayumanavan, S.; Beak, P.; Curran, D.P. “Asymmetric Deprotonation of N,N-Dihexyl-1-Naphthamides to Provide Atropisomers of N,N-Dihexyl-2-Alkyl-1-Naphthamides”, Tetrahedron Lett. 1996, 37, 2899-2902.  (DOI: 10.1016/0040-4039(96)00439-X)



Thayumanavan, S.; Lee, S.; Liu, C.; Beak, P. “Asymmetric Substitutions: High and Opposite Enantioselective Alkylations of a Racemic Organolithium Intermediate in the Presence of (-)-Sparteine,” J. Am. Chem. Soc. 1994, 116, 9755-9756. (DOI: 10.1021/ja00100a053)


Rajca, A.; Utempanya, S.; Thayumanavan, S. “Poly(arylmethyl) Octet (S=7/2) Heptaradical and Undecet (S=5) Decaradical,” J. Am. Chem. Soc. 1992, 114, 1884-1885. (DOI: 10.1021/ja00031a055)